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2014 20th International Conference on Ion Implantation Technology (IIT)最新文献

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Activation and defect dissolution of non-amorphizing, elevated temperature Si+ implants into In0.53Ga0.47As In0.53Ga0.47As中非非晶高温Si+植入物的活化和缺陷溶解
Pub Date : 2014-10-30 DOI: 10.1109/IIT.2014.6939962
A. G. Lind, K. Jones, C. Hatem
A range of implant temperatures from 20 to 300C are studied for fixed 20 keV implant energy and 6E14 cm-2 dose Si implants into In0.53Ga0.47As. Hall effect measurements performed on the samples after rapid thermal annealing reveal that Si implant activation is actually maximized for intermediate implant temperatures from 50-110C that are shown to be non-amorphizing. While these results echo the conclusion of previous studies that elevated temperature Si implants into In0.53Ga0.47As show increased activation over implants that are likely amorphizing, it is clear that there is a temperature window from 50-110C where activation is improved with increasing thermal budget for the dose and energy studied. Calculated Si solubilities of up to 1.3E19 cm-3 and sheet resistances as low as 26 ohm/sq are achieved for a 10 keV 5E14 cm-2 Si implant performed at 80C after 750C 5s annealing.
研究了20 ~ 300℃的植入温度范围,将能量为20 keV的植入物和6E14 cm-2剂量的Si植入到In0.53Ga0.47As中。在快速热退火后对样品进行的霍尔效应测量表明,在50-110℃的中间植入温度下,Si植入激活实际上是最大化的,这表明非非晶化。虽然这些结果与之前的研究结论相呼应,即升高Si植入物到In0.53Ga0.47As中的激活比可能非晶化的植入物增加,但很明显,在50-110℃之间存在一个温度窗口,随着所研究剂量和能量的热收支增加,激活得到改善。计算出的Si溶解度高达1.3E19 cm-3,片电阻低至26欧姆/平方,在80C下进行的10kev 5E14 cm-2 Si植入物经过750C 5s退火后实现。
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引用次数: 1
Simulation of 3D FinFET doping profiles introduced by ion implantation and the impact on device performance 离子注入引入的三维FinFET掺杂谱模拟及其对器件性能的影响
Pub Date : 2014-10-30 DOI: 10.1109/IIT.2014.6940008
Liping Wang, A. Brown, B. Cheng, A. Asenov
A simulation program, Anadope3D, developed to model ion implantations in FinFETs based on quasi-analytic methods, has been improved to include a set of analytical implantation models based on a Pearson distribution function, which is concise and computationally efficient. This C++ module has been integrated into the GSS atomistic device simulator GARAND, which enables more realistic doping distributions arising from ion implantation to be used for TCAD FinFET simulations. Simulations are performed on an example of an SOI FinFET with physical gate length of 20nm, including statistical simulations with Random Discrete Dopants (RDD). The impact of the realistic 3D doping profile on FinFET performance has been investigated.
基于准解析方法模拟离子注入的仿真程序Anadope3D得到了改进,包含了一组基于Pearson分布函数的解析注入模型,该模型简洁且计算效率高。该c++模块已集成到GSS原子器件模拟器GARAND中,使离子注入产生的更真实的掺杂分布能够用于TCAD FinFET模拟。对物理栅极长度为20nm的SOI FinFET进行了仿真,包括随机离散掺杂剂(RDD)的统计仿真。研究了真实三维掺杂对FinFET性能的影响。
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引用次数: 0
Thermal processing for continued scaling of semiconductor devices 半导体器件持续缩放的热处理
Pub Date : 2014-10-30 DOI: 10.1109/IIT.2014.6939954
S. Sharma, W. Aderhold, K. Raman Sharma, A. Mayur
Scaling of semiconductor devices over past decades has been made possible by continuous innovations in materials engineering as well as device integration and geometries. Thermal processing has been an enabler for manufacturing advanced devices, both as a unit process and in concert with other key technologies like ion implantation, epitaxy, and film deposition. This paper reviews the evolution of annealing technology with a special consideration to thermodynamics, kinetics and integration thermal budgets. Equipment and process innovations to meet ever-changing material and device fabrication requirements are presented.
在过去的几十年中,由于材料工程以及器件集成和几何结构的不断创新,半导体器件的缩放成为可能。无论是作为一个单元工艺,还是与离子注入、外延和薄膜沉积等其他关键技术相结合,热加工一直是制造先进设备的推动者。本文回顾了退火技术的发展,特别考虑了热力学、动力学和积分热收支。设备和工艺创新,以满足不断变化的材料和器件制造要求。
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引用次数: 3
Characterization of arsenic PIII implants in FinFETs by LEXES, SIMS and STEM-EDX 基于LEXES、SIMS和STEM-EDX的finfet中砷PIII植入物的表征
Pub Date : 2014-10-30 DOI: 10.1109/IIT.2014.6940011
K.-A. Bui-T Meura, F. Torregrosa, A. Robbes, Seo-Youn Choi, A. Merkulov, M. Moret, J. Duchaine, N. Horiguchi, Letian Li, C. Mitterbauer
FinFETs have emerged as a novel transistor architecture for 22nm technology and beyond thanks to good electrostatic control and scalability [1,2]. However, the change from planar to FinFET device architectures challenges the junction formation and the characterization. Fin sidewall doping and doping damages control are critical in scaled FinFETs [3,4,5] but both are difficult to achieve with conventional beamline ion implantation. As an alternative technique, Plasma Immersion Ion implantation (PIII) has shown promising results [6,7]. New characterization techniques such as SIMS through fins, SSRM, atom probe tomography, are needed [8,9,10] to complement standard sheet resistance and SIMS measurements to evaluate sidewall dopants. In this paper we present Low energy Electron X-Ray Emission Spectrometry (LEXES) and SIMS through fins for the characterization of arsenic implants in FinFETs by PIII. STEM-EDX has been used to double check SIMS average data at the fin's scale. The complementarity of these techniques will be presented and excellent conformal fin doping capability of the PULSION® tool is demonstrated.
由于良好的静电控制和可扩展性,finfet已成为22nm及以上技术的新型晶体管架构[1,2]。然而,从平面到FinFET器件架构的变化对结的形成和表征提出了挑战。翅片侧壁掺杂和掺杂损伤控制是缩放finfet的关键[3,4,5],但传统的束线离子注入难以实现。作为一种替代技术,等离子体浸没离子注入(PIII)已显示出良好的效果[6,7]。需要新的表征技术,如通过翅片的SIMS、SSRM、原子探针断层扫描[8,9,10]来补充标准薄片电阻和SIMS测量来评估侧壁掺杂物。在本文中,我们提出了低能电子x射线发射光谱(LEXES)和通过鳍的SIMS来表征PIII在finfet中的砷植入物。STEM-EDX已被用于重复检查SIMS在鳍尺度上的平均数据。将展示这些技术的互补性,并展示了出色的保角鳍掺杂能力。
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引用次数: 4
Selective microwave mode excitation and charge state distribution on the first stage of tandem type ECRIS 串联型ECRIS第一级的选择性微波模式激励和电荷态分布
Pub Date : 2014-10-30 DOI: 10.1109/IIT.2014.6940033
Y. Kato, D. Kimura, K. Yano, S. Kumakura, Y. Imai, T. Nishiokada, F. Sato, T. Iida
A new concept on magnetic field of plasma production and confinement has been proposed to enhance efficiency of an electron cyclotron resonance (ECR) plasma for broad and dense ion beam source under the low pressure. We make this source a part of new tandem type ion source for the first stage. We are also constructing the large bore second stage for synthesizing, extracting and analyzing ions. Both ECR plasmas are necessary to be available to coexist and to be operated individually with different plasma parameters. In the first stage, we optimize the ion beam current and ion saturation current by a mobile plate tuner. They change by the position of the plate tuner for single and multi-frequencies microwaves. The peak positions of them are close to the position where the microwave mode forms standing wave between the plate tuner and the extractor. We show a new guiding principle, which the number of efficiently azimuthal microwave mode should be selected to fit to that of multipole of comb-shaped magnets. We obtained the excitation of selective modes using new mobile plate tuner to enhance ECR efficiency. Furthermore we first obtained charge state distributions of ion beams extracted from the first stage after constructing the second stage and its beam line.
为了提高低压宽密离子束源电子回旋共振等离子体的效率,提出了等离子体产生和约束磁场的新概念。我们将该源作为第一级新型串联型离子源的一部分。我们还在建设用于离子合成、提取和分析的大口径第二阶段。两个ECR等离子体必须能够共存,并以不同的等离子体参数单独操作。在第一阶段,我们利用移动平板调谐器优化了离子束电流和离子饱和电流。对于单频率和多频率微波,它们随平板调谐器的位置而变化。它们的峰值位置接近于微波模式在平板调谐器和提取器之间形成驻波的位置。提出了一种新的指导原则,即选择有效方位微波模式的数量应与梳子形磁体的多极数相适应。我们利用新的移动平板调谐器获得了选择性模式的激励,以提高ECR效率。此外,在构造了第二级及其束流线后,我们首次得到了从第一级提取的离子束的电荷态分布。
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引用次数: 0
Silicon defects characterization for low temperature ion implantation and spike anneal processes 低温离子注入和尖峰退火过程中硅缺陷的表征
Pub Date : 2014-10-30 DOI: 10.1109/IIT.2014.6940014
G. Margutti, Diego Martirani Paolillo, Marco De Biase, L. Latessa, M. Barozzi, E. Demenev, L. Rubin, C. Spaggiari
In the last years a lot of effort has been directed in order to reduce ion implantation damage, which can be detrimental for silicon device performances. Implantation's dose rate and temperature were found to be two important factors to modulate residual damage left in silicon after anneal. In this work high dose rate, low temperature, high dose arsenic and boron implantations are compared to the corresponding low dose rate, room temperature processes in terms of silicon lattice defectiveness and dopant distribution, before and after anneal is performed. The considered implant processes are the one typically used to form a source/drain region in a CMOS process flow in the submicron technology node. A spike anneal process was applied to activate the dopant. Low temperature, high dose rate implantations have found to be effective in reducing silicon extended defects with a negligible effect on the profile of the activated dopant. Experimental set up, results and possible explanation will be reported and discussed in the paper.
在过去的几年里,为了减少离子注入对硅器件性能的损害,人们做了很多努力。发现注入剂量率和温度是调节退火后硅中残余损伤的两个重要因素。在本研究中,将高剂量率、低温、高剂量砷和硼注入与相应的低剂量率、室温工艺在退火前后硅晶格缺陷和掺杂分布方面进行了比较。所考虑的植入工艺通常用于在亚微米技术节点的CMOS工艺流程中形成源/漏区。采用脉冲退火工艺活化掺杂剂。低温、高剂量率的注入可以有效地减少硅延伸缺陷,而对活性掺杂的影响可以忽略不计。本文将报告和讨论实验设置、结果和可能的解释。
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引用次数: 4
Study of AsH3 Plasma Immersion Ion Implantation using PULSION® 使用pulusl®进行AsH3等离子体浸没离子注入的研究
Pub Date : 2014-10-30 DOI: 10.1109/IIT.2014.6939963
J. Duchaine, F. Torregrosa, Y. Spiegel, G. Borvon, S. Qin, Y. Hu, A. Mcteer
Plasma immersion ion implantation (PIII) technology is known as an alternative to overcome the limitations of conventional beam line ion implantation for shallow, high dose and 3D doping on advanced memory and logic devices. This technique also shows a better CoO as the result of higher productivity, smaller footprint and lower operating costs. Implementation in production for P-type doping and development of N-type applications address issues from the challenges linked to the use of hydrides, especially in the case of AsH3 and PH3. Problems of excessive deposition lead to difficult process integration and possible safety issues such as wafer out-gassing. [1]. Higher priced gases coupled with higher gas consumption compared to beam line are often mentioned as limitations. In this paper we present a full characterization (done at Micron and at IBS) of AsH3 plasma implantation using PULSION® (PIII tool produced by IBS). Due to its unique remote source design, PULSION® allows a wider process window using lower gas flows [2]. These design advantages minimize the before mentioned drawbacks allowing easier process integration [3]. AES (Auger Electron Spectroscopy), ARXPS (Angle Resolution X-ray Photoelectron Spectroscopy), TOF-SIMS & D-SIMS (Secondary Ion Mass Spectrometry), and TEM (Transmission Electron Microscopy) analysis are used to study deposition, doping profiles, and amorphization as a function of acceleration voltage and dose. The effect of dose on sheet resistance after Spike anneal is discussed, as well as the effect of possible hydrogen dilution. Out-gassing measurements are also presented.
等离子体浸没离子注入(PIII)技术被认为是克服传统束流线离子注入的局限性的一种替代方法,可以在先进的存储和逻辑器件上进行浅、高剂量和3D掺杂。由于生产率更高、占用空间更小、操作成本更低,该技术还显示出更好的CoO。p型掺杂的生产实施和n型应用的开发解决了与氢化物使用相关的挑战,特别是在AsH3和PH3的情况下。过度沉积的问题导致工艺集成困难和可能的安全问题,如晶圆出气。[1]。与束流管线相比,价格较高的气体加上较高的气体消耗通常被认为是限制因素。在本文中,我们提出了一个完整的表征(在Micron和IBS完成)的AsH3等离子体植入使用的浦勒®(PIII工具由IBS生产)。由于其独特的远程源设计,浦力®允许更宽的工艺窗口使用更低的气体流量[2]。这些设计优势最大限度地减少了前面提到的缺点,允许更容易的过程集成[3]。AES(俄歇电子能谱)、ARXPS(角度分辨率x射线光电子能谱)、TOF-SIMS & D-SIMS(二次离子质谱)和TEM(透射电子显微镜)分析用于研究沉积、掺杂谱和非晶化作为加速电压和剂量的函数。讨论了剂量对Spike退火后片材电阻的影响,以及可能的氢稀释的影响。还介绍了放气的测量方法。
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引用次数: 3
Thermal cycle annealing and its application to arsenic-ion implanted HgCdTe 热循环退火及其在砷离子注入HgCdTe中的应用
Pub Date : 2014-10-30 DOI: 10.1109/IIT.2014.6940053
S. Simingalam, P. Wijewarnasuriya, M. V. Rao
Arsenic ion-implantation is a standard device processing step to create selective area p+-HgCdTe (MCT) regions in planar devices. One of the issues associated with the ion-implantation process is the significant structural damage to the MCT epilayer. These structural defects limit the performance of diodes via significant tunneling reverse-bias dark currents. After ion-implantation, a high temperature annealing step is required to activate the implant (arsenic) by moving it into the tellurium sublattice and also to heal the lattice damage caused by the implantation process. In this study, we have used thermal cycle annealing (TCA) to decrease ion implantation damage. In TCA, we rapidly heat and cool an MCT sample, which provides an additional degree of freedom that is not obtainable with conventional annealing. We have successfully performed TCA for dislocation defect reduction in in-situ indium-doped MCT with limited inter-diffusion between the absorber layer and cadmium rich cap layer. We also investigated the application of TCA to arsenic ion-implanted MCT. Defects were studied using scanning electron microscopy (SEM) after subjecting the samples to Benson etching to decorate the defects. Mercury-deficient and tellurium-saturated overpressure anneals were performed in an attempt to increase mercury vacancy concentrations and, thereby, increase dislocation climb. Such anneals significantly increased the etch pit density (EPD) in both ion-implanted and un-implanted MCT. By cycle annealing, we have also shown EPD reduction in arsenic ion-implanted, long bar shaped MCT mesas formed on CdTe/Si substrates.
砷离子注入是在平面器件中产生选择性p+-HgCdTe (MCT)区域的标准器件加工步骤。与离子注入过程相关的问题之一是对MCT脱膜的显著结构损伤。这些结构缺陷限制了二极管的性能,通过显着的隧道反向偏置暗电流。离子注入后,需要一个高温退火步骤来激活植入物(砷),将其移动到碲亚晶格中,并修复植入过程造成的晶格损伤。在这项研究中,我们使用热循环退火(TCA)来减少离子注入损伤。在TCA中,我们快速加热和冷却MCT样品,这提供了传统退火无法获得的额外自由度。在吸收层和富镉帽层之间扩散有限的情况下,我们成功地对原位掺杂铟MCT的位错缺陷进行了TCA还原。我们还研究了TCA在砷离子注入MCT中的应用。对样品进行Benson蚀刻修饰后,用扫描电镜对缺陷进行了研究。进行了缺汞和饱和碲的超压退火,试图增加汞空位浓度,从而增加位错爬升。这种退火显著增加了离子注入和未注入MCT的蚀刻坑密度(EPD)。通过循环退火,我们还发现砷离子注入在CdTe/Si衬底上形成的长条形MCT平台中EPD减少。
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引用次数: 2
Ion beams, thermal processes and lithographic challenges 离子束,热加工和光刻的挑战
Pub Date : 2014-10-30 DOI: 10.1109/IIT.2014.6939966
H. Levinson, T. Brunner
Among the challenges with which lithographers are currently grappling, the issues of line-edge roughness (LER) and non-linear overlay errors intersect the concerns of ion implantation and thermal process engineers. LER, and the associated metric for contact holes, local critical dimension uniformity (LCDU), must be small to meet the requirements of advanced nodes. Photon shot-noise-induced LER and LCDU diminution, which can benefit from high resist exposure doses, must be balanced with exposure tool throughput requirements for meeting cost targets for Moore's Law. Because very small improvements in LER and LCDU can require substantial increases in resist exposure doses, post-lithographic techniques for reducing LER and LCDU can have sizable salutary impact on overall wafer costs. The impact of LER on circuit performance depends on the spatial frequencies comprising the LER, and the criticality of particular ranges of spatial frequencies may shift as a consequence of transitions to new types of devices. LER can be reduced post-lithographically by using charged particle beams. Non-linear wafer distortions, which can result from thermal processes and the etching of high-stress films, are problematic for overlay control. Correction of non-linear overlay errors requires the use of a large number of alignment sites and overlay measurements, again resulting in a trade-off between process control and wafer cost. The impact of these distortions on overlay can be predicted quantitatively by measurements of out-of-plane wafer warp. Such measurements can be used to develop processes with intrinsically low distortion and for maintaining process control in manufacturing.
在光刻工目前面临的挑战中,线边缘粗糙度(LER)和非线性叠加误差的问题交叉了离子注入和热工艺工程师的关注。LER和与之相关的接触孔度量,局部临界尺寸均匀性(LCDU)必须很小,以满足高级节点的要求。光子发射噪声诱导的LER和LCDU减少可以受益于高抗蚀暴露剂量,必须与暴露工具吞吐量要求相平衡,以满足摩尔定律的成本目标。由于LER和LCDU的微小改进可能需要大量增加抗蚀剂暴露剂量,因此减少LER和LCDU的光刻后技术可以对整体晶圆成本产生相当大的有益影响。LER对电路性能的影响取决于构成LER的空间频率,而特定空间频率范围的临界可能会随着向新型器件的过渡而发生变化。利用带电粒子束可以在光刻后减少LER。由于热加工和高应力薄膜的蚀刻导致的非线性晶圆扭曲,是覆盖层控制的问题。非线性叠加误差的校正需要使用大量的对准位置和叠加测量,再次导致过程控制和晶圆成本之间的权衡。这些变形对覆盖层的影响可以通过测量面外晶圆翘曲来定量预测。这种测量可用于开发具有低失真的工艺,并用于维持制造过程控制。
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引用次数: 0
Investigation of charge build-up in NO nitrided gate oxide on 4H-SiC during Fowler-Nordheim injection and fabrication of 4H-SiC Lateral Double-Implanted MOSFETs Fowler-Nordheim注入过程中4H-SiC上NO氮化栅氧化物电荷积累的研究及4H-SiC横向双植入mosfet的制备
Pub Date : 2014-10-30 DOI: 10.1109/IIT.2014.6940051
J. Moon, W. Bahng, I. Kang, Sang Cheol Kim, N. Kim
The charge build up in gate oxide and the field effective mobility of 4H-SiC Lateral Double Implanted Metal-Oxide-Semiconductor Field-Effect Transistors (DIMOSFETs) have been evaluated for its dependence on the Post-Oxidation Annealing (POA) time in a nitric oxide gas ambient. NO nitrided oxide for 3 hours significantly reduces the interface trap density near the conduction band and effective oxide charge density, resulting in a decrease of oxide trapped charge in gate oxide during Fowler-Nordheim injection as compared with that of NO POA for 1-2 hours. A high field effect mobility of 11.8 cm2/Vs was successfully achieved in Lateral DIMOSFETs with NO POA for 3 hours. The electrical properties of metal-oxide semiconductor devices fabricated using these oxides are discussed in terms of the oxide's chemical composition.
本文研究了4H-SiC双植入金属-氧化物-半导体场效应晶体管(dimosfet)在氧化后退火(POA)时间对栅极氧化物电荷积累和场有效迁移率的影响。NO氮化氧化物3小时显著降低了导带附近的界面陷阱密度和有效氧化物电荷密度,导致Fowler-Nordheim注入过程中栅极氧化物中的氧化物陷阱电荷比NO POA 1-2小时减少。在没有POA的情况下,在3小时内成功地实现了11.8 cm2/Vs的高场效应迁移率。从氧化物的化学成分的角度讨论了用这些氧化物制备的金属氧化物半导体器件的电学性能。
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引用次数: 0
期刊
2014 20th International Conference on Ion Implantation Technology (IIT)
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