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Chemical design of onion-like carbon-silicon diimide polymer composites 类洋葱碳硅二亚胺聚合物复合材料的化学设计
Pub Date : 2021-08-20 DOI: 10.1017/exp.2021.13
Kaili Wang, Gabriela Mera
Abstract Herein, we report the synthesis and characterization of a novel class of polymer composites based on onion-like carbons (OLCs)-silicon diimide by a salt-free polycondensation reaction. The pyridine-catalyzed polymerization reaction was carried out in the presence of various contents (0.1, 0.5, 1, and 2 wt%) of carboxyl-functionalized OLCs in argon atmosphere to provide composites with well-dispersed and covalently incorporated 0D nanocarbons throughout the 3D matrix of silicon diimide polymer. A strong dependency of the optical properties (UV absorbance and the photoluminescence spectra) on the content of functionalized OLCs incorporated within the polymer matrix was observed. The novel polymer composites are suitable precursors for the design of advanced and multifunctional 0D-nanocarbon–containing Si3N4-based ceramic nanocomposites.
摘要本文报道了一种新型的基于类洋葱碳(OLCs)-二亚胺硅的聚合物复合材料的合成和表征。在氩气气氛中,在不同含量(0.1、0.5、1和2 wt%)的羧基功能化有机碳的存在下,进行了吡啶催化的聚合反应,在硅二亚胺聚合物的三维基体中提供了分散和共价结合的0D纳米碳。光学性质(紫外吸光度和光致发光光谱)与聚合物基体中官能化聚合物的含量密切相关。这种新型聚合物复合材料是设计先进、多功能的含氮化硅纳米陶瓷复合材料的理想前驱体。
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引用次数: 0
Characterization of Philippine natural bentonite 菲律宾天然膨润土的表征
Pub Date : 2021-08-19 DOI: 10.1017/exp.2021.16
Eleanor M. Olegario, M. Gili
Abstract Philippine natural bentonite is characterized using X-ray diffractometer (XRD), scanning electron microscope (SEM), chemical analysis, thermogravimetric-differential scanning calorimetry (TG-DSC), and Fourier transform infrared (FTIR) analysis. The cation exchange capacity (CEC) was also measured. XRD shows that the mineral is composed primarily of mordenite, hectorite, and montmorillonite. SEM shows the flaky and porous structure of the bentonite powder. Chemical analyses show that SiO2 (47.90 wt%) and Al2O3 (14.02 wt%) are the major components of the clay. TG-DSC shows that the mineral contains 15.55% moisture. IR transmittance spectrum shows the common vibration bands present in the sample which include O–H stretching of inter-porous water, symmetric and asymmetric stretching of hydroxyl functional groups, asymmetrical stretching of internal tetrahedra (O–Si–O and O–Al–O), symmetrical stretching of external linkages, and so on. The measured CEC were found to be 91.37 and 43.01 meq/100 g according to the ammonium acetate method and barium acetate method, respectively.
摘要采用x射线衍射仪(XRD)、扫描电镜(SEM)、化学分析、热重-差示扫描量热法(TG-DSC)和傅里叶变换红外(FTIR)对菲律宾天然膨润土进行了表征。测定了阳离子交换容量(CEC)。XRD分析表明,该矿物主要由丝光沸石、辉石和蒙脱石组成。SEM显示膨润土粉体呈片状多孔结构。化学分析表明,SiO2 (47.90 wt%)和Al2O3 (14.02 wt%)是粘土的主要成分。TG-DSC表明,该矿物的水分含量为15.55%。红外透射光谱显示,样品中存在常见的振动带,包括孔间水的O-H拉伸、羟基官能团的对称和不对称拉伸、内部四面体(O-Si-O和O-Al-O)的不对称拉伸、外键的对称拉伸等。采用醋酸铵法和醋酸钡法测得CEC分别为91.37和43.01 meq/100 g。
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引用次数: 3
On the correction of temperatures derived from meteor wind radars due to geomagnetic activity 地磁活动对流星风雷达温度的校正
Pub Date : 2021-08-12 DOI: 10.1017/exp.2021.11
C. M. Hall, M. G. Johnsen
Abstract Radars used to observe meteor trails in the mesosphere deliver information on winds and temperature. Use of these radars is becoming a standard method for determining mesospheric dynamics and temperatures worldwide due to relatively low costs and ease of deployment. However, recent studies have revealed that temperatures may be overestimated in conditions such as high geomagnetic activity. The effect is thought to be most prevalent at high latitude, although this is not yet proven. Here, we demonstrate how temperatures might be corrected for geomagnetic effects; the demonstration is for a particular geographic location (Svalbard, 78°N, 16°E) because it is local geomagnetic disturbances that affects local temperature measurements, therefore requiring co-located instruments. We see that summer temperatures require a correction (reduction) of a few Kelvin, but winter estimates are more accurate.
用于观测中间层流星轨迹的雷达提供有关风和温度的信息。由于成本相对较低且易于部署,使用这些雷达正在成为全球范围内确定中间层动力学和温度的标准方法。然而,最近的研究表明,在高地磁活动等条件下,温度可能被高估了。这种效应被认为在高纬度地区最为普遍,尽管这一点尚未得到证实。在这里,我们演示了如何根据地磁效应对温度进行校正;该演示是针对一个特定的地理位置(Svalbard, 78°N, 16°E),因为它是局部地磁干扰,影响局部温度测量,因此需要同时放置仪器。我们看到夏天的温度需要修正(降低)几个开尔文,但冬天的估计更准确。
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引用次数: 0
Cloacal temperature responses of broiler chickens administered with fisetin and probiotic (Saccharomyces cerevisiae) and exposed to heat stress 饲喂非瑟酮和益生菌(酿酒酵母菌)并暴露于热应激的肉鸡肠道温度反应
Pub Date : 2021-08-02 DOI: 10.1017/exp.2021.15
V. O. Sumanu, T. Aluwong, J. Ayo, N. E. Ogbuagu
Abstract There is dearth information on the role of fisetin as an antistress agent in ameliorating heat stress in broiler chickens. Here, we experimentally compared probiotic, an antioxidant and antistress agent, with fisetin, an antioxidant agent with little or no report on its antistress effect. Sixty-day-old broiler chickens (Arbo Acre breed) were allotted into 4 groups of 15 birds each as follows; control, fisetin, probiotic, and fisetin + probiotic groups, respectively. All administrations were performed orally through gavage for the treatment groups. The environmental and cloacal temperature (CT) parameters were measured bi-hourly at Days 21, 28, and 35 from 7:00 to 7:00 hr, during the period of study. The environmental parameters exceeded the thermoneutral zone for broiler chickens. The probiotic-supplemented group had the least overall mean CT values all through the experimental period. Based on our findings, fisetin was not a potent antistress agent in mitigating heat stress in birds.
非瑟酮作为一种抗应激剂,在改善肉鸡热应激中的作用尚缺乏相关信息。在这里,我们实验比较了益生菌,一种抗氧化剂和抗应激剂,与非瑟酮,一种抗氧化剂,其抗应激作用很少或没有报道。选用60日龄Arbo Acre品种肉鸡,随机分为4组,每组15只;对照组、非瑟酮组、益生菌组和非瑟酮+益生菌组。治疗组均采用灌胃给药。在研究期间的第21、28和35天,从7:00到7:00,每隔2小时测量一次环境和肛管温度(CT)参数。环境参数超出了肉仔鸡的热中性区。在整个实验期间,益生菌补充组的总体平均CT值最低。根据我们的研究结果,非瑟酮在减轻鸟类热应激方面不是一种有效的抗应激剂。
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引用次数: 5
Dietary ascorbic acid and betaine improve stress responses, testosterone levels and some sexual traits in male Japanese quails during the dry season 在旱季,饲粮中添加抗坏血酸和甜菜碱可改善雄性日本鹌鹑的应激反应、睾酮水平和某些性特征
Pub Date : 2021-07-26 DOI: 10.1017/exp.2021.10
I. C. Egbuniwe, C. Uchendu, I. Obidike
Abstract The experiment investigated the effects of dietary ascorbic acid and betaine stress responses, serum testosterone levels, and some sexual traits in male Japanese quails during the dry season. A total of 240 male Japanese quails (14 days old) were used and randomly assigned to four groups, each group has three replicates (n = 20). Birds in treatment groups were fed ascorbic acid (AA); betaine (BET); and AA + BET in their diets, whereas the control birds were fed only basal diet. Environmental conditions were predominantly outside thermoneutral zone for Japanese quails. Dietary AA ± BET increased (p < .05) serum catalase, reduced glutathione and testosterone, but lowered (p < .05) cortisol levels when compared with control group. Supplemental AA, BET, or AA + BET enhanced (p < .05) cloacal gland size and sexual traits. In conclusion, dietary AA and BET improved stress responses, serum testosterone levels, and some sexual traits in male Japanese quails during the dry season.
摘要本试验旨在研究旱季日粮抗坏血酸和甜菜碱应激反应、血清睾酮水平和雄性日本鹌鹑部分性性状的影响。选用14日龄雄性日本鹌鹑240只,随机分为4组,每组3个重复(n = 20)。各处理组饲喂抗坏血酸(AA);甜菜碱(打赌);AA + BET,对照组只饲喂基础饲粮。环境条件以热中性区外为主。与对照组相比,饲粮AA±BET提高了血清过氧化氢酶(p < 0.05)、降低了谷胱甘肽和睾酮水平(p < 0.05),降低了皮质醇水平(p < 0.05)。添加AA、BET或AA + BET可提高(p < 0.05)阴囊腺的大小和性征。由此可见,饲粮中添加AA和BET可改善旱季雄性日本鹌鹑的应激反应、血清睾酮水平和部分性性状。
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引用次数: 3
Radiation dose to the heart with hypofractionation in patients with left breast cancer 左乳腺癌患者低分割对心脏的辐射剂量
Pub Date : 2021-07-14 DOI: 10.1017/exp.2021.8
B. Yadav, D. Das, Narendra Kumar, M. Singhal, N. Robert
Abstract Introduction In this study we compared radiation dose received by organs at risk (OARs) after breast conservation surgery(BCS) and mastectomy in patients with left breast cancer. Materials and methods Total 30 patients, 15 each of BCS and mastectomy were included in this study. Planning Computerised Tomography (CT) was done for each patient. Chest wall, whole breast, heart, lungs, LAD, proximal and distal LAD, and contra lateral breast was contoured for each patient. Radiotherapy plans were made by standard tangent field. Dose prescribed was 40Gy/16#/3 weeks. Mean heart dose, LAD, proximal and distal LAD, mean and V5 of right lung, and mean, V5, V10 and V20 of left lung, mean dose and V2 of contra lateral breast were calculated for each patient and compared between BCS and mastectomy patients using student’s T test. Results Mean doses to the heart, LAD, proximal LAD and distal LAD were 3.364Gy, 16.06Gy, 2.7Gy, 27.5Gy; and 4.219Gy, 14.653Gy, 4.306Gy, 24.6Gy, respectively for mastectomy and BCS patients. Left lung mean dose, V5, V10 and V20 were 5.96Gy, 16%, 14%, 12.4%; and 7.69Gy, 21%, 18% and 16% in mastectomy and BCS patients, respectively. There was no statistical significant difference in the doses to the heart and left lung between mastectomy and BCS. Mean dose to the right lung was significantly less in mastectomy as compared to BCS, 0.29Gy vs. 0.51Gy, respectively (p = 0.007). Mean dose to the opposite breast was significantly lower in patients with mastectomy than BCS (0.54Gy Vs 0.37Gy, p = 0.007). The dose to the distal LAD was significantly higher than proximal LAD both in BCS (24.6Gy Vs 4.3Gy, p = <0.0001) and mastectomy (27.5Gy Vs 2.7Gy, p = <0.0001) patients. Conclusion There was no difference in doses received by heart and left lung between BCS and mastectomy patients. Mean doses to the right lung and breast were significantly less in mastectomy patients.
摘要:在本研究中,我们比较了左乳腺癌患者保乳手术(BCS)和乳房切除术后危险器官(OARs)接受的辐射剂量。材料与方法本研究共纳入30例患者,BCS和乳房切除术各15例。对每位患者进行计划计算机断层扫描(CT)。对每位患者的胸壁、全乳、心脏、肺、LAD、LAD近端和远端以及对侧乳房进行轮廓。采用标准切线场制定放疗方案。处方剂量为40Gy/16#/3周。计算每例患者的平均心脏剂量、LAD、近端和远端LAD、右肺平均、V5、左肺平均、V5、V10、V20、对侧乳腺平均剂量、V2,并采用学生T检验比较BCS与乳腺切除术患者的差异。结果心脏、LAD、LAD近端、LAD远端平均剂量分别为3.364Gy、16.06Gy、2.7Gy、27.5Gy;乳腺切除术和BCS患者分别为4.219Gy、14.653Gy、4.306Gy、24.6Gy。左肺平均剂量、V5、V10、V20分别为5.96Gy、16%、14%、12.4%;7.69Gy,乳腺切除术和BCS患者分别为21%、18%和16%。乳腺切除术和BCS对心脏和左肺的剂量无统计学差异。与BCS相比,乳房切除术中右肺的平均剂量显著减少,分别为0.29Gy和0.51Gy (p = 0.007)。乳房切除术患者的对侧平均剂量明显低于BCS患者(0.54Gy Vs 0.37Gy, p = 0.007)。在BCS (24.6Gy Vs 4.3Gy, p = <0.0001)和乳房切除术(27.5Gy Vs 2.7Gy, p = <0.0001)患者中,远端LAD的剂量均显著高于近端LAD。结论BCS与乳腺切除术患者的心脏和左肺接受剂量无差异。乳房切除术患者对右肺和乳房的平均剂量明显减少。
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引用次数: 1
Xanthene-stained nanoparticles for phosphorescence anisotropy measurements 用于磷光各向异性测量的杂蒽染色纳米颗粒
Pub Date : 2021-07-07 DOI: 10.1017/exp.2021.12
Markus J Schmidt, T. Rösgen
Abstract For the measurement of flow-induced microrotations in flows utilizing the depolarization of phosphorescence anisotropy, suitable luminophores are crucial. The present work examines dyes of the xanthene family, namely Rhodamine B, Eosin Y and Erythrosine B. Both in solution and incorporated in particles, the dyes are examined regarding their luminescent lifetimes and their quantum yield. In an oxygen-rich environment at room temperature, all dyes exhibit lifetimes in the sub-microsecond range and a low intensity signal, making them suitable for sensing fast rotations with sensitive acquisition systems.
摘要:利用磷光各向异性去极化测量流动中引起的微旋转,合适的发光团是至关重要的。本研究考察了杂蒽家族的染料,即罗丹明B、伊红Y和红红B。无论是在溶液中还是在颗粒中,染料都考察了它们的发光寿命和量子产率。在室温富氧环境中,所有染料都表现出亚微秒范围内的寿命和低强度信号,使它们适用于敏感采集系统的快速旋转传感。
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引用次数: 0
Productive efficiency of traditional multiple cropping systems compared to monocultures of seven crop species: a benchmark study 传统复种制度与7种作物单一栽培的生产效率比较:一项基准研究
Pub Date : 2021-06-04 DOI: 10.1017/exp.2021.7
Debal Deb
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引用次数: 2
On the temporal evolution of turbopause altitude, 1996–2021, 70°N, 19°E 湍流顶高度1996-2021年,70°N, 19°E的时间演变
Pub Date : 2021-06-04 DOI: 10.1017/exp.2021.6
C. M. Hall, S. Nozawa
Abstract Medium frequency radars with multiple receivers are able to track the movement of the interference pattern on the ground from echoes from irregularities in refractive index. In particular, refractive index in the mesosphere is determined by electron density – commonly known as the ionospheric D-region. Thus using this technique it is possible to determine winds in the height regime 70-90 km, depending on the degree of ionization throughout the year. In addition, by examining the fading times of the passage of these structures, it is possible to deduce metrics pertaining to neutral air turbulence. Here, we employ a well-established method to this effect. Thereafter, comparing the turbulent intensity to the kinematic viscosity of the neutral atmosphere, we determine the turbopause altitude. Above this height, atmospheric constituents behave independently, whereas below, all components are mixed. Contrary to earlier analyses, we present evidence the turbopause altitude has been constant since approximately 2004.
多接收机中频雷达能够从折射率不规则回波中跟踪地面干涉图样的运动。特别是,中间层的折射率是由电子密度决定的——通常被称为电离层d区。因此,根据全年的电离程度,使用这种技术可以确定70-90公里高度范围内的风。此外,通过检查这些结构通过的衰落时间,可以推断出与中性空气湍流有关的指标。在这里,我们采用一种行之有效的方法来达到这一效果。然后,将湍流强度与中性大气的运动粘度进行比较,确定了湍流顶高度。在这个高度以上,大气成分的行为是独立的,而在这个高度以下,所有成分都是混合的。与先前的分析相反,我们提出的证据表明,自大约2004年以来,涡顶高度一直保持不变。
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引用次数: 0
The effect of ultrafiltration transmembrane permeation on the flow field in a surrogate system of an artificial kidney 超滤跨膜渗透对人工肾脏替代系统流场的影响
Pub Date : 2021-03-30 DOI: 10.1017/exp.2021.5
Matilde De Pascale, Mónica Faria, C. Boi, V. Semião, M. N. de Pinho
Abstract Renal Replacement Therapies generally associated to the Artificial Kidney (AK) are membrane-based treatments that assure the separation functions of the failing kidney in extracorporeal blood circulation. Their progress from conventional hemodialysis towards high-flux hemodialysis (HFHD) through the introduction of ultrafiltration membranes characterized by high convective permeation fluxes intensified the need of elucidating the effect of the membrane fluid removal rates on the increase of the potentially blood-traumatizing shear stresses developed adjacently to the membrane. The AK surrogate consisting of two-compartments separated by an ultrafiltration membrane is set to have water circulation in the upper chamber mimicking the blood flow rates and the membrane fluid removal rates typical of HFHD. Pressure drop mirrors the shear stresses quantification and the modification of the velocities profiles. The increase on pressure drop when comparing flows in slits with a permeable membrane and an impermeable wall is ca. 512% and 576% for $ mathrm{CA}22/5%{mathrm{SiO}}_2 $ and $ mathrm{CA}30/5%{mathrm{SiO}}_2 $ membranes, respectively.
肾脏替代疗法通常与人工肾(AK)相关,是基于膜的治疗,确保衰竭肾脏在体外血液循环中的分离功能。通过引入以高对流渗透通量为特征的超滤膜,他们从传统血液透析向高通量血液透析(HFHD)的发展,加强了阐明膜液去除率对膜附近形成的潜在血液创伤剪应力增加的影响的必要性。AK替代物由超滤膜分离的两个室组成,在上室设置水循环,模拟HFHD典型的血液流动速率和膜液去除速率。压降反映了剪切应力的量化和速度剖面的变化。$ mathrm{ca}22/5%{mathrm{SiO}}_2 $和$ mathrm{ca}30/5%{mathrm{SiO}}_2 $膜缝内流动的压降增幅分别为512%和576%。
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引用次数: 5
期刊
Experimental Results
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