Journal of Hazardous Materials最新文献

Resourceful treatment of wastewater is a promising way to facilitate sustainable development. Recently, photocatalytic fuel cells (PFCs) have attracted widespread attention as the method that can synchronously achieve wastewater treatment and clean energy production only depend on light. However, few PFCs focused on treating complex uranium (U(VI))-organic wastewater. This study prepared a SnS₂ nanoplate decorated carbon felt (SnS₂/CF) material by facile hydrothermal method and used as the cathode to construct a hybrid tandem photocatalytic fuel cell (HTPFC) system. Compared to the CF-HTPFC, the removal efficiencies of U(VI) and tetracycline hydrochloride (TCH) increased to 3.4 and 1.8 times in the SnS₂/CF-HTPFC system, accompanied with the reaction rate (k_obs) values increased to 30.39 and 3.78 times, respectively. More importantly, under real sunlight irradiation (From 10:00 to 16:00), the removal efficiencies of U(VI) and TCH respectively reached 92.49 % and 97.96 %, and the P_max reached 6.49 mW·cm⁻². HTPFC also displayed satisfactory performances in treating radioactive wastewater containing different organic compounds, with the removal efficiencies of U(VI) and organic compounds both exceeded 93.35 %. The loading of SnS₂ nanoplates enhanced electrochemical performance and introduced abundant S active sites, allowing more U(VI) to be adsorbed and reduced, and simultaneously promoting the removal of organic matter by improving the charge separation efficiency.

Humankind are being exposed to a cocktail of chemicals, such as chemicals released from plastic food packaging. It is of great importance to evaluate the prevalence of plastic food packaging-derived chemicals pollution along the flow of food-human. We developed a robust and practical database of 2101 chemical features associated with plastic food packaging that combined data from three sources, 925 of which were acquired from non-target screening of chemical extracts from eight commonly used plastic food packaging materials. In this database, 625 features, especially half of the non-targets, were potential migrants who likely entered our bodies through dietary intake. Biomonitoring analysis of plastic chemical features in foodstuffs or human serum samples showed that approximately 78 % of the 2101 features were detectable and approximately half were non-targets. Of these, 17 plastic chemicals with high detection frequencies (DFs) in the human serum were confirmed to be functional chemical additives. Together, our work indicates that the number of plastic chemicals in our bodies could be far greater than previously recognized, and human exposure to plastic chemicals might pose a potential health risk.

Bensulfuron methyl (BSM) residues have caused serious yield reductions of sensitive crops. Chemical oxidation is an effective remediation technology, while it affects soil quality and subsequent agricultural activity, necessitating approriate improvement measures. So Fe₂O₃-Mn₃O₄ with excellent bimetallic synergistic effect was synthesized to activate peroxymonosulfate (PMS) for BSM degradation. The catalytic activity and influencing factors were systematically predetermined in water in view of soil remediation. Results showed Fe₂O₃-Mn₃O₄/PMS oxidized 99.3 % BSM within 60 min with the help of multi-reactive species and electron transfer. Meanwhile, Fe₂O₃-Mn₃O₄/PMS treatment exhibited technical feasibility in soil that 97.6 % BSM was degraded in 5 days under the low usages of Fe₂O₃-Mn₃O₄ (0.8 %) and PMS (0.15 %). Although Fe₂O₃-Mn₃O₄/PMS decreased BSM phytotoxicity and improved maize growth, a few gaps existed between the remediated group and uncontaminated group, including biomass, length, available potassium, organic matters, pH, redox potential (Eh) and sulfate content. The introductions of biochar and chitosan in remediated soils promoted growth, increased organic matters content, improved soil resistance to acidification and decreased Eh, alleviating the negative effects of Fe₂O₃-Mn₃O₄/PMS. Overall, the study provided new insights into the combination of Fe₂O₃-Mn₃O₄/PMS and biochar and chitosan in BSM-contaminated soil, achieving BSM degradation and improvements of soil quality and plant growth.

Biomineralization techniques have been utilized to remediate heavy metals (HMs) contaminated environments. However, the effect of microbial-induced phosphate precipitation (MIPP) on HMs behavior in vanadium tailing slags has not been revealed. This study is the first to report the influence of MIPP on multiple HMs including Cd, Cu, Pb and Zn in the slags with and without soil mixing. The results showed that MIPP exhibited excellent ability for Cd immobilization, Cd immobilization rate reached 43.41 % under the optimal parameters within 7 days. Cd immobilization performance was significantly improved and sustained after the slags were covered with soil, resulting from better colonization of phosphate mineralizing bacteria in slag-soil mixtures. Surprisingly, DTPA-Cu, Zn and Pb contents in slags were all increased to varying degrees after MIPP treatment. Leaching solution mineralization tests further suggested that MIPP significantly reduced the concentration of Cd²⁺, Pb²⁺, Ca²⁺, Mg²⁺ and Al³⁺, but barely changed Cu²⁺ and Zn²⁺ concentrations. Characterization analysis confirmed that formation of phosphates including Cd(PO₄)₂ and dissolution of minerals including PbZnSiO₂ were the reason for HMs immobilization and mobilization in vanadium tailing slags. This study provides new insights for understanding biomineralization technology and using MIPP to remediate HMs contaminated mine waste.

The impact of co-occurring heavy metal (HM) and microplastic (MP) pollution on methane (CH₄) oxidation by methanotrophs (MOB) in landfill cover soil (LCS) and the role of biochar in mediating these collaborative transformations remains unclear. This study conducted batch-scale experiments using LCS treated with individual or combined HMs and MPs, with or without biochar amendment. Differentiation in methanotrophic activities, HM transformations, MP aging, soil properties, microbial communities, and functional genes across the groups were analyzed. Biochar proved essential in sustaining efficient CH₄ oxidation under HM and MP stress, mainly by diversifying MOB, and enhancing polysaccharide secretion to mitigate environmental stress. While low levels of HMs slightly inhibited CH₄ oxidation, high HM concentration enhanced methanotrophic activities by promoting electron transfer process. MPs consistently stimulated CH₄ oxidation, exerting a stronger influence than HMs. Notably, the simultaneous presence of low levels of HMs and MPs synergistically boosted CH₄ oxidation, linked to distinct microbial evolution and adaptation. Methanotrophic activities were demonstrated to affect the fate of HMs and MPs. Complete passivation of Cu was readily achieved, whereas Zn stabilization was negatively influenced by biochar and MPs. The aging of MPs was also partially suppressed by biochar and HM adsorption.

The co-occurrence of nutrients and pharmaceuticals and personal care products (PPCPs) in sewage effluent can degrade water quality of the receiving watersheds. This study investigated the simultaneous removal of excess nutrients and PPCP contaminants by developing a novel woodchip bioreactor and biochar (B²) treatment system. The result revealed that woodchip bioreactors could effectively remove nitrate via a denitrification process and adsorb some PPCPs. Biochar as a secondary treatment system significantly reduced the concentrations of PPCPs and dissolved reactive phosphorus (DRP) (p < 0.05), compared to the woodchip bioreactor. The removal efficiencies of all targeted contaminants by the B² system were evaluated using various hydraulic retention times (HRTs) and biochar types (pelletized versus granular biochar). Longer HRTs and smaller biochar particles (granular biochar) could enhance the removal efficiencies of targeted contaminants. Average contaminant removals were 77.25 % for nitrate-N, 99.03 % for DRP, 69.51 % for ibuprofen, 73.65 % for naproxen, 91.09 % for sitagliptin, and 96.96 % for estrone, with woodchip bioreactor HRTs of 12 ± 1.4 h and granular biochar HRTs of 2.1 ± 0.1 h. Notably, the second-stage biochar systems effectively mitigated by-products leaching from woodchip bioreactors. The presence of PPCPs in the woodchip bioreactors enriched certain species, such as Methylophilus (69.6 %), while inhibiting other microorganisms and reducing microbial community diversity. Furthermore, a scaled-up B² system was analyzed and assessed, indicating that the proposed engineering treatment system could provide decades of service in real-world applications. Overall, this study suggests that the B² system has promising applications for addressing emerging and conventional contaminants.

Flumethrin mitigates Varroa’s harm to honeybee colonies; however, its residues in colonies threaten the fitness of honeybee hosts and gut microbiota. Our previous research has shown that flumethrin induces significant physiological effects on honeybee larvae; but the effects of flumethrin on the gut microbiota and metabolism of adult honeybees are still unknown. In this study, 1-day-old honeybees were exposed to 0, 0.01, 0.1, and 1 mg/L flumethrin for 14 days and the impacts of flumethrin on the intestinal system were evaluated. The results showed that exposure to 1 mg/L flumethrin significantly reduced honeybee survival and the activities of antioxidative enzymes (superoxide dismutase and catalase) and detoxification enzymes (glutathione S-transferase) in honeybee heads. Moreover, exposure to 0.01, 0.1, and 1 mg/L flumethrin significantly decreased the diversity of the honeybee gut microbiota. Results from untargeted metabolomics showed that long-term exposure to 0.01, 0.1, and 1 mg/L flumethrin caused changes in the metabolic pathways of honeybee gut microbes. Furthermore, increased metabolism of phenylalanine, tyrosine, and tryptophan derivatives was observed in honeybee gut microbes. These findings underscore the importance of careful consideration in using pesticides in apiculture and provide a basis for safeguarding honeybees from pollutants, considering the effects on gut microbes.

Microbial remediation of heavy metal (HM)-contaminated soil is a sustainable approach; however, the impact of microbial inoculation on the internal environment of plants remains understudied. Thus, Enterobacter sp. FM-1 (Enterobacter sp.) and the hyperaccumulator Bidens pilosa L. (B. pilosa L.) were used to study these effects. Through analyses of plant physiological and biochemical characteristics, the endophytic microbial community composition, microbial co-occurrence networks and functional predictions, the potential mechanisms by which Enterobacter sp. benefits the phytoremediation of HM-contaminated soil by B. pilosa L. were elucidated. Inoculation with Enterobacter sp. promoted the growth of B. pilosa L. and influenced the endophytic microbial community diversity in B. pilosa L. Interactions among endophytes facilitated the formation of microbial networks, with endophytic fungi playing a more prominent role than endophytic bacteria as the level of HM contamination increased. Functional predictions via PICRUSt2 revealed that endophytic bacteria are involved primarily in processes related to carbohydrate metabolism, ABC transporters, and amino acid metabolism. In conclusion, this study provides evidence for the beneficial role of microbes in improving the plant endosphere environment.

Dissolved organic matter (DOM) present in aquatic environments can significantly influence microalgal metabolism and the enrichment of heavy metals. However, the specific mechanism through which typical DOM affects the enrichment of the heavy metal chromium (Cr) in green algae remains unclear. This study investigates the impacts of varying concentrations of humic acid (HA), selected as a representative DOM in water, on the growth, metabolism, and Cr enrichment in Chlorella vulgaris, a typical green alga. The results indicated that low concentrations of HA were capable of enhancing Cr enrichment in C. vulgaris, with the highest Cr enrichment rate recorded at 41.50 % at TOC = 10 mg/L. The enrichment of Cr in algal cells primarily occurred through cell proliferation and complexation reduction of extracellular polymeric substances (EPS). In the presence of HA, C. vulgaris predominantly removed Cr through extracellular adsorption, accounting for 79.76–85.88 % of the total Cr removal. Furthermore, carboxyl complexation and hydroxyl reduction within EPS facilitated both the enrichment of Cr (18.72–21.49 %) and the reduction of Cr(VI) (63.93–74.10 %). These findings provide valuable insights into strategies for mitigating heavy metal pollution and managing associated risks in aquatic environments.

The distribution characteristics of Cr(VI) species in contaminated soil is crucial for soil remediation; however, there is currently a lack of methods for analysing anionic Cr(VI) species in soil. This study has developed a novel sequential extraction method for speciation of Cr(VI) and Cr(III). Besides extraction experiments, simulated chromium species were prepared to verify the presence of proposed chromium species. The results show that Cr(VI) species in soil can be categorized into water-soluble Cr(VI), electrostatically adsorbed Cr(VI), Cr(VI) specifically adsorbed by minerals containing exchangeable Ca²⁺, Cr(VI) specifically adsorbed by hydrous metal oxides, calcium chromate Cr(VI) and stable complexed adsorption Cr(VI). These Cr(VI) species can be selectively extracted by specific solutions through ion exchange or weak acid dissolution. The most stable Cr(VI) species is Cr(VI) complexed by hydrous iron oxides through bidentate ligand binding; only by dissolution of hydrous iron oxides can this Cr(VI) species be leached. The distribution of Cr(VI) species is closely linked to particular soil compositions including exchangeable Ca²⁺ and hydrous iron oxides which determinate the Cr(VI) adsorption in soil. Cr(III) species comprise Fe-Cr coprecipitate hydroxides Cr(III), Fe-Mn oxide-bound Cr(III), organic matter-bound Cr(III) and residual Cr(III). Their distribution depends on the types of reductants present in the soil.