Pub Date : 2026-03-01Epub Date: 2025-12-16DOI: 10.1016/j.micrna.2025.208528
Saba Khalil , Muneerah Alomar , Muhammad Ali Hamza Shahbaz , Mohammed Jalalah , Amir Muhammad Afzal , M.A. Diab , Farid A. Harraz
Hydrogen is emerging as a promising clean and sustainable energy carrier for energy generation and storage via electrolysis. The design of multifunctional electrodes that can catalyze and store energy is a significant issue. This paper presents a hierarchically engineered composite electrode incorporating a combination of redox-active species based binary transition metal oxide (ZrV2O7), with a conductive structure of g-C3N4 and rGO to provide an improved capacity of charge-storage. The optimized design facilitates fast diffusion of ions and charge transfer as well as stable electrochemical cycling with the resultant superior energy-storage capability and consistent HER electrocatalytic splitting capability. The ZrV2O7@g-C3N4–electrode delivers the highest specific capacity of 1123 Cg-1 in Hg/HgO referencing cell system. The ZrV2O7@g-C3N4/rGO//AC-hybrid device presents the tunable charge storage response, with 35 Wh kg−1 and 2559 W kg−1, of 223 Cg-1 of energy density (Ed), Power density (Pd), and specific capacity measurements. The ZrV2O7@g-C3N4–electrode provides enhanced HER kinetics with an overpotential of 57 mV and the Tafel slope of 61 mV.dec−1, and outstanding cycling stability and durability. The efficient electrocatalytic response of the present ZrV2O7@g-C3N4/rGO electrode presents it as a hybrid, like platform, having a promising approach to next-generation hybrid devices in which energy conversion, high energy density, and fast power delivery can be simultaneously attained.
氢正在成为一种有前途的清洁和可持续的能源载体,用于通过电解发电和储存能源。能够催化和储存能量的多功能电极的设计是一个重要的问题。本文提出了一种分层设计的复合电极,该电极结合了氧化还原活性物质二元过渡金属氧化物(ZrV2O7),具有g-C3N4和rGO的导电结构,以提供改进的电荷存储能力。优化后的设计促进了离子的快速扩散和电荷转移,以及稳定的电化学循环,从而获得了卓越的储能能力和一致的HER电催化分裂能力。ZrV2O7@g-C3N4 -电极在Hg/HgO基准电池系统中提供最高的1123 Cg-1比容量。ZrV2O7@g-C3N4/rGO//交流混合装置具有可调的电荷存储响应,能量密度(Ed)、功率密度(Pd)和比容量测量值分别为35 Wh kg -1和2559 W kg -1。ZrV2O7@g-C3N4 -电极提供了增强的HER动力学,过电位为57 mV, Tafel斜率为61 mV.dec−1,并且具有出色的循环稳定性和耐久性。目前ZrV2O7@g-C3N4/rGO电极的高效电催化响应表明它是一个混合平台,具有下一代混合设备的有前途的方法,其中能量转换,高能量密度和快速电力输送可以同时实现。
{"title":"Novel bifunctional ZrV2O7@g-C3N4/rGO electrode with synergistic interface engineering for high-efficiency hydrogen evolution and advanced hybrid supercapacitor in alkaline media","authors":"Saba Khalil , Muneerah Alomar , Muhammad Ali Hamza Shahbaz , Mohammed Jalalah , Amir Muhammad Afzal , M.A. Diab , Farid A. Harraz","doi":"10.1016/j.micrna.2025.208528","DOIUrl":"10.1016/j.micrna.2025.208528","url":null,"abstract":"<div><div>Hydrogen is emerging as a promising clean and sustainable energy carrier for energy generation and storage via electrolysis. The design of multifunctional electrodes that can catalyze and store energy is a significant issue. This paper presents a hierarchically engineered composite electrode incorporating a combination of redox-active species based binary transition metal oxide (ZrV<sub>2</sub>O<sub>7</sub>), with a conductive structure of g-C<sub>3</sub>N<sub>4</sub> and rGO to provide an improved capacity of charge-storage. The optimized design facilitates fast diffusion of ions and charge transfer as well as stable electrochemical cycling with the resultant superior energy-storage capability and consistent HER electrocatalytic splitting capability. The ZrV<sub>2</sub>O<sub>7</sub>@g-C<sub>3</sub>N<sub>4</sub>–electrode delivers the highest specific capacity of 1123 Cg<sup>-1</sup> in Hg/HgO referencing cell system. The ZrV<sub>2</sub>O<sub>7</sub>@g-C<sub>3</sub>N<sub>4</sub>/rGO//AC-hybrid device presents the tunable charge storage response, with 35 Wh kg<sup>−1</sup> and 2559 W kg<sup>−1</sup>, of 223 Cg<sup>-1</sup> of energy density (E<sub>d</sub>), Power density (P<sub>d</sub>), and specific capacity measurements. The ZrV<sub>2</sub>O<sub>7</sub>@g-C<sub>3</sub>N<sub>4</sub>–electrode provides enhanced HER kinetics with an overpotential of 57 mV and the Tafel slope of 61 mV.dec<sup>−1</sup>, and outstanding cycling stability and durability. The efficient electrocatalytic response of the present ZrV<sub>2</sub>O<sub>7</sub>@g-C<sub>3</sub>N<sub>4</sub>/rGO electrode presents it as a hybrid, like platform, having a promising approach to next-generation hybrid devices in which energy conversion, high energy density, and fast power delivery can be simultaneously attained.</div></div>","PeriodicalId":100923,"journal":{"name":"Micro and Nanostructures","volume":"211 ","pages":"Article 208528"},"PeriodicalIF":3.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145841730","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-03-01Epub Date: 2025-12-27DOI: 10.1016/j.micrna.2025.208541
Mirunalini Aravindan , C. Periasamy , Ramanand A.C. , Muneeswaran Packiaraj , S. Raghavan , Preeth Raguraman
This work presents the design and optimization of AlGaN/GaN based High Electron Mobility Transistors (HEMT) with an AlO functionalization layer for the detection of Heavy Metal Ions (HMIs) in water. Silvaco TCAD simulations were used to optimize the HEMT structure and to test its response to varying concentrations of mercury (Hg) and lead (Pb) ions. The obtained simulation results demonstrate that the AlO functionalized HEMT structure exhibits notable sensitivity of 0.48 mV/(mg/mL) and 0.452 mV/(mg/mL) for Hg and Pb ions, respectively. However, the selectivity of the proposed sensor between the two ions is poor, which poses a challenge for accurate discrimination between different heavy metal ions. To address this limitation, a machine learning-based approach was employed, utilizing key electrical characteristics such as threshold voltage (Vth) and saturation current () to improve ion differentiation and selectivity. This proposed ML method provides a generalizable strategy for simultaneous detection and multi-ion quantification of coexisting metal ions. The simulation study also indicated that the proposed AlO functionalized AlGaN/GaN HEMT based sensor has potential applications in mercury and lead ion detection in an aqueous environment.
{"title":"Design and simulation of HEMT-based sensor for Heavy Metal Ion detection with selectivity enhancement using ensemble methods","authors":"Mirunalini Aravindan , C. Periasamy , Ramanand A.C. , Muneeswaran Packiaraj , S. Raghavan , Preeth Raguraman","doi":"10.1016/j.micrna.2025.208541","DOIUrl":"10.1016/j.micrna.2025.208541","url":null,"abstract":"<div><div>This work presents the design and optimization of AlGaN/GaN based High Electron Mobility Transistors (HEMT) with an Al<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>O<span><math><msub><mrow></mrow><mrow><mn>3</mn></mrow></msub></math></span> functionalization layer for the detection of Heavy Metal Ions (HMIs) in water. Silvaco TCAD simulations were used to optimize the HEMT structure and to test its response to varying concentrations of mercury (Hg<span><math><msup><mrow></mrow><mrow><mn>2</mn><mo>+</mo></mrow></msup></math></span>) and lead (Pb<span><math><msup><mrow></mrow><mrow><mn>2</mn><mo>+</mo></mrow></msup></math></span>) ions. The obtained simulation results demonstrate that the Al<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>O<span><math><msub><mrow></mrow><mrow><mn>3</mn></mrow></msub></math></span> functionalized HEMT structure exhibits notable sensitivity of 0.48 mV/(mg/mL) and 0.452 mV/(mg/mL) for Hg<span><math><msup><mrow></mrow><mrow><mn>2</mn><mo>+</mo></mrow></msup></math></span> and Pb<span><math><msup><mrow></mrow><mrow><mn>2</mn><mo>+</mo></mrow></msup></math></span> ions, respectively. However, the selectivity of the proposed sensor between the two ions is poor, which poses a challenge for accurate discrimination between different heavy metal ions. To address this limitation, a machine learning-based approach was employed, utilizing key electrical characteristics such as threshold voltage (Vth) and saturation current (<span><math><msub><mrow><mi>I</mi></mrow><mrow><mi>D</mi><mi>S</mi><mi>S</mi></mrow></msub></math></span>) to improve ion differentiation and selectivity. This proposed ML method provides a generalizable strategy for simultaneous detection and multi-ion quantification of coexisting metal ions. The simulation study also indicated that the proposed Al<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>O<span><math><msub><mrow></mrow><mrow><mn>3</mn></mrow></msub></math></span> functionalized AlGaN/GaN HEMT based sensor has potential applications in mercury and lead ion detection in an aqueous environment.</div></div>","PeriodicalId":100923,"journal":{"name":"Micro and Nanostructures","volume":"211 ","pages":"Article 208541"},"PeriodicalIF":3.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145884788","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-03-01Epub Date: 2026-01-02DOI: 10.1016/j.micrna.2025.208559
Vijaya Kumar K. , Rithika R. , Suresh Balanethiram , J. Indra
Threshold voltage () extraction in Tunnel Field-Effect Transistors (TFETs) remains a challenging task due to lack of inversion layer formation in channel region. In this work, we investigate the reliability of three widely used extraction techniques: Constant Current (CC), Transconductance Change (TC), and Linear Extrapolation (LE) methods across ten silicon-based TFET structures featuring variations in spacer material, spacer length, gate oxide material, contact placement position and contact geometry. Simulations were performed at multiple drain voltages ( = 0.01V, 0.5V, 1.0V, and 1.5 V) to study the influence of drain bias on threshold behavior. Our results reveal that the dependence on due to Drain Induced Barrier Lowering (DIBL) is captured accurately in TC but not in CC. Also we inferred that LE method follows the trend of TC method. This comparative analysis highlights the inherent trade-offs between physical accuracy and bias sensitivity in different extraction methods and provides insights for selecting appropriate techniques in TFET modeling and circuit design.
{"title":"Review of reliability of threshold voltage (Vth) extraction methods in silicon-based tunnel field effect transistors (TFETs)","authors":"Vijaya Kumar K. , Rithika R. , Suresh Balanethiram , J. Indra","doi":"10.1016/j.micrna.2025.208559","DOIUrl":"10.1016/j.micrna.2025.208559","url":null,"abstract":"<div><div>Threshold voltage (<span><math><msub><mrow><mi>V</mi></mrow><mrow><mi>th</mi></mrow></msub></math></span>) extraction in Tunnel Field-Effect Transistors (TFETs) remains a challenging task due to lack of inversion layer formation in channel region. In this work, we investigate the reliability of three widely used <span><math><msub><mrow><mi>V</mi></mrow><mrow><mi>th</mi></mrow></msub></math></span> extraction techniques: Constant Current (CC), Transconductance Change (TC), and Linear Extrapolation (LE) methods across ten silicon-based TFET structures featuring variations in spacer material, spacer length, gate oxide material, contact placement position and contact geometry. Simulations were performed at multiple drain voltages (<span><math><msub><mrow><mi>V</mi></mrow><mrow><mi>DS</mi></mrow></msub></math></span> = 0.01V, 0.5V, 1.0V, and 1.5 V) to study the influence of drain bias on threshold behavior. Our results reveal that the <span><math><msub><mrow><mi>V</mi></mrow><mrow><mi>th</mi></mrow></msub></math></span> dependence on <span><math><msub><mrow><mi>V</mi></mrow><mrow><mi>DS</mi></mrow></msub></math></span> due to Drain Induced Barrier Lowering (DIBL) is captured accurately in TC but not in CC. Also we inferred that LE method follows the trend of TC method. This comparative analysis highlights the inherent trade-offs between physical accuracy and bias sensitivity in different extraction methods and provides insights for selecting appropriate techniques in TFET modeling and circuit design.</div></div>","PeriodicalId":100923,"journal":{"name":"Micro and Nanostructures","volume":"211 ","pages":"Article 208559"},"PeriodicalIF":3.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145939148","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-03-01Epub Date: 2026-01-06DOI: 10.1016/j.micrna.2026.208562
Shufang Li, Yunfeng Chen, Junqi Tang
Stable and efficient red-emitting phosphors hold significant application value for next-generation phosphor-converted white light-emitting diodes (pc-WLEDs). This study successfully synthesized europium-doped strontium orthoborate (Sr3B2O6: Eu3+) red phosphors via a high-temperature solid-state reaction method. The phosphor samples were pure phase and had an average particle size of 1.99 ± 0.88 μm. Near the optimal doping concentration (x = 0.040), the integrated intensity contribution of the 5D0→7F4 (704 nm) electric-dipole transition was significantly enhanced. The Sr3B2O6 host matrix can effectively increase the electric-dipole transition of Eu3+, resulting in chromaticity coordinates (0.629, 0.348) close to those of standard red light and high color purity. The quantum efficiency of Sr2.96B2O6:0.04Eu3+ is 33.76 %, with a fluorescence lifetime of 1.349 ms. Furthermore, its luminescence intensity at 498 K remained at 68.90 % of the room temperature intensity. The encapsulated pc-WLED device exhibits white emission with chromaticity coordinates of (0.334, 0.344), and located in the white region. The pc-WLED device also has a high color purity with a high color rendering index (CRI or Ra = 90) and correlated color temperature (CCT) of 5437 K. These results demonstrate the excellent application potential of this phosphor in the field of white LED lighting.
{"title":"Study on the enhanced electric dipole transition ratio of europium (Eu3+) in strontium orthoborate red phosphor and its WLED applications","authors":"Shufang Li, Yunfeng Chen, Junqi Tang","doi":"10.1016/j.micrna.2026.208562","DOIUrl":"10.1016/j.micrna.2026.208562","url":null,"abstract":"<div><div>Stable and efficient red-emitting phosphors hold significant application value for next-generation phosphor-converted white light-emitting diodes (pc-WLEDs). This study successfully synthesized europium-doped strontium orthoborate (Sr<sub>3</sub>B<sub>2</sub>O<sub>6</sub>: Eu<sup>3+</sup>) red phosphors via a high-temperature solid-state reaction method. The phosphor samples were pure phase and had an average particle size of 1.99 ± 0.88 μm. Near the optimal doping concentration (x = 0.040), the integrated intensity contribution of the <sup><em>5</em></sup><em>D</em><sub><em>0</em></sub> <em>→</em><sup><em>7</em></sup><em>F</em><sub><em>4</em></sub> (704 nm) electric-dipole transition was significantly enhanced. The Sr<sub>3</sub>B<sub>2</sub>O<sub>6</sub> host matrix can effectively increase the electric-dipole transition of Eu<sup>3+</sup>, resulting in chromaticity coordinates (0.629, 0.348) close to those of standard red light and high color purity. The quantum efficiency of Sr<sub>2.96</sub>B<sub>2</sub>O<sub>6</sub>:0.04Eu<sup>3+</sup> is 33.76 %, with a fluorescence lifetime of 1.349 ms. Furthermore, its luminescence intensity at 498 K remained at 68.90 % of the room temperature intensity. The encapsulated pc-WLED device exhibits white emission with chromaticity coordinates of (0.334, 0.344), and located in the white region. The pc-WLED device also has a high color purity with a high color rendering index (CRI or Ra = 90) and correlated color temperature (CCT) of 5437 K. These results demonstrate the excellent application potential of this phosphor in the field of white LED lighting.</div></div>","PeriodicalId":100923,"journal":{"name":"Micro and Nanostructures","volume":"211 ","pages":"Article 208562"},"PeriodicalIF":3.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145939147","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-03-01Epub Date: 2025-12-13DOI: 10.1016/j.micrna.2025.208522
Aruna Dore, M. Manikandan
Optimization of Electron Blocking Layer (EBL) composition in Aluminum Gallium Nitride (AlGaN) Ultraviolet (UV) Light-Emitting Diodes (LEDs) represents an advanced device design framework where EBL properties are tuned to improve carrier injection, radiative recombination, and overall device efficiency. This setup supports the interaction between material composition, thickness, and LED performance parameters through predictive and optimization strategies; however, Internal Quantum Efficiency (IQE), Hole Injection Efficiency (HIE), carrier confinement efficiency, and efficiency droop may be suboptimal due to nonlinear dependencies and uncertainties in the EBL design space, potentially limiting overall device performance. Moreover, inefficient design selection, reduced optical output, and inaccurate performance predictions can further hinder the effectiveness of UV LEDs. To overcome these issues, this manuscript proposes a method for EBL optimization in AlGaN UV LEDs. The suggested hybrid technique combines Fuzzy Embedded Recurrent Neural Network (FERNN) and Spider-Tailed Horned Viper Optimization (STHVO), and is therefore called the FERNN-STHVO technique. The primary goal of the suggested technique is to maximize IQE, HIE, and carrier confinement efficiency, while minimizing efficiency droop. The FERNN predicts key LED performance parameters by capturing nonlinear relationships and handling uncertainties in the input design space. The STHVO tunes the FERNN weight parameter to achieve optimal device performance. By then, MATLAB is used to develop the suggested method, and it is contrasted with other current methods such as Extreme Gradient Boosting (XGBoost), Convolutional Neural Network (CNN), and JAYA Optimization Algorithm (JAYA). The suggested FERNN-STHVO method improves IQE to 53 %, enhances HIE to 72 %, and increases carrier confinement efficiency to 69 %. It also achieves a substantially higher efficiency droop reduction of 48 % and reduces leakage current by 56 %, thereby enabling balanced carrier dynamics, supporting stronger radiative recombination, and enhancing the overall performance and stability of AlGaN UV LEDs.
{"title":"Optimization of electron blocking layer composition in AlGaN ultraviolet light-emitting diodes using fuzzy embedded RNN and spider-tailed horned viper algorithm","authors":"Aruna Dore, M. Manikandan","doi":"10.1016/j.micrna.2025.208522","DOIUrl":"10.1016/j.micrna.2025.208522","url":null,"abstract":"<div><div>Optimization of Electron Blocking Layer (EBL) composition in Aluminum Gallium Nitride (AlGaN) Ultraviolet (UV) Light-Emitting Diodes (LEDs) represents an advanced device design framework where EBL properties are tuned to improve carrier injection, radiative recombination, and overall device efficiency. This setup supports the interaction between material composition, thickness, and LED performance parameters through predictive and optimization strategies; however, Internal Quantum Efficiency (IQE), Hole Injection Efficiency (HIE), carrier confinement efficiency, and efficiency droop may be suboptimal due to nonlinear dependencies and uncertainties in the EBL design space, potentially limiting overall device performance. Moreover, inefficient design selection, reduced optical output, and inaccurate performance predictions can further hinder the effectiveness of UV LEDs. To overcome these issues, this manuscript proposes a method for EBL optimization in AlGaN UV LEDs. The suggested hybrid technique combines Fuzzy Embedded Recurrent Neural Network (FERNN) and Spider-Tailed Horned Viper Optimization (STHVO), and is therefore called the FERNN-STHVO technique. The primary goal of the suggested technique is to maximize IQE, HIE, and carrier confinement efficiency, while minimizing efficiency droop. The FERNN predicts key LED performance parameters by capturing nonlinear relationships and handling uncertainties in the input design space. The STHVO tunes the FERNN weight parameter to achieve optimal device performance. By then, MATLAB is used to develop the suggested method, and it is contrasted with other current methods such as Extreme Gradient Boosting (XGBoost), Convolutional Neural Network (CNN), and JAYA Optimization Algorithm (JAYA). The suggested FERNN-STHVO method improves IQE to 53 %, enhances HIE to 72 %, and increases carrier confinement efficiency to 69 %. It also achieves a substantially higher efficiency droop reduction of 48 % and reduces leakage current by 56 %, thereby enabling balanced carrier dynamics, supporting stronger radiative recombination, and enhancing the overall performance and stability of AlGaN UV LEDs.</div></div>","PeriodicalId":100923,"journal":{"name":"Micro and Nanostructures","volume":"211 ","pages":"Article 208522"},"PeriodicalIF":3.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145799764","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-03-01Epub Date: 2025-12-14DOI: 10.1016/j.micrna.2025.208527
Ammar Armghan , Bo Bo Han , Ashish Baldania , Khaled Aliqab , Meshari Alsharari , Yogesh Sharma , Shobhit K. Patel
Solar energy is essential for driving the transition toward a clean and sustainable energy cycle. Research on solar absorbers is a key focus in solar energy systems, as it directly contributes to improved energy harvesting performance. The current design with the material composition of the Cr–Fe3O4–ZrO2 and a graphene nanostructure is applied in the investigation of the current solar structure. The current absorber can work in the ultra-wideband (UV-MIR) spectra and with an efficient rate of 94.66 % for 2800 nm. Moreover, the current solar absorber can reach 97.38 % for 1000 nm with the proficient square-resonator design. We distributed the machine learning section in the current work to describe the predicted and actual value output in each parameter with the linear regression method. With the good efficiency of radiation, the current research can be used as a renewable energy option in hatcheries and dairies, swimming pool warming, the agricultural sector, health clubs, boiler feed, and so on.
{"title":"Next-generation nanostructured graphene–Cr–fe3O4–ZrO2 solar absorber: AI-driven performance prediction and optimization for renewable energy applications","authors":"Ammar Armghan , Bo Bo Han , Ashish Baldania , Khaled Aliqab , Meshari Alsharari , Yogesh Sharma , Shobhit K. Patel","doi":"10.1016/j.micrna.2025.208527","DOIUrl":"10.1016/j.micrna.2025.208527","url":null,"abstract":"<div><div>Solar energy is essential for driving the transition toward a clean and sustainable energy cycle. Research on solar absorbers is a key focus in solar energy systems, as it directly contributes to improved energy harvesting performance. The current design with the material composition of the Cr–Fe<sub>3</sub>O<sub>4</sub>–ZrO<sub>2</sub> and a graphene nanostructure is applied in the investigation of the current solar structure. The current absorber can work in the ultra-wideband (UV-MIR) spectra and with an efficient rate of 94.66 % for 2800 nm. Moreover, the current solar absorber can reach 97.38 % for 1000 nm with the proficient square-resonator design. We distributed the machine learning section in the current work to describe the predicted and actual value output in each parameter with the linear regression method. With the good efficiency of radiation, the current research can be used as a renewable energy option in hatcheries and dairies, swimming pool warming, the agricultural sector, health clubs, boiler feed, and so on.</div></div>","PeriodicalId":100923,"journal":{"name":"Micro and Nanostructures","volume":"211 ","pages":"Article 208527"},"PeriodicalIF":3.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145799782","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-03-01Epub Date: 2025-12-24DOI: 10.1016/j.micrna.2025.208537
V.V. Manju , R. Sanjana , Vinayakprasanna N. Hegde , S. Divakara , B.C. Hemaraju , Janya Lumbini , Namratha , N. Raghu , R. Somashekar
In this study titanium (Ti4+) doped zinc oxide (ZnO) nanoparticles were synthesized via a green solution combustion method employing Calotropis gigantea as fuel. Employing various characterization techniques, the structural, morphological, elastic, and electromechanical properties were studied. The Rietveld refinement confirms the presence of hexagonal wurtzite structure with lattice strain induced by Ti4+ substitution. The computational simulation using GULP reveals how Ti4+ doping modifies the mechanical stiffness and dielectric response of ZnO by showing direction-dependent elastic and dielectric behaviour. The crystallite size obtained using Scherrer equation and dislocation density have shown a non-linear trend with optimal grain growth at 5 % of Ti4+ as observed in 3D map. Electron density (ED) mapping reveals evolving symmetry and strain distribution across doping levels. The analysis of surface texture highlights enhanced surface waviness and roughness with heterogeneity. The shift in vibrational modes can be seen in FTIR spectra, affirming dopant incorporation and reduced surface organics. A tunable bandgap from 3.25 to 3.50 eV have been obtained using UV–Vis absorption, showing potential for optoelectronics. These materials have application in UV-protective coatings, sensors, and photocatalytic systems.
{"title":"Structural, morphological, optical, and electromechanical analysis of green-synthesized Ti-doped ZnO nanoparticles for optoelectronic applications","authors":"V.V. Manju , R. Sanjana , Vinayakprasanna N. Hegde , S. Divakara , B.C. Hemaraju , Janya Lumbini , Namratha , N. Raghu , R. Somashekar","doi":"10.1016/j.micrna.2025.208537","DOIUrl":"10.1016/j.micrna.2025.208537","url":null,"abstract":"<div><div>In this study titanium (Ti<sup>4+</sup>) doped zinc oxide (ZnO) nanoparticles were synthesized via a green solution combustion method employing <em>Calotropis gigantea</em> as fuel. Employing various characterization techniques, the structural, morphological, elastic, and electromechanical properties were studied. The Rietveld refinement confirms the presence of hexagonal wurtzite structure with lattice strain induced by Ti<sup>4+</sup> substitution. The computational simulation using GULP reveals how Ti<sup>4+</sup> doping modifies the mechanical stiffness and dielectric response of ZnO by showing direction-dependent elastic and dielectric behaviour. The crystallite size obtained using Scherrer equation and dislocation density have shown a non-linear trend with optimal grain growth at 5 % of Ti<sup>4+</sup> as observed in 3D map. Electron density (ED) mapping reveals evolving symmetry and strain distribution across doping levels. The analysis of surface texture highlights enhanced surface waviness and roughness with heterogeneity. The shift in vibrational modes can be seen in FTIR spectra, affirming dopant incorporation and reduced surface organics. A tunable bandgap from 3.25 to 3.50 eV have been obtained using UV–Vis absorption, showing potential for optoelectronics. These materials have application in UV-protective coatings, sensors, and photocatalytic systems.</div></div>","PeriodicalId":100923,"journal":{"name":"Micro and Nanostructures","volume":"211 ","pages":"Article 208537"},"PeriodicalIF":3.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145884875","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Present study proposes a biosensor built around heterojunction electrically doped junctionless TFET to obtain label-free biomolecule surveillance to lower fabrication sophistication and expense of nanotechnology biosensors. Dielectric constants of different immobilized biomolecules in interior of nano cavity are changed to determine shift in ambipolar current, perceived as sensing variable. In suggested device, polarity gate-1 (PG-1) bias of 1.2 V and PG-2 bias of −1.2 V, is applied across heterojunction to stimulate n+ and p+, drain and source, correspondingly. Portion of dielectric oxide layer is etched towards drain channel tunnelling intersection to create nanogap cavity underneath PG-1 terminal, used to trap biomolecule test specimens. Presence of neutral and charged molecules inside cavities have been examined through modifications to electrical properties of suggested biosensor, including electric field, drain current, etc. Subthreshold swing, drain current, threshold voltage, switching ratio, and transconductance-to-current ratio are used to assess suggested biosensor's sensing capability. Suggested HJ-CD-ED-JLTFET biosensor, employing a neutral biomolecule having a dielectric constant of 12, reaches absolute maximum sensitivity of 3.86 × 109 assuming a fully packed nanocavity. To comprehend potential difficulties, implications of non-ideal problems on sensitivity, such as various fill factors (FFs), locations of biomolecules and steric hindrances, are investigated for suggested biosensor.
{"title":"Design and performance investigation of heterojunction electrically doped junctionless TFET for label-free biomolecule detection considering ambipolar conduction","authors":"Priyanka Kwatra , Sajai Vir Singh , Kaushal Nigam , Mukesh Kumar Bind","doi":"10.1016/j.micrna.2026.208564","DOIUrl":"10.1016/j.micrna.2026.208564","url":null,"abstract":"<div><div>Present study proposes a biosensor built around heterojunction electrically doped junctionless TFET to obtain label-free biomolecule surveillance to lower fabrication sophistication and expense of nanotechnology biosensors. Dielectric constants of different immobilized biomolecules in interior of nano cavity are changed to determine shift in ambipolar current, perceived as sensing variable. In suggested device, polarity gate-1 (PG-1) bias of 1.2 V and PG-2 bias of −1.2 V, is applied across heterojunction to stimulate n<sup>+</sup> and p<sup>+</sup>, drain and source, correspondingly. Portion of dielectric oxide layer is etched towards drain channel tunnelling intersection to create nanogap cavity underneath PG-1 terminal, used to trap biomolecule test specimens. Presence of neutral and charged molecules inside cavities have been examined through modifications to electrical properties of suggested biosensor, including electric field, drain current, etc. Subthreshold swing, drain current, threshold voltage, switching ratio, and transconductance-to-current ratio are used to assess suggested biosensor's sensing capability. Suggested HJ-CD-ED-JLTFET biosensor, employing a neutral biomolecule having a dielectric constant of 12, reaches absolute maximum sensitivity of 3.86 × 10<sup>9</sup> assuming a fully packed nanocavity. To comprehend potential difficulties, implications of non-ideal problems on sensitivity, such as various fill factors (FFs), locations of biomolecules and steric hindrances, are investigated for suggested biosensor.</div></div>","PeriodicalId":100923,"journal":{"name":"Micro and Nanostructures","volume":"211 ","pages":"Article 208564"},"PeriodicalIF":3.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145939145","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-03-01Epub Date: 2025-12-30DOI: 10.1016/j.micrna.2025.208548
Shangxuan Sun , Ming Cai , Han Su , Min Lu , Xiaomin He , Tao Lin , Zhaonian Yang , Shulong Wang
Hybrid plasmonic waveguides represent advanced optical transmission structures with significant potential for applications in integrated photonics. Relative to traditional plasmonic waveguides, the lower transmission losses and longer propagation distances are shown in hybrid plasmonic waveguides. However, existing designs for hybrid plasmonic waveguides predominantly rely on standard finite element simulation methods. Such methods are computationally intensive and inefficient, consequently hindering the development of novel device architectures. To address the limitation, this study developed a predictive model for the transmission characteristics of the triangle hybrid plasmonic waveguide by combining a dataset on the order of 104 elements generated via finite element simulations with a convolutional neural network (CNN). With different geometric parameters, the model delivers rapid and accurate predictions of key properties in hybrid triangular plasmonic waveguides, including the figure of merit, propagation length, normalized effective mode area, and the imaginary part of the effective refractive index for the triangular hybrid plasmonic waveguide. The approach accelerates simulations by approximately 6.05 × 102 times compared to traditional COMSOL simulations. Predictions from the CNN model demonstrate close agreement with COMSOL results, showing a higher R2 value of 0.989, outperforming conventional machine learning methods. The model enables swift and precise determination of optimal structural dimensions, significantly reducing the costs of designing and fabricating triangular hybrid plasmonic waveguides. Additionally, the proposed model exhibits broad applicability and can serve as a transfer learning foundation for predicting analogous waveguide structures, thereby substantially contributing to the engineering deployment of hybrid plasmonic optical waveguides.
{"title":"Precise prediction of transmission characteristics in triangle hybrid plasmonic waveguide based on convolutional neural networks","authors":"Shangxuan Sun , Ming Cai , Han Su , Min Lu , Xiaomin He , Tao Lin , Zhaonian Yang , Shulong Wang","doi":"10.1016/j.micrna.2025.208548","DOIUrl":"10.1016/j.micrna.2025.208548","url":null,"abstract":"<div><div>Hybrid plasmonic waveguides represent advanced optical transmission structures with significant potential for applications in integrated photonics. Relative to traditional plasmonic waveguides, the lower transmission losses and longer propagation distances are shown in hybrid plasmonic waveguides. However, existing designs for hybrid plasmonic waveguides predominantly rely on standard finite element simulation methods. Such methods are computationally intensive and inefficient, consequently hindering the development of novel device architectures. To address the limitation, this study developed a predictive model for the transmission characteristics of the triangle hybrid plasmonic waveguide by combining a dataset on the order of 10<sup>4</sup> elements generated via finite element simulations with a convolutional neural network (CNN). With different geometric parameters, the model delivers rapid and accurate predictions of key properties in hybrid triangular plasmonic waveguides, including the figure of merit, propagation length, normalized effective mode area, and the imaginary part of the effective refractive index for the triangular hybrid plasmonic waveguide. The approach accelerates simulations by approximately 6.05 × 10<sup>2</sup> times compared to traditional COMSOL simulations. Predictions from the CNN model demonstrate close agreement with COMSOL results, showing a higher R<sup>2</sup> value of 0.989, outperforming conventional machine learning methods. The model enables swift and precise determination of optimal structural dimensions, significantly reducing the costs of designing and fabricating triangular hybrid plasmonic waveguides. Additionally, the proposed model exhibits broad applicability and can serve as a transfer learning foundation for predicting analogous waveguide structures, thereby substantially contributing to the engineering deployment of hybrid plasmonic optical waveguides.</div></div>","PeriodicalId":100923,"journal":{"name":"Micro and Nanostructures","volume":"211 ","pages":"Article 208548"},"PeriodicalIF":3.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145939151","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-03-01Epub Date: 2026-01-08DOI: 10.1016/j.micrna.2025.208535
Sohail Mumtaz , Sameerah I. Al-Saeedi , Arfan Razzaq , Muhammad Imran , Muhammad Azhar Mumtaz , Amir Muhammad Afzal , M.A. Diab , Heba A. El-Sabban
{"title":"Corrigendum to “Designing CoTb2O4 electrodes integrated with MoTe2 and graphene for high-performance supercapacitors and HER catalysis” [Micro Nanostruct., 209 (2026) 208457]","authors":"Sohail Mumtaz , Sameerah I. Al-Saeedi , Arfan Razzaq , Muhammad Imran , Muhammad Azhar Mumtaz , Amir Muhammad Afzal , M.A. Diab , Heba A. El-Sabban","doi":"10.1016/j.micrna.2025.208535","DOIUrl":"10.1016/j.micrna.2025.208535","url":null,"abstract":"","PeriodicalId":100923,"journal":{"name":"Micro and Nanostructures","volume":"211 ","pages":"Article 208535"},"PeriodicalIF":3.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145939144","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}