首页 > 最新文献

2019 IEEE 69th Electronic Components and Technology Conference (ECTC)最新文献

英文 中文
Preparation and Characterization of Electroplated Cu/Graphene Composite 电镀铜/石墨烯复合材料的制备与表征
Pub Date : 2019-05-28 DOI: 10.1109/ECTC.2019.00-12
Xin Wang, Qian Wang, Jian Cai, Changmin Song, Yang Hu, Yang Zhao, Yu Pei
Cu and unoxidized graphene composite films were prepared by electroplating under room temperature. Graphene was added to the electrolyte of Cu to form composite materials to improve the performance of Cu for interconnection. Composite electrolyte containing high concentration of graphene (up to 0.5 g/L) was prepared by adding CTAB as surfactant. And ultrasound was also used to increase dispersion degree and reduce graphene agglomeration in electrolyte. Average coefficient of thermal expansion (CTE) of the composite films determined by thermo-mechanical analysis (TMA) shows a decrease from 17.3 ppm/K to 14.2 ppm/K from 260 K to 320 K, which reduce CTE by 18 % compared with Cu. CTE of the composite materials can be reduced to 10 ppm/K at 243 K, which is only 60 % of CTE of Cu. The thermal conductivity of the composite materials measured by phase sensitive transient thermo-reflectance (PSTTR) technique shows an improvement from 385 W/m.K to 468 W/m.K. CTE and thermal conductivity of the composite materials both decrease with the increase of current density. And they also both increase with the increase of graphene concentration. The composite materials also show good mechanical properties. The average hardness is 2.5 GPa, which is about 2 times of Cu. And the average elastic modulus is 145 GPa, which is 38 % higher than that of Cu. The resistivity of the composite materials is basically equivalent to that of pure Cu. Result of the experiment proved that the composite materials have better performance under low temperature conditions. The improvement of material properties makes composite materials have good application prospects for 3D interconnection in the near future.
采用室温电镀法制备了Cu和未氧化石墨烯复合薄膜。将石墨烯加入到Cu的电解液中形成复合材料,提高Cu的互连性能。以CTAB为表面活性剂,制备了含高浓度石墨烯(高达0.5 g/L)的复合电解质。超声波也可以提高石墨烯在电解液中的分散程度,减少石墨烯的团聚。热力学分析(TMA)测定的复合膜的平均热膨胀系数(CTE)在260 ~ 320 K时从17.3 ppm/K降至14.2 ppm/K,与Cu相比降低了18%。在243 K时,复合材料的CTE可降至10 ppm/K,仅为Cu的60%。采用相敏瞬态热反射(pstr)技术测量复合材料的导热系数比385 W/m有所提高。K至468 W/m.K。复合材料的CTE和导热系数均随电流密度的增大而减小。它们都随着石墨烯浓度的增加而增加。复合材料也表现出良好的力学性能。平均硬度为2.5 GPa,约为Cu的2倍。平均弹性模量为145 GPa,比Cu的弹性模量高38%。复合材料的电阻率基本相当于纯铜的电阻率。实验结果表明,该复合材料在低温条件下具有较好的性能。材料性能的提高使得复合材料在不久的将来具有良好的三维互联应用前景。
{"title":"Preparation and Characterization of Electroplated Cu/Graphene Composite","authors":"Xin Wang, Qian Wang, Jian Cai, Changmin Song, Yang Hu, Yang Zhao, Yu Pei","doi":"10.1109/ECTC.2019.00-12","DOIUrl":"https://doi.org/10.1109/ECTC.2019.00-12","url":null,"abstract":"Cu and unoxidized graphene composite films were prepared by electroplating under room temperature. Graphene was added to the electrolyte of Cu to form composite materials to improve the performance of Cu for interconnection. Composite electrolyte containing high concentration of graphene (up to 0.5 g/L) was prepared by adding CTAB as surfactant. And ultrasound was also used to increase dispersion degree and reduce graphene agglomeration in electrolyte. Average coefficient of thermal expansion (CTE) of the composite films determined by thermo-mechanical analysis (TMA) shows a decrease from 17.3 ppm/K to 14.2 ppm/K from 260 K to 320 K, which reduce CTE by 18 % compared with Cu. CTE of the composite materials can be reduced to 10 ppm/K at 243 K, which is only 60 % of CTE of Cu. The thermal conductivity of the composite materials measured by phase sensitive transient thermo-reflectance (PSTTR) technique shows an improvement from 385 W/m.K to 468 W/m.K. CTE and thermal conductivity of the composite materials both decrease with the increase of current density. And they also both increase with the increase of graphene concentration. The composite materials also show good mechanical properties. The average hardness is 2.5 GPa, which is about 2 times of Cu. And the average elastic modulus is 145 GPa, which is 38 % higher than that of Cu. The resistivity of the composite materials is basically equivalent to that of pure Cu. Result of the experiment proved that the composite materials have better performance under low temperature conditions. The improvement of material properties makes composite materials have good application prospects for 3D interconnection in the near future.","PeriodicalId":6726,"journal":{"name":"2019 IEEE 69th Electronic Components and Technology Conference (ECTC)","volume":"8 1","pages":"2234-2239"},"PeriodicalIF":0.0,"publicationDate":"2019-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90657814","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Silver Sintering on Organic Substrates for the Embedding of Power Semiconductor Devices 用于功率半导体器件嵌入的有机衬底上的银烧结
Pub Date : 2019-05-28 DOI: 10.1109/ECTC.2019.00222
A. Schiffmacher, J. Wilde, Lorenz Litzenberger, T. Huesgen, V. Polezhaev
The requirements for power electronic assemblies are continuously increasing and are mainly driven by costs, functionality, and reliability. A novel and promising approach is the embedding of power semiconductor devices into PCB-materials. Benefits are the reduction in size and volume of the system. The embedding of semiconductor devices provides a high degree of miniaturization. Also printed circuit board technology in combination with the use of established processes apparently has the potential for low-cost manufacturing. Further functional advantages are the possibility to place passive components and peripheral circuits close to the switching devices, enabling shorter commutating paths. In consequence, they are expected to produce smaller parasitic effects caused by the package, which results in higher possible frequencies and reduced conduction and switching losses. However, there is a significant challenge regarding package design, processing, and materials selection to make use of this potential even at high operating temperatures. To address only one aspect, generally used materials, like epoxy-glass-substrates (FR4) and solder alloys like PbSnAg or SAC are not suitable for temperatures above 150 °C. This work will introduce and evaluate a concept for double-side Ag-sintered semiconductor chips, which are embedded between two organic high-temperature PCBs. A proof-of-concept will be presented by setting up a 30 kW (600 V, 50 A) power package as a demonstrator.
对电力电子组件的要求不断增加,主要是由成本、功能和可靠性驱动的。一种新颖而有前途的方法是将功率半导体器件嵌入pcb材料中。好处是减少了系统的大小和体积。半导体器件的嵌入提供了高度的小型化。此外,印刷电路板技术与现有工艺相结合,显然具有低成本制造的潜力。进一步的功能优势是可以将无源元件和外围电路放置在开关器件附近,从而实现更短的换向路径。因此,它们有望产生较小的由封装引起的寄生效应,从而导致更高的可能频率并降低传导和开关损耗。然而,在包装设计、加工和材料选择方面,即使在高工作温度下也要利用这种潜力,这是一个重大挑战。仅解决一个方面,通常使用的材料,如环氧玻璃基板(FR4)和焊料合金,如PbSnAg或SAC,不适合高于150°C的温度。这项工作将介绍和评估双面银烧结半导体芯片的概念,该芯片嵌入在两个有机高温pcb之间。概念验证将通过设置一个30千瓦(600v, 50a)的电源包作为演示。
{"title":"Silver Sintering on Organic Substrates for the Embedding of Power Semiconductor Devices","authors":"A. Schiffmacher, J. Wilde, Lorenz Litzenberger, T. Huesgen, V. Polezhaev","doi":"10.1109/ECTC.2019.00222","DOIUrl":"https://doi.org/10.1109/ECTC.2019.00222","url":null,"abstract":"The requirements for power electronic assemblies are continuously increasing and are mainly driven by costs, functionality, and reliability. A novel and promising approach is the embedding of power semiconductor devices into PCB-materials. Benefits are the reduction in size and volume of the system. The embedding of semiconductor devices provides a high degree of miniaturization. Also printed circuit board technology in combination with the use of established processes apparently has the potential for low-cost manufacturing. Further functional advantages are the possibility to place passive components and peripheral circuits close to the switching devices, enabling shorter commutating paths. In consequence, they are expected to produce smaller parasitic effects caused by the package, which results in higher possible frequencies and reduced conduction and switching losses. However, there is a significant challenge regarding package design, processing, and materials selection to make use of this potential even at high operating temperatures. To address only one aspect, generally used materials, like epoxy-glass-substrates (FR4) and solder alloys like PbSnAg or SAC are not suitable for temperatures above 150 °C. This work will introduce and evaluate a concept for double-side Ag-sintered semiconductor chips, which are embedded between two organic high-temperature PCBs. A proof-of-concept will be presented by setting up a 30 kW (600 V, 50 A) power package as a demonstrator.","PeriodicalId":6726,"journal":{"name":"2019 IEEE 69th Electronic Components and Technology Conference (ECTC)","volume":"20 1","pages":"1443-1450"},"PeriodicalIF":0.0,"publicationDate":"2019-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76496426","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Fine-Pitch (≤10 µm) Direct Cu-Cu Interconnects Using In-Situ Formic Acid Vapor Treatment 采用原位甲酸蒸气处理的细间距(≤10µm)直接Cu-Cu互连
Pub Date : 2019-05-28 DOI: 10.1109/ECTC.2019.00099
SivaChandra Jangam, A. Bajwa, U. Mogera, Pranav Ambhore, Tom Colosimo, B. Chylak, S. Iyer
We demonstrate a solderless direct copper-copper (Cu-Cu) thermal compression bonding (TCB) process for die-to-wafer assembly in ambient environment using a novel in-situ formic acid vapor treatment. We show that this approach produces excellent Cu-Cu bonds with an average shear strength of >150 MPa. Using this TCB process, we demonstrate dielet assemblies on the Silicon-Interconnect Fabric (Si-IF) platform with fine-pitch (≤ 10 µm) Cu-Cu interconnects. Further, we show electrical continuity across multiple dies on the Si-IF with an interconnect specific contact resistance of <0.7 Ω-µm2.
我们展示了一种无焊直接铜-铜(Cu-Cu)热压缩键合(TCB)工艺,用于在环境环境中使用新的原位甲酸蒸汽处理进行模到晶圆组装。我们发现这种方法产生了优异的Cu-Cu键,平均剪切强度>150 MPa。利用这种TCB工艺,我们展示了具有细间距(≤10 μ m) Cu-Cu互连的硅互连结构(Si-IF)平台上的dielet组件。此外,我们还显示了Si-IF上多个晶片的电连续性,其互连特定接触电阻<0.7 Ω-µm2。
{"title":"Fine-Pitch (≤10 µm) Direct Cu-Cu Interconnects Using In-Situ Formic Acid Vapor Treatment","authors":"SivaChandra Jangam, A. Bajwa, U. Mogera, Pranav Ambhore, Tom Colosimo, B. Chylak, S. Iyer","doi":"10.1109/ECTC.2019.00099","DOIUrl":"https://doi.org/10.1109/ECTC.2019.00099","url":null,"abstract":"We demonstrate a solderless direct copper-copper (Cu-Cu) thermal compression bonding (TCB) process for die-to-wafer assembly in ambient environment using a novel in-situ formic acid vapor treatment. We show that this approach produces excellent Cu-Cu bonds with an average shear strength of >150 MPa. Using this TCB process, we demonstrate dielet assemblies on the Silicon-Interconnect Fabric (Si-IF) platform with fine-pitch (≤ 10 µm) Cu-Cu interconnects. Further, we show electrical continuity across multiple dies on the Si-IF with an interconnect specific contact resistance of <0.7 Ω-µm2.","PeriodicalId":6726,"journal":{"name":"2019 IEEE 69th Electronic Components and Technology Conference (ECTC)","volume":"75 1","pages":"620-627"},"PeriodicalIF":0.0,"publicationDate":"2019-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86006735","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 14
3D-MiM (MUST-in-MUST) Technology for Advanced System Integration 用于先进系统集成的3D-MiM (MUST-in-MUST)技术
Pub Date : 2019-05-28 DOI: 10.1109/ECTC.2019.00008
A. Su, T. Ku, C. Tsai, K. Yee, Douglas C. H. Yu
An advanced 3D Multi-stack (MUST) system integration technology, 3D MUST-in-MUST (3D-MiM) fan out package, has been developed as next generation wafer-level fan-out package technology. 3D-MiM technology utilizes a more simplified architecture which eliminates BGAs between packages for system-level performance, power and form-factor (PPA) purpose. This technology also makes use of a modularized approach for both design and integration flow to improve design flexibility and integration efficiency. Known-good pre-stacked memory cube and/or logic-memory cubes are fabricated by leveraging the established integrated fan-out technology platform (InFO) in tools, materials, design rules, and processes to shorten development cycle time and achieve cost effectiveness. Two 3D-MiM fan-out examples are presented in this paper. The first 3D-MiM package integrates a SoC with 16 memory chips in a 15x15 mm2 footprint with 0.5 mm package height (final BGA included) for mobile application. The other 3D-MiM package integrates 8 SoCs with 32 memory chips in a 43x28 mm2 footprint to mimic a system integration of multiple logic cores and multiple memory chips for HPC applications.
作为先进的3D多堆叠(MUST)系统集成技术,3D MUST-in-MUST (3D- mim)扇出封装已被开发为下一代晶圆级扇出封装技术。3D-MiM技术采用更简化的架构,消除了封装之间的bga,以实现系统级性能、功耗和外形因素(PPA)的目的。该技术还对设计和集成流程采用模块化方法,以提高设计灵活性和集成效率。通过在工具、材料、设计规则和流程中利用已建立的集成扇出技术平台(InFO)来制造已知的预堆叠内存立方体和/或逻辑内存立方体,以缩短开发周期时间并实现成本效益。本文给出了两个3D-MiM扇出的实例。第一个3D-MiM封装集成了一个SoC和16个内存芯片,占地面积为15x15mm2,封装高度为0.5 mm(包括最终BGA),适用于移动应用。另一款3D-MiM封装集成了8个soc和32个存储芯片,占地面积为43x28mm2,模拟了HPC应用的多个逻辑核心和多个存储芯片的系统集成。
{"title":"3D-MiM (MUST-in-MUST) Technology for Advanced System Integration","authors":"A. Su, T. Ku, C. Tsai, K. Yee, Douglas C. H. Yu","doi":"10.1109/ECTC.2019.00008","DOIUrl":"https://doi.org/10.1109/ECTC.2019.00008","url":null,"abstract":"An advanced 3D Multi-stack (MUST) system integration technology, 3D MUST-in-MUST (3D-MiM) fan out package, has been developed as next generation wafer-level fan-out package technology. 3D-MiM technology utilizes a more simplified architecture which eliminates BGAs between packages for system-level performance, power and form-factor (PPA) purpose. This technology also makes use of a modularized approach for both design and integration flow to improve design flexibility and integration efficiency. Known-good pre-stacked memory cube and/or logic-memory cubes are fabricated by leveraging the established integrated fan-out technology platform (InFO) in tools, materials, design rules, and processes to shorten development cycle time and achieve cost effectiveness. Two 3D-MiM fan-out examples are presented in this paper. The first 3D-MiM package integrates a SoC with 16 memory chips in a 15x15 mm2 footprint with 0.5 mm package height (final BGA included) for mobile application. The other 3D-MiM package integrates 8 SoCs with 32 memory chips in a 43x28 mm2 footprint to mimic a system integration of multiple logic cores and multiple memory chips for HPC applications.","PeriodicalId":6726,"journal":{"name":"2019 IEEE 69th Electronic Components and Technology Conference (ECTC)","volume":"69 1","pages":"1-6"},"PeriodicalIF":0.0,"publicationDate":"2019-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86907303","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
Feasibility Study of Fan-Out Panel-Level Packaging for Heterogeneous Integrations 异质集成扇出面板级封装的可行性研究
Pub Date : 2019-05-28 DOI: 10.1109/ECTC.2019.00010
C. Ko, Henry Yang, J. Lau, Ming Li, Curry Lin, Chieh-Lin Chang, Jhih-Yuan Pan, Hsing-Hui Wu, Iris Xu, Tony Chen, Zhang Li, K. Tan, Penny Lo, R. So, Y. H. Chen, N. Fan, E. Kuah, M. Lin, Y. Cheung, Eric Ng, Cao Xi, R. Beica, S. Lim, N. Lee, Mian Tao, J. Lo, Ricky S. W. Lee
The design, materials, process, and fabrication of a heterogeneous integration of 4 chips by a FOPLP (fan-out panel-level packaging) with chip-first and dies face-down formation are investigated in this study. Emphasis is placed on the application of a new assembly process and materials for fabricating the RDLs (redistribution layers) of the FOPLP. The panel size is 508mm x 508mm. The epoxy molding compound (EMC) is a dry-film material and is molded by lamination method. The minimum metal line width and spacing is 10µm and they are fabricated by printed circuit board (PCB) method and equipment.
在本研究中,研究了采用芯片优先和模具面朝下形成的FOPLP(扇形面板级封装)的4个芯片的异构集成的设计,材料,工艺和制造。重点介绍了一种新的组装工艺和材料的应用,用于制造FOPLP的再分布层。面板尺寸为508mm × 508mm。环氧成型复合材料(EMC)是一种干膜材料,采用层压成型。金属线宽度和间距最小为10µm,采用PCB (printed circuit board)方法和设备制作。
{"title":"Feasibility Study of Fan-Out Panel-Level Packaging for Heterogeneous Integrations","authors":"C. Ko, Henry Yang, J. Lau, Ming Li, Curry Lin, Chieh-Lin Chang, Jhih-Yuan Pan, Hsing-Hui Wu, Iris Xu, Tony Chen, Zhang Li, K. Tan, Penny Lo, R. So, Y. H. Chen, N. Fan, E. Kuah, M. Lin, Y. Cheung, Eric Ng, Cao Xi, R. Beica, S. Lim, N. Lee, Mian Tao, J. Lo, Ricky S. W. Lee","doi":"10.1109/ECTC.2019.00010","DOIUrl":"https://doi.org/10.1109/ECTC.2019.00010","url":null,"abstract":"The design, materials, process, and fabrication of a heterogeneous integration of 4 chips by a FOPLP (fan-out panel-level packaging) with chip-first and dies face-down formation are investigated in this study. Emphasis is placed on the application of a new assembly process and materials for fabricating the RDLs (redistribution layers) of the FOPLP. The panel size is 508mm x 508mm. The epoxy molding compound (EMC) is a dry-film material and is molded by lamination method. The minimum metal line width and spacing is 10µm and they are fabricated by printed circuit board (PCB) method and equipment.","PeriodicalId":6726,"journal":{"name":"2019 IEEE 69th Electronic Components and Technology Conference (ECTC)","volume":"16 1","pages":"14-20"},"PeriodicalIF":0.0,"publicationDate":"2019-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87302634","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Reliability Investigation of Extremely Large Ratio Fan-Out Wafer-Level Package with Low Ball Density for Ultra-Short-Range Radar 超近距离雷达用超低球密度超大比扇出片级封装可靠性研究
Pub Date : 2019-05-28 DOI: 10.1109/ECTC.2019.00081
P.S. Huang, C.K. Yu, W. S. Chiang, M. Z. Lin, Y.H. Fang, M. J. Lin, N. Liu, B. Lin, I. Hsu
Driven by aggressive development of electronic products with high robustness demand for automotive application to endure severe usage environment, both component-level and board-level reliabilities have to be concerned more for safety assurance. In this paper, a system-on-chip millimeter-wave ultra-short range radar (mmWave USRR) realized in complementary metal-oxide-semiconductor (CMOS) technology and assembled with fan-out wafer level packaging (FOWLP) technology was introduced, and the board-level reliability (BLR) was studied experimentally on the risk of chip-to-board interaction (CBI). The factors of solder ball material, package thickness and underfill material, thought to dominate on CBI performance, were studied experimentally. First of all, two solder materials were studied to evaluate their capabilities for this FOWLP to against board level thermal cycling and drop tests. It was found that the solder with higher elastic modulus performed much better on board-level thermal cycling (BLTC) reliability. Moreover, no difference was found in board level drop test since no failure occurred in both solder materials. Both package thicknesses of 425 µm and 580 µm were studied on the board level reliabilities, and the results revealed that the design with both thicker Si die and thicker molding material significantly improved the BLTC reliability. Both epoxy-based materials - one is low-CTE underfill material and the other is edge-bond glue, were applied to know the workability of enhancing the BLTC performance on the FOWLP. The experiment results showed that both the epoxy materials miserably decreased the BLTC performance, and severe solder crack and bulk underfill crack were found. Since vibration test is indispensable and of much concern for automotive electronics, the stringent test condition of sine-wave frequency swept from 20 Hz to 2,000 Hz and peak acceleration of either 50g or 20g, was applied to evaluate anti-vibration property of the FOWLP mTV mounted on daisy-chain PCB. From the results of 50g peak acceleration vibration test, high resistance was found in the specific daisy-chain loop which electrically connects corner solder balls. From the failure analysis it could be found that delamination existed at the interface of redistribution layer (RDL) and under-bump metallization (UBM) of component side and PCB Cu trace crack. It is noteworthy that all the failures only happened on the package located at the 5x3 array corner while subjecting to Z-axis vibration. From experience, poorly fixing the PCB on vibration platform potentially causes more bending stain on PCB during Z-direction vibration and further concentrates much higher stress singularly nearby the corner. Moreover, the board-level vibration test with 20g peak acceleration was also implemented, and there wasn't any failure found. Finally, the BLR was thoroughly studied for the extremely large area-ratio FOWLP, and the package was proved its capability of meeting AEC-Q100 compl
随着汽车应用对电子产品的高稳健性要求的迅猛发展,元器件级和电路板级的可靠性都必须更加关注安全保障。本文介绍了一种采用互补金属氧化物半导体(CMOS)技术实现并采用扇出晶圆级封装(FOWLP)技术组装的系统级毫米波超短距离雷达(mmWave USRR),并通过实验研究了芯片-板相互作用(CBI)风险下的板级可靠性(BLR)。实验研究了影响CBI性能的主要因素焊球材料、封装厚度和衬底材料。首先,研究了两种焊料材料,以评估它们在该FOWLP中抗板级热循环和跌落测试的能力。结果表明,弹性模量较高的焊料在板级热循环(BLTC)可靠性方面表现较好。此外,由于两种焊料材料均未发生故障,因此在电路板水平跌落测试中没有发现差异。对425µm和580µm封装厚度在板级可靠性上进行了研究,结果表明,采用更厚的Si模和更厚的成型材料的设计显著提高了BLTC的可靠性。采用低cte底填材料和边粘胶两种环氧基材料,研究了在FOWLP上提高BLTC性能的可加工性。实验结果表明,两种环氧材料均显著降低了BLTC的性能,并出现了严重的焊料裂纹和大块底填裂纹。由于振动测试在汽车电子产品中是必不可少的,也是备受关注的,因此采用正弦波扫描频率从20 Hz到2000 Hz,峰值加速度为50g或20g的严格测试条件,对安装在菊链PCB上的FOWLP mTV的抗振动性能进行了评估。从50g峰值加速度振动试验结果来看,在连接角焊料球的特定菊花链回路中发现了高电阻。从失效分析中可以发现,在元件侧重分布层(RDL)和凹凸下金属化层(UBM)的界面和PCB板的铜迹裂纹处存在分层现象。值得注意的是,在z轴振动作用下,所有的失效只发生在位于5x3阵列角的封装上。从经验来看,在振动平台上固定不良的PCB可能会在z方向振动期间导致PCB上更多的弯曲污渍,并进一步在拐角附近集中更高的应力。此外,还进行了20g峰值加速度的板级振动测试,未发现任何故障。最后,对超大面积比FOWLP的BLR进行了深入研究,证明了该封装能够满足AEC-Q100的严格可靠性测试要求。
{"title":"Reliability Investigation of Extremely Large Ratio Fan-Out Wafer-Level Package with Low Ball Density for Ultra-Short-Range Radar","authors":"P.S. Huang, C.K. Yu, W. S. Chiang, M. Z. Lin, Y.H. Fang, M. J. Lin, N. Liu, B. Lin, I. Hsu","doi":"10.1109/ECTC.2019.00081","DOIUrl":"https://doi.org/10.1109/ECTC.2019.00081","url":null,"abstract":"Driven by aggressive development of electronic products with high robustness demand for automotive application to endure severe usage environment, both component-level and board-level reliabilities have to be concerned more for safety assurance. In this paper, a system-on-chip millimeter-wave ultra-short range radar (mmWave USRR) realized in complementary metal-oxide-semiconductor (CMOS) technology and assembled with fan-out wafer level packaging (FOWLP) technology was introduced, and the board-level reliability (BLR) was studied experimentally on the risk of chip-to-board interaction (CBI). The factors of solder ball material, package thickness and underfill material, thought to dominate on CBI performance, were studied experimentally. First of all, two solder materials were studied to evaluate their capabilities for this FOWLP to against board level thermal cycling and drop tests. It was found that the solder with higher elastic modulus performed much better on board-level thermal cycling (BLTC) reliability. Moreover, no difference was found in board level drop test since no failure occurred in both solder materials. Both package thicknesses of 425 µm and 580 µm were studied on the board level reliabilities, and the results revealed that the design with both thicker Si die and thicker molding material significantly improved the BLTC reliability. Both epoxy-based materials - one is low-CTE underfill material and the other is edge-bond glue, were applied to know the workability of enhancing the BLTC performance on the FOWLP. The experiment results showed that both the epoxy materials miserably decreased the BLTC performance, and severe solder crack and bulk underfill crack were found. Since vibration test is indispensable and of much concern for automotive electronics, the stringent test condition of sine-wave frequency swept from 20 Hz to 2,000 Hz and peak acceleration of either 50g or 20g, was applied to evaluate anti-vibration property of the FOWLP mTV mounted on daisy-chain PCB. From the results of 50g peak acceleration vibration test, high resistance was found in the specific daisy-chain loop which electrically connects corner solder balls. From the failure analysis it could be found that delamination existed at the interface of redistribution layer (RDL) and under-bump metallization (UBM) of component side and PCB Cu trace crack. It is noteworthy that all the failures only happened on the package located at the 5x3 array corner while subjecting to Z-axis vibration. From experience, poorly fixing the PCB on vibration platform potentially causes more bending stain on PCB during Z-direction vibration and further concentrates much higher stress singularly nearby the corner. Moreover, the board-level vibration test with 20g peak acceleration was also implemented, and there wasn't any failure found. Finally, the BLR was thoroughly studied for the extremely large area-ratio FOWLP, and the package was proved its capability of meeting AEC-Q100 compl","PeriodicalId":6726,"journal":{"name":"2019 IEEE 69th Electronic Components and Technology Conference (ECTC)","volume":"25 1","pages":"493-497"},"PeriodicalIF":0.0,"publicationDate":"2019-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87516626","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
A New Development of Direct Bonding to Aluminum and Nickel Surfaces by Silver Sintering in air Atmosphere 空气气氛下银烧结与铝、镍表面直接结合的新进展
Pub Date : 2019-05-28 DOI: 10.1109/ECTC.2019.00021
Ly May Chew, Tamira Stegmann, Erika Schwenk, M. Dubis, W. Schmitt
Owing to the superb properties of silver such as high melting temperature, high thermal and electrical conductivity, low temperature silver sinter technology has attracted growing attention in recent years especially for the applications required high power and high operating temperature. Current silver sinter technology required plating of precious metal finishing on the substrates prior to sintering process in order to form a strong sinter joint. Direct bonding on non-precious metal surfaces by silver sintering is therefore of great interest, since the precious metal finishing on substrate is no longer necessary, which will lead to the reduction of manufacturing cost. This paper explores the development of a safe-to-use micro-silver sinter paste for pressure sintering on aluminum and nickel surfaces. In this study, Ag metallized Si dies were attached on nickel-plated direct copper bonding substrates and high purity aluminum plates by silver sintering process at 250 °C with a pressure of 10 MPa for 3 min in air atmosphere. The cross-sectional SEM images of sintered samples indicate that a dense sintered layer was formed on Ni and Al surface. After die shear test, SEM-EDX was conducted on the fracture surface of Ni and Al substrates and the results confirmed that silver sintered joint was created on Ni and Al surface. The EDX analysis results further illustrate an interdiffusion of Ag/Ni and Ag/Al occurred at the interface located between sintered layer and substrates. High bonding strength of silver sintered joint was created on Ni and Al surfaces and the average die shear strength remained above 30 N/mm² after 500 h storage at 250 °C. Cohesive break in the sintered layer was obtained for both Ni and Al samples before and after high temperature storage where silver sintered layer can be found on both the die backside and the substrate surface indicating that good adhesion on Ni and Al surfaces was achieved with the newly developed silver sinter paste.
由于银具有高熔点、高导热性和高导电性等优良性能,低温银烧结技术近年来受到越来越多的关注,特别是在需要高功率和高工作温度的应用领域。目前的银烧结技术需要在烧结过程之前在衬底上镀上贵金属精加工,以形成牢固的烧结接头。因此,通过银烧结在非贵金属表面上直接结合是非常有趣的,因为不再需要在基材上进行贵金属精加工,这将导致制造成本的降低。本文研究了一种用于铝和镍表面压力烧结的安全使用的微银烧结膏体的开发。本研究采用银烧结工艺,在250℃、10 MPa、3 min的空气环境下,将银金属化的Si模具附着在镀镍直接铜键合基板和高纯铝板上。烧结试样的SEM横截面图表明,在Ni和Al表面形成了致密的烧结层。经过模剪试验,对Ni和Al基体断口进行SEM-EDX扫描,结果证实在Ni和Al表面形成了银烧结接头。EDX分析结果进一步表明,Ag/Ni和Ag/Al在烧结层与衬底之间的界面处发生了相互扩散。在250℃下保存500 h后,银烧结接头在Ni和Al表面形成了较高的结合强度,平均模抗剪强度保持在30 N/mm²以上。高温储存前后,Ni和Al样品的烧结层均出现了内聚断裂,在模具背面和衬底表面均出现了银烧结层,表明新制备的银烧结浆料在Ni和Al表面均取得了良好的附着力。
{"title":"A New Development of Direct Bonding to Aluminum and Nickel Surfaces by Silver Sintering in air Atmosphere","authors":"Ly May Chew, Tamira Stegmann, Erika Schwenk, M. Dubis, W. Schmitt","doi":"10.1109/ECTC.2019.00021","DOIUrl":"https://doi.org/10.1109/ECTC.2019.00021","url":null,"abstract":"Owing to the superb properties of silver such as high melting temperature, high thermal and electrical conductivity, low temperature silver sinter technology has attracted growing attention in recent years especially for the applications required high power and high operating temperature. Current silver sinter technology required plating of precious metal finishing on the substrates prior to sintering process in order to form a strong sinter joint. Direct bonding on non-precious metal surfaces by silver sintering is therefore of great interest, since the precious metal finishing on substrate is no longer necessary, which will lead to the reduction of manufacturing cost. This paper explores the development of a safe-to-use micro-silver sinter paste for pressure sintering on aluminum and nickel surfaces. In this study, Ag metallized Si dies were attached on nickel-plated direct copper bonding substrates and high purity aluminum plates by silver sintering process at 250 °C with a pressure of 10 MPa for 3 min in air atmosphere. The cross-sectional SEM images of sintered samples indicate that a dense sintered layer was formed on Ni and Al surface. After die shear test, SEM-EDX was conducted on the fracture surface of Ni and Al substrates and the results confirmed that silver sintered joint was created on Ni and Al surface. The EDX analysis results further illustrate an interdiffusion of Ag/Ni and Ag/Al occurred at the interface located between sintered layer and substrates. High bonding strength of silver sintered joint was created on Ni and Al surfaces and the average die shear strength remained above 30 N/mm² after 500 h storage at 250 °C. Cohesive break in the sintered layer was obtained for both Ni and Al samples before and after high temperature storage where silver sintered layer can be found on both the die backside and the substrate surface indicating that good adhesion on Ni and Al surfaces was achieved with the newly developed silver sinter paste.","PeriodicalId":6726,"journal":{"name":"2019 IEEE 69th Electronic Components and Technology Conference (ECTC)","volume":"19 1","pages":"87-93"},"PeriodicalIF":0.0,"publicationDate":"2019-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72847118","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Novel Solder Pads for Self-Aligned Flip-Chip Assembly 用于自对准倒装芯片组装的新型焊盘
Pub Date : 2019-05-28 DOI: 10.1109/ECTC.2019.00086
Y. Martin, S. Kamlapurkar, N. Marchack, J. Nah, T. Barwicz
Self-alignment via solder-surface tension in flip-chip bonding opens the door to low-cost, high-throughput assembly of components with sub-micron accuracy. This is especially impactful to integrated photonics as used for high speed optical communication and sensors [1,2]. Assembly yield hinges on the details of solder-induced forces and on the geometry of the melted solder surface. Low curvature of melted solder is best to balance solder forces for optimal re-alignment yield but leads to shallow contact angles and solder de-wetting on traditional solder pads. We introduce and demonstrate the concept of recessed solder pads with shallow angled edges. Such geometry enables arbitrarily-low curvature of the molten solder surface and even flat or slightly concave shapes. The solder stays anchored at the angled edges of recessed pads and can be made to flow in long and narrow conduits. Both aspects are key to widening the fabrication and process window for the solder-induced chip-alignment technology.
在倒装芯片键合中,通过焊料表面张力进行自对准,为低成本、高通量、亚微米精度的组件组装打开了大门。这对用于高速光通信和传感器的集成光子学尤其有影响[1,2]。组装成品率取决于焊料诱导力的细节和熔化焊料表面的几何形状。低曲率的熔化焊料是最好的平衡焊料力,以获得最佳的重新对准产量,但导致浅接触角和焊料脱湿的传统焊盘。我们介绍并演示了具有浅角度边缘的嵌入式焊盘的概念。这样的几何形状使得熔融焊料表面的曲率任意低,甚至平坦或微凹的形状。焊料固定在凹焊盘的倾斜边缘,可以使其在长而窄的管道中流动。这两个方面是扩大焊点诱导芯片对准技术的制造和工艺窗口的关键。
{"title":"Novel Solder Pads for Self-Aligned Flip-Chip Assembly","authors":"Y. Martin, S. Kamlapurkar, N. Marchack, J. Nah, T. Barwicz","doi":"10.1109/ECTC.2019.00086","DOIUrl":"https://doi.org/10.1109/ECTC.2019.00086","url":null,"abstract":"Self-alignment via solder-surface tension in flip-chip bonding opens the door to low-cost, high-throughput assembly of components with sub-micron accuracy. This is especially impactful to integrated photonics as used for high speed optical communication and sensors [1,2]. Assembly yield hinges on the details of solder-induced forces and on the geometry of the melted solder surface. Low curvature of melted solder is best to balance solder forces for optimal re-alignment yield but leads to shallow contact angles and solder de-wetting on traditional solder pads. We introduce and demonstrate the concept of recessed solder pads with shallow angled edges. Such geometry enables arbitrarily-low curvature of the molten solder surface and even flat or slightly concave shapes. The solder stays anchored at the angled edges of recessed pads and can be made to flow in long and narrow conduits. Both aspects are key to widening the fabrication and process window for the solder-induced chip-alignment technology.","PeriodicalId":6726,"journal":{"name":"2019 IEEE 69th Electronic Components and Technology Conference (ECTC)","volume":"78 1","pages":"528-534"},"PeriodicalIF":0.0,"publicationDate":"2019-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81185074","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Active Through-Silicon Interposer Based 2.5D IC Design, Fabrication, Assembly and Test 基于有源通硅中间体的2.5D集成电路设计、制造、组装和测试
Pub Date : 2019-05-28 DOI: 10.1109/ECTC.2019.00094
J. Jayabalan, V. C. Nachiappan, Sharon Lim Pei Siang, Wang Xiangyu, Jong Ming Chinq, S. Bhattacharya
Active Through-Silicon Interposer (ATSI) based 2.5D/3D IC packaging is a solution to extend Moore's law beyond the limitations inherent in 2D packages. We present the implementation of an ATSI platform for providing Analog to Digital converter (ADC), Digital to Analog converter (DAC) and embedded Power Management Unit (ePMU) functions to support high performance logic, fabrication of 140 micron pitch Via-Last Through-Silicon Via (TSV) of 40 micron height, assembly of Chip-on-Chip-on Substrate, functional test and reliability assessment. The active interposer fabricated in 130nm CMOS easily supports the I/O, Analog, Electro Static Discharge (ESD), De-cap functions with via-last TSV. This approach enables significant die-size reduction of the top die (usually in expensive 16nm CMOS or below tech. node) to achieve system miniaturization and cost reduction
基于有源通硅中间体(ATSI)的2.5D/3D IC封装是一种扩展摩尔定律的解决方案,超越了2D封装固有的限制。我们提出了一个ATSI平台的实现,提供模数转换器(ADC),数模转换器(DAC)和嵌入式电源管理单元(ePMU)功能,以支持高性能逻辑,制造140微米间距的40微米高度的通硅通孔(TSV),片上片基板组装,功能测试和可靠性评估。采用130nm CMOS制造的有源中间体可轻松支持I/O、模拟、静电放电(ESD)、De-cap等功能。这种方法可以显著减小顶晶片(通常采用昂贵的16nm CMOS或以下技术节点)的晶片尺寸,从而实现系统小型化和降低成本
{"title":"Active Through-Silicon Interposer Based 2.5D IC Design, Fabrication, Assembly and Test","authors":"J. Jayabalan, V. C. Nachiappan, Sharon Lim Pei Siang, Wang Xiangyu, Jong Ming Chinq, S. Bhattacharya","doi":"10.1109/ECTC.2019.00094","DOIUrl":"https://doi.org/10.1109/ECTC.2019.00094","url":null,"abstract":"Active Through-Silicon Interposer (ATSI) based 2.5D/3D IC packaging is a solution to extend Moore's law beyond the limitations inherent in 2D packages. We present the implementation of an ATSI platform for providing Analog to Digital converter (ADC), Digital to Analog converter (DAC) and embedded Power Management Unit (ePMU) functions to support high performance logic, fabrication of 140 micron pitch Via-Last Through-Silicon Via (TSV) of 40 micron height, assembly of Chip-on-Chip-on Substrate, functional test and reliability assessment. The active interposer fabricated in 130nm CMOS easily supports the I/O, Analog, Electro Static Discharge (ESD), De-cap functions with via-last TSV. This approach enables significant die-size reduction of the top die (usually in expensive 16nm CMOS or below tech. node) to achieve system miniaturization and cost reduction","PeriodicalId":6726,"journal":{"name":"2019 IEEE 69th Electronic Components and Technology Conference (ECTC)","volume":"108 1","pages":"587-593"},"PeriodicalIF":0.0,"publicationDate":"2019-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81624474","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 9
Low Temperature Cu Interconnect with Chip to Wafer Hybrid Bonding 低温铜互连与晶片混合键合
Pub Date : 2019-05-28 DOI: 10.1109/ECTC.2019.00100
Guilian Gao, L. Mirkarimi, Thomas Workman, G. Fountain, J. Theil, Gabe Guevara, Ping Liu, Bongsub Lee, P. Mrozek, M. Huynh, C. Rudolph, T. Werner, A. Hanisch
Current DRAM advanced chip stack packages such as the high bandwidth memory (HBM) use throughsilicon-via (TSV) and thermal compression bonding (TCB) of solder capped micro bumps for the inter-layer connection. The bonding process has low throughput and cannot overcome the challenge of scaling below 40 µm pitch. These are compelling reasons to seek an alternative approach such as hybrid bonding. The pursuit of fine pitch die stacking with TSV interconnect using hybrid bonding is pervasive in the packaging industry today due to the promise of improved performance. Specifically, the Cu interconnect provides improved thermal and electrical performance and the all inorganic interface of the complete die stack offers enhanced thermal-mechanical performance and reliability in the final chip stack. Direct Bond Interconnect technology, also known as low temperature hybrid bonding, forms a spontaneous dielectric-to-dielectric bond at room temperature and then establishes metal-to-metal connection (usually Cu-to-Cu bond) by a low temperature batch annealing process (150 – 300°C). The direct bond process eliminates the need for solder and underfill and associated problems. While the hybrid bonding exists today in wafer-towafer (W2W) format in high volume manufacturing, chip to wafer (C2W) bonding developed for future product lines is making significant process in the past three years. A bonding process with high throughput has been demonstrated with electrical test yield above 90% with a daisy chain structure that covers 50mm^2 of bonding area. The bonded parts showed superior reliability performance in temperature cycling, high temperature storage and autoclave testing. This paper presents the latest development in C2W hybrid bonding and demonstrates the low temperature annealing capability and integration with TSV.
目前的DRAM先进芯片堆栈封装,如高带宽存储器(HBM),采用通硅通孔(TSV)和热压缩键合(TCB)的焊料覆盖微凸点进行层间连接。该键合工艺的吞吐量较低,无法克服40 μ m间距以下的缩放挑战。这些都是寻求混合键等替代方法的令人信服的理由。由于提高性能的承诺,使用混合键合的TSV互连追求细间距芯片堆叠在今天的封装行业中是普遍存在的。具体来说,Cu互连提供了改进的热学和电学性能,并且整个芯片堆栈的所有无机接口提供了增强的热机械性能和最终芯片堆栈的可靠性。Direct Bond Interconnect技术,又称低温杂化键合(low temperature hybrid bonding),在室温下形成自发的介电-介电键,然后通过低温批量退火工艺(150 - 300℃)建立金属-金属连接(通常为cu - cu键)。直接粘合工艺消除了焊料和下填充以及相关问题的需要。虽然目前在大批量生产中以晶圆-晶圆(W2W)形式存在混合键合,但为未来产品线开发的芯片到晶圆(C2W)键合在过去三年中取得了重大进展。在覆盖50mm^2粘接面积的菊花链结构下,证明了一种高通量的粘接工艺,电测试良率在90%以上。结合件在温度循环、高温储存和高压灭菌试验中表现出优异的可靠性。本文介绍了C2W杂化键合的最新进展,并展示了低温退火性能和与TSV的集成。
{"title":"Low Temperature Cu Interconnect with Chip to Wafer Hybrid Bonding","authors":"Guilian Gao, L. Mirkarimi, Thomas Workman, G. Fountain, J. Theil, Gabe Guevara, Ping Liu, Bongsub Lee, P. Mrozek, M. Huynh, C. Rudolph, T. Werner, A. Hanisch","doi":"10.1109/ECTC.2019.00100","DOIUrl":"https://doi.org/10.1109/ECTC.2019.00100","url":null,"abstract":"Current DRAM advanced chip stack packages such as the high bandwidth memory (HBM) use throughsilicon-via (TSV) and thermal compression bonding (TCB) of solder capped micro bumps for the inter-layer connection. The bonding process has low throughput and cannot overcome the challenge of scaling below 40 µm pitch. These are compelling reasons to seek an alternative approach such as hybrid bonding. The pursuit of fine pitch die stacking with TSV interconnect using hybrid bonding is pervasive in the packaging industry today due to the promise of improved performance. Specifically, the Cu interconnect provides improved thermal and electrical performance and the all inorganic interface of the complete die stack offers enhanced thermal-mechanical performance and reliability in the final chip stack. Direct Bond Interconnect technology, also known as low temperature hybrid bonding, forms a spontaneous dielectric-to-dielectric bond at room temperature and then establishes metal-to-metal connection (usually Cu-to-Cu bond) by a low temperature batch annealing process (150 – 300°C). The direct bond process eliminates the need for solder and underfill and associated problems. While the hybrid bonding exists today in wafer-towafer (W2W) format in high volume manufacturing, chip to wafer (C2W) bonding developed for future product lines is making significant process in the past three years. A bonding process with high throughput has been demonstrated with electrical test yield above 90% with a daisy chain structure that covers 50mm^2 of bonding area. The bonded parts showed superior reliability performance in temperature cycling, high temperature storage and autoclave testing. This paper presents the latest development in C2W hybrid bonding and demonstrates the low temperature annealing capability and integration with TSV.","PeriodicalId":6726,"journal":{"name":"2019 IEEE 69th Electronic Components and Technology Conference (ECTC)","volume":"61 1","pages":"628-635"},"PeriodicalIF":0.0,"publicationDate":"2019-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91100824","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 22
期刊
2019 IEEE 69th Electronic Components and Technology Conference (ECTC)
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1