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Cathode with a temperature-switchable interlayer for thermally self-regulating smart lithium-ion batteries 具有温度可切换中间层的阴极,用于热自动调节智能锂离子电池
IF 17 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-12-01 Epub Date: 2025-09-15 DOI: 10.1016/j.etran.2025.100483
Kehan Le , Chunchun Sang , Qijun Luo , Hui Li , Yongjin Fang , Xinping Ai
Thermal safety is crucial for the large-scale application of lithium-ion batteries (LIBs) in electric vehicles and energy storage stations. To boost thermal safety of LIBs, we propose herein a reversible temperature-responsive membrane (RTRM) and use this membrane as surface-modification layer of current collector to develop temperature-responsive cathodes. The RTRM is fabricated by uniformly dispersing conductive fillers of short-cut carbon fibers (CCFs) in a blended plastic matrix of low-density polyethylene (LDPE) and ultra-high molecular weight polyethylene (UHMWPE) through solution casting. Benefiting from the large thermal expansion provided by LDPE and good structural reproducibility given rise by the ultra-high melt viscosity of UHMWPE, the as-fabricated RTRM exhibits a strong and reversible positive temperature coefficient (PTC) effect, with its resistivity increasing sharply by 7.1 orders of magnitude at 110–120 °C and returning to the initial value reversibly upon cooling down even after 30 thermal cycles. As a result, the LiFePO4 cathode with the RTRM demonstrates a reversible temperature-switching behavior by spontaneously halting the electrode reaction at elevated temperatures and resuming the electrode reaction upon cooling, thereby providing reversible thermal protection for LIBs. Notably, such a temperature-switchable cathode maintains normal charge-discharge performance even after 28 thermal on/off cycles. This study offers a promising strategy for developing temperature-responsive cathode and thermally self-regulating smart LIBs.
热安全对于锂离子电池在电动汽车和储能站的大规模应用至关重要。为了提高锂离子电池的热安全性,我们提出了一种可逆的温度响应膜(RTRM),并将该膜作为集流器的表面修饰层来制备温度响应阴极。RTRM是在低密度聚乙烯(LDPE)和超高分子量聚乙烯(UHMWPE)混合塑料基体中均匀分散导电短切碳纤维(CCFs),通过溶液浇铸法制备的。得益于LDPE的大热膨胀和超高熔体粘度带来的良好结构再现性,制备的RTRM表现出强烈的可逆正温度系数(PTC)效应,其电阻率在110-120℃时急剧增加7.1个数量级,即使在30个热循环后冷却后也能可逆地恢复到初始值。结果表明,具有RTRM的LiFePO4阴极具有可逆的温度开关行为,在高温下自发停止电极反应,冷却后恢复电极反应,从而为锂离子电池提供可逆的热保护。值得注意的是,这种温度可切换阴极即使在28次热开/关循环后也能保持正常的充放电性能。该研究为开发温度响应阴极和热自调节智能锂离子电池提供了一种有前途的策略。
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引用次数: 0
Multi-parameter degradation of PEMFCs in freeze/thaw cycles: Impacts of assembly force and initial membrane water content on cold start durability for transportation applications 冻融循环中pemfc的多参数退化:装配力和初始膜含水量对运输应用冷启动耐久性的影响
IF 17 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-12-01 Epub Date: 2025-10-24 DOI: 10.1016/j.etran.2025.100505
Lei Shi , Ruitao Li , Chang Du , Julong Zhou , Yahui Yi , Ze Liu , Jianbin Su , Liqin Qian , Tiancai Ma , Shijia Yang , Chengyu Xia , Xingwang Tang
The adaptability of fuel cell vehicles in extreme low-temperature environments remains a critical challenge urgently requiring breakthroughs in the transportation sector. As a core factor influencing low-temperature operational reliability, freeze/thaw cycles directly impact the performance stability and service life of fuel cells, and hold decisive significance for advancing the popularization and application of fuel cell vehicles in cold regions. This study investigates the degradation mechanisms of fuel cells subjected to freeze/thaw cycles under varying initial membrane dissolved water content and assembly force conditions. Building on three preliminary experiments-initial water content calibration, freezing time retardation analysis, and initial microstructure characterization of the catalytic layer and gas diffusion layer-a 100-h freeze/thaw test was conducted. Electrochemical impedance spectroscopy, cyclic voltammetry, and other characterization techniques were employed to assess the fuel cell degradation process. The degradation rate during freeze/thaw cycles was quantified using the distribution of relaxation times method and electrochemical active surface area. High-magnification optical microscopy and scanning electron microscopy were utilized to examine the microstructure of disassembled gas diffusion layers post-freeze/thaw cycles, offering insights into structural damage to both the catalytic layer and gas diffusion layer. Results reveal that higher assembly forces exacerbate gas diffusion layer degradation, leading to slower mass transport and increased mass transport resistance-with the distribution of relaxation times low-frequency peak rising by 202 % under a 13 N m assembly force after 5 cycles. Additionally, higher initial membrane dissolved water content slightly accelerates GDL degradation and significantly contributes to catalytic layer degradation, as evidenced by a 29 % reduction in electrochemical active surface area for 100 % initial water content after 5 cycles. The degradation mechanisms of fuel cells under freeze-thaw cycles revealed in this study provide crucial support for improving the low-temperature reliability of fuel cell vehicles in the transportation sector and promoting their commercialization and application in cold regions.
燃料电池汽车在极端低温环境下的适应性仍然是交通运输领域急需突破的关键挑战。冻融循环作为影响燃料电池低温运行可靠性的核心因素,直接影响燃料电池的性能稳定性和使用寿命,对推进燃料电池汽车在寒冷地区的推广应用具有决定性意义。本研究探讨了不同初始膜溶解水含量和组装力条件下燃料电池在冻融循环下的降解机理。在初始含水量标定、冻结时间延迟分析、催化层和气体扩散层初始微观结构表征三个初步实验的基础上,进行了100 h冻融试验。利用电化学阻抗谱、循环伏安法和其他表征技术对燃料电池的降解过程进行了评价。利用弛豫时间分布法和电化学活性表面积对冻融循环过程中的降解速率进行了量化。利用高倍光学显微镜和扫描电子显微镜对冻融循环后分解的气体扩散层的微观结构进行了观察,从而深入了解了催化层和气体扩散层的结构破坏情况。结果表明,较高的装配力加剧了气体扩散层的降解,导致质量输运变慢和质量输运阻力增加,在13 N m装配力下,5次循环后,低频峰的弛豫次数分布增加了202%。此外,较高的初始膜溶解水含量会略微加速GDL的降解,并显著促进催化层的降解。5个循环后,当初始水含量达到100%时,电化学活性表面积减少29%。本研究揭示的燃料电池在冻融循环下的降解机理,为提高燃料电池汽车在交通运输领域的低温可靠性,促进其在寒冷地区的商业化应用提供了重要支持。
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引用次数: 0
Towards real-world battery health intelligence: A review of machine learning advances and challenges in SOH estimation 面向现实世界的电池健康智能:SOH估计中机器学习的进展和挑战的综述
IF 17 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-12-01 Epub Date: 2025-11-04 DOI: 10.1016/j.etran.2025.100509
Xing Shu , Jiangwei Shen , Fengxiang Guo , Yonggang Liu , Yuanjian Zhang , Zheng Chen , Hongqian Zhao
Lithium-ion batteries have become the dominant power source in electric transportation due to their high energy density and long cycle life. Nevertheless, prolonged operation leads to irreversible degradation, and results in capacity fade and safety risks. Accurate estimation of state of health (SOH) is therefore critical for ensuring reliable electric vehicle operation and for guiding maintenance strategies. In recent years, extensive research has been devoted to SOH estimation, supported by both laboratory investigations and field applications. Unlike previous reviews that mainly focus on either laboratory data or algorithmic modeling, this review uniquely bridges the gap between lab-based methods and practical applications using real vehicle operational data by providing a comparative analysis of datasets, estimation methods, and application challenges. A systematic survey of recent advances is provided in lithium-ion battery SOH estimation. First, accelerated aging experiments under laboratory conditions and operational data acquisition in real-world scenarios are reviewed and compared. The extraction of health features, feature optimization, and dimensionality reduction techniques are elaborated. Second, the progress in modeling methods is summarized, including shallow neural networks, convolutional neural networks, recurrent neural networks, attention-based networks, and physics-informed networks. Third, SOH label acquisition methods and estimation approaches for real-world datasets are analyzed. Finally, three major challenges are discussed for improving SOH estimation accuracy in practice, including bridging the gap between laboratory and real-world conditions, achieving more reliable SOH labeling, and reducing the dependence on large-scale training data.
锂离子电池因其能量密度高、循环寿命长等优点,已成为电动交通领域的主导电源。然而,长时间的运行会导致不可逆的老化,并导致产能衰退和安全风险。因此,准确估计健康状态(SOH)对于确保电动汽车可靠运行和指导维护策略至关重要。近年来,在实验室研究和现场应用的支持下,对SOH估算进行了广泛的研究。与以往主要关注实验室数据或算法建模的综述不同,本综述通过对数据集、估计方法和应用挑战的比较分析,独特地弥合了基于实验室的方法与使用真实车辆运行数据的实际应用之间的差距。对锂离子电池SOH估算的最新进展进行了系统的综述。首先,对实验室条件下的加速老化实验和现实场景下的操作数据采集进行了回顾和比较。阐述了健康特征的提取、特征优化和降维技术。其次,总结了建模方法的进展,包括浅神经网络、卷积神经网络、循环神经网络、基于注意力的网络和物理信息网络。第三,分析了真实数据集的SOH标签获取方法和估计方法。最后,讨论了在实践中提高SOH估计精度的三个主要挑战,包括弥合实验室和现实条件之间的差距,实现更可靠的SOH标记,以及减少对大规模训练数据的依赖。
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引用次数: 0
Atmosphere-regulated thermal runaway characteristics and multidimensional safety assessment of sodium-ion and lithium-ion batteries 钠离子和锂离子电池大气调节热失控特性及多维安全评价
IF 17 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-12-01 Epub Date: 2025-09-06 DOI: 10.1016/j.etran.2025.100475
Zhixiang Cheng, Zhiyuan Li, Yuxuan Li, Yin Yu, Chaoshi Liu, Zhenwei Wu, Peiyu Duan, Huang Li, Wenxin Mei, Qingsong Wang
Understanding and quantifying the thermal runaway behavior of emerging battery chemistries is essential for ensuring safety in real-world applications. This study systematically investigates the thermal runaway characteristics of sodium-ion (SIB) and lithium-ion (LIB) batteries of comparable volumes under both air and inert gas environments. Experimental results show that under low-oxygen conditions, SIB and nickel–cobalt–manganese (NCM) cells exhibit substantial mitigation of thermal runaway severity, including over 35 % decrease in gas generation metrics, while lithium iron phosphate (LFP) cells remain largely unaffected. In gas composition analysis, NCM cells show significant decreases in CO2/CO and O2/N2 ratios, whereas SIB and LFP display no notable compositional changes. Based on experimental data and literature, a multidimensional database of thermal runaway parameters is developed, incorporating metrics such as gas explosiveness, toxicity, and heat of combustion. Three classical multi-criteria evaluation methods—Technique for Order Preference by Similarity to Ideal Solution, Principal Component Analysis, and a median-based approach—are applied and compared. To address limitations arising from dimensional and variance scale differences among parameters, an expected contribution method is proposed to enable balanced and consistent scoring. Results demonstrate that this method enhances fairness and interpretability, particularly in scenarios with substantial scale disparities among variables arising from cross-battery systems. This work establishes a quantitative safety assessment framework that enables cross-platform comparisons and provides guidance for battery system design, risk zoning, and thermal mitigation strategies. The framework is broadly applicable to emerging battery chemistries and advances battery safety evaluation across diverse application environments.
理解和量化新兴电池化学物质的热失控行为对于确保实际应用中的安全性至关重要。本研究系统地研究了同等体积的钠离子(SIB)和锂离子(LIB)电池在空气和惰性气体环境下的热失控特性。实验结果表明,在低氧条件下,SIB和镍钴锰(NCM)电池的热失控严重程度得到了显著缓解,其中产气指标降低了35%以上,而磷酸铁锂(LFP)电池在很大程度上不受影响。在气体成分分析中,NCM细胞的CO2/CO和O2/N2比例显著降低,而SIB和LFP细胞的成分没有显著变化。基于实验数据和文献,开发了一个多维热失控参数数据库,包括气体爆炸性、毒性和燃烧热等指标。应用并比较了三种经典的多准则评价方法——理想解相似性排序偏好法、主成分分析法和基于中值法。为了解决参数之间的维度和方差尺度差异所带来的限制,提出了一种期望贡献方法,以实现平衡和一致的评分。结果表明,该方法增强了公平性和可解释性,特别是在跨电池系统产生的变量之间存在巨大规模差异的情况下。这项工作建立了一个定量的安全评估框架,可以进行跨平台比较,并为电池系统设计、风险分区和热缓解策略提供指导。该框架广泛适用于新兴的电池化学物质,并在不同的应用环境中推进电池安全评估。
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引用次数: 0
Impact of shutdown operations on the recovery of reversible degradation in proton exchange membrane fuel cells 关闭操作对质子交换膜燃料电池可逆降解恢复的影响
IF 17 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-12-01 Epub Date: 2025-09-01 DOI: 10.1016/j.etran.2025.100468
Ruitao Li , Julong Zhou , Naiyuan Yao , Yuhan Zhou , Weikang Lin , Zishun Xu , Jianbin Su , Lei Shi , Tiancai Ma
In proton exchange membrane fuel cells, partial performance loss accumulated during long-term operation can be recovered through optimized operation or shutdown, a process known as reversible degradation. However, most existing studies focus on small-scale single cells and laboratory-scale test conditions, without adequately considering the constraints inherent to practical system-level operation. Therefore, investigating the influence of practically adjustable shutdown parameters on recovery effectiveness is crucial. Moreover, large-scale stacks exhibit spatial heterogeneity in degradation and recovery, both across cell positions and within individual cells. This heterogeneity plays a key role in identifying reversible degradation and formulating recovery strategies. In this study, accelerated stress tests were conducted on a full-size short stack under New European Driving Cycle conditions. Experimental variables included shutdown temperature, operating temperature, and purging methods, to evaluate their effects on recovery. Changes in stack consistency and electrochemically active surface area before and after recovery were analyzed. Results indicate that moderate retention of condensed water promotes ionomer rehydration and performance recovery, while uneven water distribution leads to spatial differences in recovery. Inter-cell and in-plane inconsistencies increase with current density, with voltage deviations exceeding 40 mV between cells and 20 mV within cells at 594 A. The outlet region exhibited weaker recovery consistency and greater sensitivity to load fluctuations, with response amplification reaching approximately 300 %. Cooling measures during recovery improved both steady-state performance and dynamic response. This work provides important insights into the optimization of shutdown parameters and spatial performance variation in large PEMFC stacks, supporting the development of improved operational strategies to enhance durability and efficiency in practical applications.
在质子交换膜燃料电池中,在长期运行中积累的部分性能损失可以通过优化运行或关闭来恢复,这一过程被称为可逆降解。然而,大多数现有的研究都集中在小规模的单细胞和实验室规模的测试条件上,没有充分考虑实际系统级操作固有的约束。因此,研究实际可调的关井参数对采收率的影响至关重要。此外,无论是跨细胞位置还是单个细胞内,大规模堆栈在退化和恢复方面都表现出空间异质性。这种异质性在识别可逆性降解和制定恢复策略方面起着关键作用。在本研究中,在新欧洲驾驶循环条件下对全尺寸短堆进行了加速压力测试。实验变量包括停机温度、操作温度和净化方法,以评估其对回收率的影响。分析了采油前后储层稠度和电化学活性表面积的变化。结果表明,适度的冷凝水保留促进了离聚体的再水化和性能恢复,而水分分布不均匀导致了恢复的空间差异。电池间和面内不一致性随着电流密度的增加而增加,594 A时电池间电压偏差超过40 mV,电池内电压偏差超过20 mV。出口区域的恢复一致性较弱,对负荷波动的敏感性较大,响应放大约为300%。恢复过程中的冷却措施提高了稳态性能和动态响应。这项工作为优化大型PEMFC堆的关断参数和空间性能变化提供了重要见解,支持开发改进的操作策略,以提高实际应用中的耐久性和效率。
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引用次数: 0
A state-of-the-art review on eVTOL thermal management: system architectures, key components and emerging technologies eVTOL热管理的最新研究综述:系统架构、关键组件和新兴技术
IF 17 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-12-01 Epub Date: 2025-09-12 DOI: 10.1016/j.etran.2025.100480
Zhe Li , Peng Xie , Cheng Lin , Guoyu Liu
Electric vertical takeoff and landing aircraft (eVTOL) represent a transformative solution for modern transportation, offering high speed, low noise, and operational flexibility. However, the performance of their powertrains is highly temperature-sensitive, and their operating scenarios and mission profiles differ significantly from those of ground-based electric vehicles (EVs). In addition, cabin thermal regulation significantly affects energy consumption, thereby influencing the flight range. Consequently, an efficient thermal management system (TMS) is essential for eVTOL applications. This paper first reviews eVTOL powertrain architectures, followed by a systematic examination of the corresponding TMS architectures, including their operating principles, characteristics, and limitations. The thermal management requirements of key powertrain components are then analyzed, along with the review of relevant thermal management technologies. Moreover, emerging technologies applicable to eVTOLs are discussed, with an emphasis on their potential to enhance system performance. Finally, current research gaps are identified, and directions for future investigation are proposed. To the best of our knowledge, this is the first dedicated review of thermal management technologies for eVTOLs, aiming to clarify the state of the art, identify existing challenges, and provide valuable insights for researchers and industry practitioners.
电动垂直起降飞机(eVTOL)代表了现代交通运输的变革性解决方案,具有高速度、低噪音和操作灵活性。然而,它们的动力系统性能对温度高度敏感,并且它们的运行场景和任务剖面与地面电动汽车(ev)有很大不同。此外,客舱热调节显著影响能量消耗,从而影响飞行距离。因此,高效的热管理系统(TMS)对于eVTOL应用至关重要。本文首先回顾了eVTOL动力系统架构,然后系统地研究了相应的TMS架构,包括它们的工作原理、特点和局限性。然后分析了关键动力总成部件的热管理要求,并对相关热管理技术进行了综述。此外,还讨论了适用于evtol的新兴技术,重点是它们提高系统性能的潜力。最后,指出了当前研究的不足,并提出了未来研究的方向。据我们所知,这是eVTOLs热管理技术的第一次专门审查,旨在澄清最新技术,确定存在的挑战,并为研究人员和行业从业者提供有价值的见解。
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引用次数: 0
Multi-level passive-active thermal control for battery thermal runaway prevention and suppression in electric vehicles 电动汽车电池热失控预防与抑制多级被动-主动热控制
IF 17 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-12-01 Epub Date: 2025-09-04 DOI: 10.1016/j.etran.2025.100467
Jiekai Xie , Junlin Li , Canbing Li , Xinyan Huang , Guoqing Zhang , Xiaoqing Yang
Resolving the contradiction between heat-dissipation during normal operation and thermal-insulation after thermal runaway (TR) is highly desirable for battery thermal safety system but remains challenges. Herein, a multi-leveled thermal control strategy, i.e., passive cooling - active cooling - passive suppression - active suppression, has been proposed for TR prevention-suppression of the battery packs. The system is primarily designed by modular composite phase change material (CPCM), liquid cooling (LC) plates and aerogel plates (APs). Firstly, the passive cooling CPCM coordinated with active LC enables a suitable working temperature, low temperature gradient and low energy consumption of the battery pack under variable environments. Secondly, the modular design of the battery pack couples with the passive thermal-insulation effect of APs, successfully preventing TR from propagating to other modules. Thirdly, APs work synergistically with dynamic LC, greatly enhancing the directional heat-dissipation, and consequently, the TR propagation can be suppressed to the lowest level. By the flexible dynamic flow rate adjustment, the TR of large-scaled battery packs with different configurations of 4S12P, 6S8P, 8S6P and 12S4P can be successfully suppressed in the initially-triggered cell.
解决电池正常工作时的散热与热失控后的隔热之间的矛盾是电池热安全系统迫切需要解决的问题,但仍是一个挑战。本文提出了一种多层热控制策略,即被动冷却-主动冷却-被动抑制-主动抑制,以防止电池组的TR抑制。该系统主要由模块化复合相变材料(CPCM)、液体冷却(LC)板和气凝胶板(APs)设计而成。首先,被动冷却CPCM与主动LC相协调,使电池组在可变环境下具有合适的工作温度、低温度梯度和低能耗。其次,电池组的模块化设计与ap的被动隔热效应耦合,成功地阻止了TR传播到其他模块。第三,ap与动态LC协同工作,大大增强了定向散热,从而将TR传播抑制到最低水平。通过灵活的动态流量调节,4S12P、6S8P、8S6P和12S4P不同配置的大型电池组的TR可以在初始触发电池中成功抑制。
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引用次数: 0
State-of-charge estimation over full battery lifespan under diverse fast-charging protocols: A lightweight base-error joint modeling framework 多种快速充电协议下全电池寿命的充电状态估计:轻量级基础误差联合建模框架
IF 17 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-12-01 Epub Date: 2025-09-05 DOI: 10.1016/j.etran.2025.100474
Ganglin Cao , Shouxuan Chen , Yuanfei Geng , Shuzhi Zhang , Yao Jia , Rong Feng , Yongjun Liu
Accurate state-of-charge (SOC) online estimation during various multi-stage constant current (MCC) fast-charging protocols over battery entire lifespan holds significant importance. In this work, we develop a lightweight-training oriented data-driven base-error joint modeling framework to fill this research gap. Through deep learning-based initial-cycle data training and lightweight machine learning-based typical-cycle data training, we only extract approximately 1 % of whole battery data for data-driven base-error joint modeling. With consideration of SOC time-dependency, short-term Ampere-hour is further combined via a simple filter structure to guarantee final SOC estimation accuracy. The validation, derived from a public battery degradation dataset comprising 8 different MCC fast-charging protocols from 46 cells, demonstrates that our framework allows rapid data-driven base-error joint modeling with training time only about l min, where both average mean absolute error and average root mean square error of SOC estimation during various MCC fast-charging protocols over battery entire lifespan are roughly below 0.3 %. Our work, for the first time, reveals the possibility of joint data-driven model trained via extremely few data on accurate SOC online estimation with consideration of various MCC fast-charging protocols and battery degradation status, and also offers a pretty concise but efficient solution for multi-scenario battery aging diagnosis and voltage dynamics forecast. The code accompanying this work is available at https://github.com/szzhang96/A-light-weighted-training-oriented-data-driven-base-error-joint-modeling-method-for-SOC-estimation.
在不同的多级恒流(MCC)快速充电协议中,准确的在线估计电池的充电状态(SOC)具有重要的意义。在这项工作中,我们开发了一个面向轻量级训练的数据驱动基础误差联合建模框架来填补这一研究空白。通过基于深度学习的初始周期数据训练和基于轻量级机器学习的典型周期数据训练,我们只提取了大约1%的整个电池数据,用于数据驱动的基础误差联合建模。考虑到SOC的时间依赖性,通过简单的滤波器结构进一步组合短期安培小时,以保证最终的SOC估计精度。来自46个电池的8种不同MCC快速充电协议的公共电池退化数据集的验证表明,我们的框架允许快速数据驱动的基本误差联合建模,训练时间仅为1分钟,其中各种MCC快速充电协议下SOC估计的平均绝对误差和平均均方根误差在电池整个使用寿命期间大致低于0.3%。我们的工作首次揭示了通过极少量数据训练的联合数据驱动模型在考虑各种MCC快速充电协议和电池退化状态的情况下进行准确的SOC在线估计的可能性,并为多场景电池老化诊断和电压动态预测提供了一种非常简洁而高效的解决方案。本文附带的代码可从https://github.com/szzhang96/A-light-weighted-training-oriented-data-driven-base-error-joint-modeling-method-for-SOC-estimation获得。
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引用次数: 0
Breaking the voltage plateau barrier: Slope-adaptive state-of-charge estimation for LFP batteries with temperature-aware hysteresis modeling 突破电压平台障碍:基于温度感知迟滞模型的LFP电池的斜率自适应充电状态估计
IF 17 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-12-01 Epub Date: 2025-09-23 DOI: 10.1016/j.etran.2025.100473
Lisen Yan , Jun Peng , Heng Li , Zhiwu Huang , Dirk Uwe Sauer , Weihan Li
The open-circuit voltage (OCV) hysteresis effect significantly complicates state-of-charge (SOC) estimation of LiFePO4 batteries. While prior research has focused on major-loop hysteresis between full charge and discharge, accurately modeling minor-loop hysteresis during partial charge/discharge remains a persistent challenge. This paper proposes a data-driven hysteresis model that incorporates historical SOC and temperature data, with which an adaptive SOC estimator is designed to accommodate slope variations in minor-loop hysteresis. The proposed model accurately captures complex voltage hysteresis across different charge/discharge paths and temperature conditions using deep long short-term memory neural networks trained on hysteresis test data. This OCV component is integrated into a second-order equivalent circuit model, achieving both high-precision battery modeling and computational efficiency. The model parameters are optimized effectively using a multistep parameter identification method enhanced by a meta-heuristic algorithm. The proposed SOC estimator dynamically adjusts its covariance matrices in response to voltage slope variations during the plateau, improving Kalman gain matching to eliminate cumulative errors and enhance accuracy. Extensive experimental results show that over 95% of samples achieve a mean absolute error of less than 0.56% across various usage scenarios. The proposed method outperforms two state-of-the-art methods by 46.2% and 45.7% in root mean square error, demonstrating fast convergence and robust estimation even within the voltage plateau.
开路电压(OCV)滞后效应使LiFePO4电池的荷电状态(SOC)估算变得非常复杂。虽然先前的研究主要集中在完全充电和放电之间的主回路滞后,但准确建模部分充电/放电期间的小回路滞后仍然是一个持续的挑战。本文提出了一个数据驱动的滞后模型,该模型结合了历史SOC和温度数据,并设计了一个自适应SOC估计器,以适应小环滞后的斜率变化。该模型利用基于滞后测试数据训练的深度长短期记忆神经网络,准确捕获了不同充放电路径和温度条件下的复杂电压滞后。该OCV组件集成到二阶等效电路模型中,实现了高精度电池建模和计算效率。采用基于元启发式算法的多步参数辨识方法对模型参数进行了有效优化。本文提出的SOC估计器可以根据平台电压斜率的变化动态调整协方差矩阵,改进卡尔曼增益匹配,消除累积误差,提高估计精度。大量的实验结果表明,超过95%的样本在各种使用场景下的平均绝对误差小于0.56%。该方法的均方根误差比两种最先进的方法分别高出46.2%和45.7%,证明了即使在电压平台内也能快速收敛和鲁棒估计。
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引用次数: 0
Dynamic flight challenges in PEMFC-powered UAVs: Towards intelligent management and sustainable propulsion pemfc动力无人机的动态飞行挑战:迈向智能管理和可持续推进
IF 17 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-12-01 Epub Date: 2025-10-29 DOI: 10.1016/j.etran.2025.100506
Xikai Tu , Jin Wu , Zhiming Tao , Chang Wen , Zhengkai Tu
Proton exchange membrane fuel cell (PEMFC)-powered unmanned aerial vehicles (UAVs) exhibit nonlinear and coupled behavior under dynamic flight conditions. To enable intelligent management, this study proposes an adaptive air stoichiometric ratio (ASR) strategy that dynamically responds to real-time variations in payload and acceleration. Although ASR optimization has been studied under steady-state conditions, its regulation under realistic UAV dynamics remains underexplored and experimentally unverified. We develop a coupled framework integrating UAV flight dynamics, an air-cooled PEMFC model, and mass–heat transfer multiphysics, and validate it through dynamic flight tests. Results show that optimal ASR varies significantly with operating conditions: with a 40 kg payload, ASR increases from 52 to 81 as acceleration changes from −0.6 to 0.6 m/s2; at 0.6 m/s2, raising the payload from 25 to 40 kg increases ASR from 24 to 81. Optimal ASR regulation improves stack voltage by 0.170 V, reduces hydrogen consumption by 2.05 mg per 100 m of flight, lowers temperature by 18.32 %, and enhances efficiency, voltage uniformity, and temperature uniformity. Notably, ASR exhibits a nonlinear influence on performance: it improves markedly from 25 to 28 kg, remains stable between 28 and 31 kg, and rises again at 40 kg. Experimental validation (error <1.1 %) confirms model accuracy and demonstrates the effectiveness of ASR optimization in PEMFC-powered UAVs. Beyond UAV applications, the proposed adaptive ASR strategy offers a pathway toward intelligent air management in fuel-cell propulsion systems, with direct relevance to emerging electric transportation modes such as urban air mobility vehicles, cargo drones, and hybrid-electric aircraft.
以质子交换膜燃料电池(PEMFC)为动力的无人机在动态飞行条件下表现出非线性和耦合行为。为了实现智能管理,本研究提出了一种自适应空气化学计量比(ASR)策略,该策略可以动态响应有效载荷和加速度的实时变化。虽然ASR优化已经在稳态条件下进行了研究,但其在实际无人机动力学下的调节仍未得到充分探索和实验验证。建立了集成无人机飞行动力学、风冷PEMFC模型和传质传热多物理场的耦合框架,并通过动态飞行试验对其进行了验证。结果表明,最佳ASR随工况变化显著:当载荷为40 kg时,当加速度从- 0.6 m/s2增加到0.6 m/s2时,ASR从52增加到81;在0.6 m/s2的速度下,将有效载荷从25 kg提高到40 kg, ASR从24增加到81。优化后的ASR调节使堆叠电压提高0.170 V,每100 m飞行氢耗降低2.05 mg,温度降低18.32%,并提高了效率、电压均匀性和温度均匀性。值得注意的是,ASR对性能表现出非线性影响:在25至28 kg期间,ASR显著提高,在28至31 kg之间保持稳定,在40 kg时再次上升。实验验证(误差<; 1.1%)证实了模型的准确性,并证明了在pemfc驱动的无人机中ASR优化的有效性。除了无人机应用之外,提出的自适应ASR策略还为燃料电池推进系统的智能空气管理提供了一条途径,与新兴的电动交通方式(如城市空中交通工具、货运无人机和混合动力飞机)直接相关。
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Etransportation
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