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High-on/off ratio organic photodetectors via incorporating Kaolinite 通过加入高岭石实现高开关比有机光电探测器
Pub Date : 2024-06-15 DOI: 10.1016/j.micrna.2024.207914
Jinghui Li , Zhenbo Chen , Xuan Yu , Xiaoming Yu , Qian Qiao , Hai Zhang , Zhenhua Li , Yingtang Zhou

Organic photodetectors (OPDs) have received wide attention for the weak-light signals sensitivity and promising application in imaging, and optical communication. While limited light absorption due to low carrier mobility of organic active layer. ZnO nanorods (NRs) possesses excellent photoelectric and light-trapping properties have been used in OPDs. Herein, for the first time, ZnO NRs were hydrothermal synthesized based on Kaolinite-ZnO (KAZN) seed layer. Kaolinite is a natural substance that originates from layered silicate minerals, possess unique crystal chemical properties. The KAZN NRs exhibits a smaller grain size, enhanced crystallinity and significantly enhanced light-scattering (average Haze increased 36 % from 300 to 800 nm) compared with ZnO NRs. Meanwhile, KAZN NRs have a narrower band gap, leading to superior photoelectric emission. The resulting KAZN NRs OPDs showed an enhancement in responsivity (Rs) by 44 % and achieved an impressively high On/Off ratio (18,744), representing a remarkable increase of 1800 %@ 440 nm. The noise equivalent power (NEP) has decreased by an order of magnitude at full test band. The significant improvement can be attributed to the introduction of Kaolinite, which alters the NRs crystal structure and effectively reduces OPDs dark current while enhancing photocurrent. Our research provides a simple and cost-effective approach for improving light-scattering characteristics and optoelectronic performance for ZnO based-photovoltaic devices.

有机光电探测器(OPD)因其对微弱光信号的灵敏度以及在成像和光通信领域的应用前景而受到广泛关注。由于有机活性层的载流子迁移率较低,因此对光的吸收有限。ZnO 纳米棒(NRs)具有优异的光电和光捕获特性,已被用于 OPD。本文首次基于高岭石-氧化锌(KAZN)种子层水热合成了氧化锌纳米棒。高岭石是一种源自层状硅酸盐矿物的天然物质,具有独特的晶体化学性质。与 ZnO NRs 相比,KAZN NRs 的晶粒尺寸更小,结晶度更高,光散射能力明显增强(从 300 纳米到 800 纳米,平均雾度增加了 36%)。同时,KAZN NRs 的带隙更窄,因此光电发射性能更佳。由此产生的 KAZN NRs OPD 的响应率(Rs)提高了 44%,实现了令人印象深刻的高通断比(18,744),在 440 纳米波长处显著提高了 1800%。在整个测试波段,噪声等效功率(NEP)降低了一个数量级。这一重大改进可归功于高岭石的引入,它改变了 NRs 晶体结构,在增强光电流的同时有效降低了 OPD 的暗电流。我们的研究为改善基于氧化锌的光电器件的光散射特性和光电性能提供了一种简单而经济有效的方法。
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引用次数: 0
Band gap shifting of halide perovskite KSrCl3 from ultra-violet to visible region under pressure for photovoltaic applications 在压力作用下,卤化物过氧化物 KSrCl3 的带隙从紫外区转移到可见光区,用于光伏应用
Pub Date : 2024-06-14 DOI: 10.1016/j.micrna.2024.207911
Z. Jellil , A. Idrissi el oudrhiri , H. Jebari , A. Soussi , Mohamed Eddekkar , Ilyass Ez-zejjari , H. Ez-Zahraouy

This research delves into the influence of hydrostatic pressure on the structural, electronic, and optical characteristics of the cubic halide perovskite KSrCl3. The reduction in interatomic distance caused by pressure has a considerable effect on the unit cell volume and lattice constant of this perovskite. As pressure increases, the electronic band gap closes, transferring from the ultraviolet to the visible spectrum. This phenomenon increases the efficiency of optoelectronic devices by simplifying the transition of electrons from the valence band to the conduction band. In addition, the material becomes more appropriate for use in a variety of optoelectronic applications when the band gap changes from indirect to direct at pressures of about 50 GPa. A comprehensive optical analysis suggests that KSrCl3 holds potential applications in surgical tools, integrated circuits, QLED, OLED, solar cells, waveguides, and materials designed for solar heat reduction. The tolerance factor “t" confirms the stability of the KSrCl3 phase across the applied pressure range, and the formation energy values with negative values show the attained thermodynamic stability.

本研究深入探讨了静水压力对立方卤化物包晶 KSrCl3 的结构、电子和光学特性的影响。压力造成的原子间距离的减小对这种包晶的单胞体积和晶格常数有相当大的影响。随着压力的增加,电子带隙会缩小,从紫外光谱转移到可见光谱。这一现象简化了电子从价带到导带的转变过程,从而提高了光电设备的效率。此外,当带隙在大约 50 GPa 的压力下从间接带隙变为直接带隙时,这种材料更适合用于各种光电应用。全面的光学分析表明,KSrCl3 在外科手术工具、集成电路、QLED、OLED、太阳能电池、波导和用于减少太阳热量的材料中都有潜在的应用。公差系数 "t "证实了 KSrCl3 相在整个应用压力范围内的稳定性,而负值的形成能值则表明其达到了热力学稳定性。
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引用次数: 0
Impact of self-heating on geometric variations in nano-ribbon FET: Analog/RF perspective 自热对纳米带状 FET 几何变化的影响:模拟/射频视角
Pub Date : 2024-06-13 DOI: 10.1016/j.micrna.2024.207908
Dheeraj Kumar , Rashi Chaudhary , Rajendra Mitharwal , Brinda Bhowmick , Rajesh Saha

In recent technology, Nano Ribbon FET (NR-FET) is an emerging device due to its enhanced effective width than other FET devices. In this paper, the electrical parameters including self-heating effect (SHE) for NRFET is presented. The drain current (ID), transconductance (gm), transconductance generation factor (TGF = gm/ID), and cut-off frequency (fc) are highlighted in NRFET with/without considering SHE. It is observed that various electrical parameters are degraded by significant amount in the presence of SHE for NR-FET. The gm is changed from 1.45 to 0.725 mS in presence of SHE, whereas, fc is reduced to 2.47 THz from 4.5 THz in presence of SHE for NRFET. Further, the effect of variation in width and height of ribbon in NRFET on e-density, drain current, and transconductance are reported with/without including SHE. Result reveals that with increased width/height, the performance of NRFET is enhanced and this is further degraded with including SHE. Finally, the important parameters like lattice temperature and thermal resistance (Rth) are calculated for NRFET. The calculated lattice temperature and Rth are 375.2 K and 1.534 K/μWatt, respectively.

在最新技术中,纳米带状场效应晶体管(NR-FET)是一种新兴器件,因为它的有效宽度比其他场效应晶体管器件更大。本文介绍了 NRFET 的电气参数,包括自热效应(SHE)。重点介绍了考虑/不考虑 SHE 的 NRFET 的漏极电流 (ID)、跨导 (gm)、跨导产生系数 (TGF = gm/ID) 和截止频率 (fc)。结果表明,在存在 SHE 的 NR-FET 中,各种电气参数都有显著下降。存在 SHE 时,gm 从 1.45 mS 下降到 0.725 mS,而存在 SHE 时,NRFET 的 fc 从 4.5 THz 下降到 2.47 THz。此外,还报告了 NRFET 中色带宽度和高度的变化对电子密度、漏极电流和跨导的影响,其中包括/不包括 SHE。结果表明,随着宽度/高度的增加,NRFET 的性能得到提高,而加入 SHE 后,性能进一步降低。最后,计算了 NRFET 的晶格温度和热阻 (Rth) 等重要参数。计算得出的晶格温度和 Rth 分别为 375.2 K 和 1.534 K/μW。
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引用次数: 0
Impact of varying channel length on Analog/RF performances in a novel n-type silicon-based DG-JLT 不同通道长度对新型 n 型硅基 DG-JLT 模拟/射频性能的影响
Pub Date : 2024-06-13 DOI: 10.1016/j.micrna.2024.207913
Rohan Ghosh, Shriyans Roy, Ayush Kashyap, Atanu Kundu

Shrinking MOSFETs suffer performance hits due to short-channel effects and leakage. Junctionless transistors JLTs emerge as promising alternatives due to simpler fabrication and better gate control. This paper investigates the analog and RF performance characteristics of n-type Silicon-Based Double Gate Junctionless Transistors with varying channel lengths (15 nm, 20 nm, and 25 nm) This study evaluates analog device performance through critical parameters: drain current density (Id), transconductance (gm), output resistance (RO), intrinsic gain (gmRO), and transconductance generation factor (gm/Id). These parameters assess current handling, gain characteristics, and design efficiency, providing a comprehensive analysis for analog circuit applications. Results indicate that the device having 15 nm channel length exhibits a transconductance which is 25.38 % more than the 20 nm variant and drain current which is 44.7 % more than the latter, suggesting its superior performance to devices with longer channel lengths. In addition, the RF performance of the devices is evaluated using the small signal model of the device. This work further investigates the high-frequency response of the devices using key figures of merit (FoMs): gate capacitances (Cgs, Cgd, Cgg), cut-off frequency (fT), and maximum oscillation frequency (fMAX). These parameters quantify the influence of parasitic capacitances on switching speed and the maximum useable frequency for analog and RF applications. Analyzing Cgs, Cgd, and Cgg reveals the impact of gate control on high-frequency operation. The device having 15 nm channel length, exhibits an increase of 47.29 % in fT and 68.97 % increase in fMAX compared to device having 20 nm channel length. The findings underscore the significance of channel length optimization in enhancing the Analog and RF performance of n-type Silicon-based Double Gate Junctionless Transistors.

由于短沟道效应和漏电,不断缩小的 MOSFET 性能受到影响。无结晶体管 JLT 因其更简单的制造工艺和更好的栅极控制而成为有前途的替代品。本文研究了具有不同沟道长度(15 nm、20 nm 和 25 nm)的 n 型硅基双栅无结晶体管的模拟和射频性能特性。这项研究通过漏极电流密度 (Id)、跨导 (gm)、输出电阻 (RO)、本征增益 (gmRO) 和跨导生成因子 (gm/Id) 等关键参数来评估模拟器件的性能。这些参数评估了电流处理、增益特性和设计效率,为模拟电路应用提供了全面的分析。结果表明,沟道长度为 15 nm 的器件的跨导比 20 nm 的器件高 25.38%,漏极电流比后者高 44.7%,表明其性能优于沟道长度更长的器件。此外,还利用器件的小信号模型评估了器件的射频性能。这项工作利用关键性能指标(FoMs)进一步研究了器件的高频响应:栅极电容(Cgs、Cgd、Cgg)、截止频率(fT)和最大振荡频率(fMAX)。这些参数量化了寄生电容对开关速度以及模拟和射频应用最大可用频率的影响。对 Cgs、Cgd 和 Cgg 的分析揭示了栅极控制对高频操作的影响。与 20 nm 沟道长度的器件相比,15 nm 沟道长度的器件 fT 提高了 47.29%,fMAX 提高了 68.97%。研究结果强调了优化沟道长度对提高 n 型硅基双栅无结晶体管的模拟和射频性能的重要意义。
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引用次数: 0
Effects of bismuth particle inclusions on surface and internal wear of single crystal iron: A molecular dynamics simulation 铋颗粒夹杂物对单晶铁表面和内部磨损的影响:分子动力学模拟
Pub Date : 2024-06-12 DOI: 10.1016/j.micrna.2024.207912
Guangyuan Li , Fazhan Wang , Zhanwen Chen , Yuan Fan , Pan Li , Menghui Liu , Hong Wu

The influence of bismuth (Bi) nanoparticles on single-crystal iron (Fe) under rigid ball rolling-sliding friction conditions is investigated using molecular dynamics simulations.Various aspects such as frictional force, dislocation length, dislocation configuration, and frictional surface are examined, along with the characteristics of bismuth particles at different depths of inclusion during wear provide partial theories for the application of free-cutting steels containing Bi. The results indicate that the morphology of wear chips accumulation and the lattice structure of wear chips depend significantly on the different forms of Bi inclusions and rotation periods of rigid ball. The extracted atomic displacement vectors theoretically explain the reasons for different accumulation morphologies and reveal atomic trajectories for subsurface damage due to inward movements. Furthermore, comparing the friction force curves between specimens with inclusions and pure Fe demonstrates that the softer Bi particles soften the workpiece, leading to corresponding wear and damage even at lower friction forces compared to the pure Fe model. Additionally, the study finds that dislocations play a dominant role in wear damage, with Bi particles hindering dislocation slip, as evidenced by the significant inhibition of Von Mises stresses by bismuth. Bi also prevents dislocation nucleation within itself, avoiding deeper wear damage to the iron matrix after slip, ultimately resulting in less severe subsurface frictional damage in the inclusion model compared to pure iron. Deeper inclusions significantly induce the generation of high-energy dislocations during wear, attributed to Bi aiding in strain energy storage, thereby higher strain energy for dislocations in Fe media.

利用分子动力学模拟研究了刚球滚动-滑动摩擦条件下纳米铋(Bi)粒子对单晶铁(Fe)的影响。研究了摩擦力、位错长度、位错构型和摩擦表面等多个方面,以及磨损过程中不同夹杂深度铋粒子的特征,为含铋易切削钢的应用提供了部分理论依据。结果表明,磨损屑堆积的形态和磨损屑的晶格结构在很大程度上取决于不同形式的铋夹杂物和刚性球的旋转周期。所提取的原子位移矢量从理论上解释了不同堆积形态的原因,并揭示了由于向内运动造成的次表层损伤的原子轨迹。此外,比较含有夹杂物的试样和纯铁试样的摩擦力曲线表明,较软的 Bi 粒子会软化工件,从而导致相应的磨损和损坏,即使与纯铁模型相比摩擦力较低也是如此。此外,研究还发现,位错在磨损损坏中起着主导作用,铋粒子阻碍了位错滑移,铋对 Von Mises 应力的显著抑制就是证明。铋还能防止位错在自身内部成核,避免滑移后对铁基体造成更深的磨损破坏,最终导致包体模型中的次表层摩擦破坏比纯铁模型更轻。较深的夹杂物在磨损过程中会明显诱发高能位错的产生,这归因于铋有助于应变能存储,从而提高了铁介质中位错的应变能。
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引用次数: 0
Electronic and transport properties of U-cut edge patterned AGNR superlattice for RTD application 用于热电阻应用的 U 切边图案 AGNR 超晶格的电子和传输特性
Pub Date : 2024-06-10 DOI: 10.1016/j.micrna.2024.207900
Bikramjit Basumatary , Agile Mathew

In this paper, we first characterize a superlattice structure created by repeating a heterostructure formed from two armchair graphene nanoribbon (AGNR) segments with different widths. We investigate the electronic and transport properties of this structure by varying its widths and lengths to demonstrate the tunability of its overall band gap. The plot of the local density of states shows the formation of localized states at the low band gap segments of the superlattice. The superlattice is then used as a barrier to create a double barrier quantum well (DBQW) to design a proposed resonant tunneling diode (RTD) structure. We observe this device's negative differential resistance (NDR) operation for a range of bias voltages between the contacts. We study the effect of dimensional parameters on the RTD performance. The non-equilibrium Green's function method, based on a tight-binding model, is employed for numerical computation.

在本文中,我们首先描述了一种超晶格结构的特性,这种超晶格结构是由两个不同宽度的扶手石墨烯纳米带(AGNR)片段重复形成的异质结构。我们通过改变其宽度和长度来研究这种结构的电子和传输特性,以证明其整体带隙的可调性。局部态密度图显示,在超晶格的低带隙段形成了局部态。然后,利用超晶格作为势垒来创建双势垒量子阱(DBQW),从而设计出一种拟议的共振隧穿二极管(RTD)结构。我们观察到该器件在触点间一定范围的偏置电压下的负差分电阻 (NDR) 工作特性。我们研究了尺寸参数对 RTD 性能的影响。数值计算采用了基于紧密结合模型的非平衡格林函数法。
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引用次数: 0
Improvement of p-type ohmic contact of GaN laser diodes by using delta-doped p-GaN contact layer 使用三角掺杂的 p-GaN 接触层改善 GaN 激光二极管的 p 型欧姆触点
IF 2.7 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2024-06-04 DOI: 10.1016/j.micrna.2024.207899
Rui Lang , Menglai Lei , Shukun Li , Huanqing Chen , Hua Zong , Shengxiang Jiang , Guo Yu , Weihua Chen , Xiaodong Hu

The p-type ohmic contact of GaN laser diodes has been optimized in several ways. The heavily doped p-GaN contact layer obtained by using delta-doping method, which effectively suppressed the self compensation effect of Mg ions during the heavy doping. By optimizing the delta-doping period, temperature, and thickness of the p-GaN contact layer, the activation energy of Mg atoms is reduced, and the hole concentration in the surface contact layer is further increased. Finally, the specific contact resistivity of the p-type ohmic contact of the GaN laser, measured more accurately by using the transmission line module, was successfully reduced to the order of 1E-3 Ω cm2.

GaN 激光二极管的对型欧姆接触已通过多种方法进行了优化。采用三角掺杂法获得的重掺杂 p-GaN 接触层,有效抑制了重掺杂过程中镁离子的自补偿效应。通过优化 p-GaN 接触层的△掺杂周期、温度和厚度,降低了镁原子的活化能,进一步提高了表面接触层中的空穴浓度。最后,利用传输线模块更精确地测量了氮化镓激光器 p 型欧姆接触的比接触电阻率,成功地将其降低到 1E-3 Ω cm2 的数量级。
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引用次数: 0
Computation of the near-infrared electro-absorption in GeSn/SiGeSn step quantum wells GeSn/SiGeSn 梯级量子阱中的近红外电吸收计算
Pub Date : 2024-06-02 DOI: 10.1016/j.micrna.2024.207876
N. Yahyaoui , E. Jellouli , P. Baser , N. Zeiri , M. Said , Mohammad N. Murshed

In this study, we propose a theoretical simulation of the type-I step quantum well obtained from GeSn/SiGeSn to scan a wide range of telecommunication wavelengths and obtain near-infrared optical modulators. At T = 300 K, the band discontinuities and energy gap between stretched Ge1−xSnx and relaxed Si0.1Ge0.9−ySny due to the acquisition of the heterostructure were calculated.

Then, optimization of this heterostructure based on (Si) GeSn was performed using the solid theory model to balance out the composition y of Si0.1Ge0.9-ySny relaxed and thickness of Ge0.91Sn0.09 QWs. The eigenenergies and their related wavefunctions are computed by solving the Schrödinger equation using the finite difference method under the framework of the effective mass approximation. Depending on the y concentration, the energy levels of the electron and the heavy hole, the change of transition energies and oscillator strength were examined for different well widths. Additionally, the absorption coefficient with y concentration and structure parameters were examined.

From the findings obtained, it was determined that this material group is very important to obtain high efficiency from electro-absorption modulators covering the 1.55 μm wavelength range.

在这项研究中,我们提出了对 GeSn/SiGeSn 制成的 I 型阶跃量子阱进行理论模拟,以扫描宽范围的电信波长并获得近红外光调制器。在 T = 300 K 时,计算了由于异质结构的获得而导致的拉伸 Ge1-xSnx 与松弛 Si0.1Ge0.9-ySny 之间的能带不连续性和能隙。然后,利用固体理论模型对这种基于(Si)GeSn 的异质结构进行了优化,以平衡松弛 Si0.1Ge0.9-ySny 的成分 y 和 Ge0.91Sn0.09 QW 的厚度。在有效质量近似的框架下,使用有限差分法求解薛定谔方程,从而计算出特征能及其相关波函数。根据 y 浓度、电子和重空穴的能级,研究了不同阱宽下跃迁能量和振荡器强度的变化。此外,还研究了吸收系数与 y 浓度和结构参数的关系。根据研究结果,可以确定该材料群对于在 1.55 μm 波长范围内获得高效电吸收调制器非常重要。
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引用次数: 0
On the effect of patterned hole on the thermal conductivity of Ψ-graphene nanosheet: A molecular dynamics simulation 图案孔对Ψ-石墨烯纳米片导热率的影响:分子动力学模拟
Pub Date : 2024-06-01 DOI: 10.1016/j.micrna.2024.207898
Yanqun Shen, Dongmei Bi, Bohao Wang, Shujie Liu

Molecular Dynamics (MD) simulation is used here to evaluate Thermal Conductivity (TC) of perfect and defective ψ-graphene. The defect is applied in the shape of circle, square, diamond, and triangle shapes on the nanosheets. Moreover, vacancy defect is also applied to the nanosheet. The influence of the defect on the TC of the ψ-graphene is investigated. It is shown that TC of the defective ψ-graphene is lower than the perfect one. Besides, to investigate the effect of temperature on the TC of the ψ-graphene, the temperature is changed in the range of 200–700 K. It is shown that the TC is inversely depends on the temperature. However, increasing the temperature leads to increase in the TC of the considered structure.

分子动力学(MD)模拟用于评估完美和缺陷ψ-石墨烯的导热率(TC)。纳米片上的缺陷形状有圆形、方形、菱形和三角形。此外,纳米片上还存在空位缺陷。研究了缺陷对ψ-石墨烯透明度的影响。结果表明,缺陷ψ-石墨烯的 TC 低于完美ψ-石墨烯。此外,为了研究温度对ψ-石墨烯 TC 的影响,在 200-700 K 的范围内改变温度。然而,温度升高会导致所考虑结构的热导率增加。
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引用次数: 0
Electrolyte gated based pH sensing vertical TFET biosensor: Design, simulation and noise analysis 基于电解质门控的 pH 传感垂直 TFET 生物传感器:设计、模拟和噪声分析
Pub Date : 2024-05-31 DOI: 10.1016/j.micrna.2024.207897
Aditya Kumar Singh Pundir , Pawandeep Kaur , Srinivas Burra , Prashant Mani , Girish Wadhwa

In this manuscript, a pH-based stepped oxide gate underlap vertical tunnel field-effect transistor (hetero-pHVTFET) biosensor with GaSb-doped layers is explored. A novel feature of the proposed device involves the use of stepped oxides with underlapped cavity gates. During the fabrication of devices, several challenges have emerged. A vertical tunnel field-effect transistor (VTFET) is proposed in this study for the detection of biological molecules such as proteins, enzymes, deoxyribonucleic acids, and others using label-based electrical recognition through the Stern layer. The simulation model provides a generalized solution for biological molecule detection, featuring the effects of pH sensing. Surface potential and device current (IDS) are investigated in relation to pH changes. Moreover, pH sensors have also been used to measure changes in hydrogen ion concentration within electrolyte solutions and to examine the sensitivity of proposed biological sensors based on alterations in the density of states. A 40 nm cavity length of the proposed hetero-pHVTFET biosensor is estimated to have a drain current sensitivity of 9.2 × 105.

本手稿探讨了一种基于 pH 值的阶梯氧化物栅下搭接垂直隧道场效应晶体管(hetero-pHVTFET)生物传感器。该器件的一个新特点是使用了具有下重叠空腔栅极的阶梯氧化物。在器件制造过程中,出现了一些挑战。本研究提出了一种垂直隧道场效应晶体管 (VTFET),用于通过斯特恩层对蛋白质、酶、脱氧核糖核酸等生物分子进行基于标签的电识别检测。仿真模型提供了生物分子检测的通用解决方案,并具有 pH 值传感效果。研究了与 pH 值变化相关的表面电位和器件电流(IDS)。此外,pH 传感器还被用于测量电解质溶液中氢离子浓度的变化,并根据状态密度的变化研究拟议生物传感器的灵敏度。据估计,40 nm 腔长的拟议异质-pHVTFET 生物传感器的漏极电流灵敏度为 9.2 × 105。
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引用次数: 0
期刊
Micro and Nanostructures
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