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Consolidation model for soft ground under airlift-assisted vacuum preloading 气升辅助真空预压下软土地基固结模型
IF 6.2 1区 工程技术 Q1 ENGINEERING, GEOLOGICAL Pub Date : 2026-06-01 Epub Date: 2026-01-30 DOI: 10.1016/j.geotexmem.2026.01.006
Xinbei Lin , Zhen Huang , Li Shi , Yuanqiang Cai
Recently, a novel soft ground improvement technique termed airlift-assisted vacuum preloading (AAVP) has been proposed, which is featured by cyclically injecting pressurized air at the bottom of prefabricated vertical drains (PVDs) to expel water from the drain. This airlift process can achieve nearly lossless transmission of vacuum pressure along the PVDs and induce pneumatic fractures that enhance soil permeability. In this study, a nonlinear consolidation model was developed with full consideration of the time-varying pressure condition and the permeability improvement associated with cyclic airlift operations. The analytical solution was obtained by employing the piecewise linearization technique, and was first verified by degenerating it into conventional vacuum preloading (CVP) process and comparing to the classical drain-well solution. The complete solution was further validated against large-scale model test data. Parametric analyses revealed that, compared with CVP, AAVP significantly accelerates the consolidation process, exhibiting not only faster pore pressure dissipation but also a greater magnitude of dissipation that exceeds the applied vacuum. Theoretical results indicate that the advantages of AAVP become more pronounced under greater treatment depths and in soil with adverse conditions such as smear and clogging effects, highlighting its strong potential for application in ultra-thick soft deposits and high-water-content reclamation land.
近年来,人们提出了一种新的软土地基改善技术,称为气升辅助真空预压(AAVP),其特点是在预制垂直排水管(PVDs)底部循环注入加压空气以排出排水管中的水。这种气举过程可以实现真空压力沿PVDs的几乎无损传递,并产生气动裂缝,从而提高土壤的渗透性。在本研究中,充分考虑时变压力条件和循环气举作业带来的渗透率提高,建立了非线性固结模型。采用分段线性化方法得到了解析解,并将其退化为常规真空预压过程,并与经典排水井解进行了对比验证。通过大规模模型试验数据进一步验证了完整的解决方案。参数分析表明,与CVP相比,AAVP显著加速了固结过程,不仅表现出更快的孔压耗散,而且耗散幅度更大,超过了施加真空。理论结果表明,AAVP处理深度越大,在存在涂抹、堵塞等不利条件的土壤中,其优势越明显,在超厚软质沉积物和高含水率复垦土地中具有较强的应用潜力。
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引用次数: 0
Influence of sea surface temperature in the southern Indian and Atlantic Oceans on austral summer rainfall in southern Tanzania 南印度洋和大西洋海表温度对坦桑尼亚南部夏季降水的影响
IF 4.4 2区 地球科学 Q1 METEOROLOGY & ATMOSPHERIC SCIENCES Pub Date : 2026-06-01 Epub Date: 2026-02-10 DOI: 10.1016/j.atmosres.2026.108847
Dickson Mbigi, Zacharia Florence Mtewele
As one of the prominent oceanic regions exhibiting high interannual variability of sea surface temperature (SST), the southern Indian and Atlantic Oceans have been found to exert strong impacts on January–February-March (JFM) rainfall in southern Tanzania. The JFM rainfall is found to be significantly linked to the subtropical Indian Ocean Dipole (SIOD)-like SST pattern over the southern Indian Ocean and southern Atlantic Ocean Tripole (SAOT)-like SST structure over the southern Atlantic Ocean. This relationship is linearly independent of the effects of El Niño–Southern Oscillation and the Indian Ocean dipole. The presence of a weakened Mascarene high associated with the negative SIOD phase leads to southerly wind anomalies across the Mozambique Channel, which enhances moisture transport into southern Tanzania and rainfall over the region. The SAOT, on the other hand, excites a zonal elongated wave train-like pattern that induces large-scale cyclonic circulation over the southern Indian Ocean. Subsequently, the western flank of the cyclonic circulation excites southerly wind anomalies traversing through the Mozambique Channel towards the study region, leading to rainfall over the study region. Moreover, the observed wave train-like pattern is echoed in the upper levels, but the anticyclonic center over southern Australia expands further towards northern Madagascar. At this position, the associated anticyclonic wind anomalies reach southern Tanzania to create a divergence condition, enhancing rainfall conditions. Finally, the joint SIOD and SAOT indices show enhanced contribution to the rainfall, explaining about 28% of rainfall variability.
南印度洋和大西洋对坦桑尼亚南部1 - 2 - 3月(JFM)降水有很强的影响,是年际海温(SST)年际变化显著的海洋区域之一。JFM降水与南印度洋的副热带印度洋偶极子(SIOD)型海温和南大西洋的南大西洋三极子(SAOT)型海温有显著关系。这种关系与El Niño-Southern振荡和印度洋偶极子的影响线性无关。与负SIOD相相关的减弱的马斯卡林高压的存在导致横跨莫桑比克海峡的偏南风异常,这加强了进入坦桑尼亚南部的水分输送和该地区的降雨。另一方面,SAOT激发了一种纬向细长波列模式,在南印度洋上空诱发了大规模的气旋环流。随后,气旋环流的西侧翼激发南风异常穿过莫桑比克海峡向研究区域移动,导致研究区域降雨。此外,观测到的波列状模式在高层也得到了响应,但澳大利亚南部的反气旋中心进一步向马达加斯加北部扩展。在这个位置,相关的反气旋风异常到达坦桑尼亚南部,创造了辐散条件,增强了降雨条件。最后,SIOD和SAOT联合指数对降水的贡献增强,解释了约28%的降水变率。
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引用次数: 0
Cretanallachiidae – a new family of the specialized Cretaceous Neuroptera 白垩纪神经翅目特化的一个新科
IF 1.7 3区 地球科学 Q1 GEOLOGY Pub Date : 2026-06-01 Epub Date: 2026-01-21 DOI: 10.1016/j.cretres.2026.106317
Vladimir N. Makarkin
The subfamily Cretanallachiinae is elevated to a family level, Cretanallachiidae, stat. nov. Its autapomorphies are bipectinate antennae in males and a long ventro-caudal extension of the 9th tergite in females. The family is known only from mid-Cretaceous Kachin amber. It is likely closely related to Dilaridae, an undescribed ithonoid-like taxon from the Middle Jurassic, and to a lesser extent Ithonidae. They lived in humid tropical forests with diverse angiosperms and probably fed on their flowers (nectar and/or pollen) using relatively long sucking mouthparts.
该亚科被提升到一个科的水平,雄性为双翅触角,雌性为第9触角的长腹尾延伸。这个家族只在白垩纪中期的克钦琥珀中被发现。它可能与中侏罗世的一种未描述的ithonoid类分类单元Dilaridae有密切关系,并且在较小程度上与Ithonidae有密切关系。它们生活在潮湿的热带森林中,有各种被子植物,可能用相对较长的吸吮口器吸食它们的花朵(花蜜和/或花粉)。
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引用次数: 0
Episodic early Paleozoic arc magmatism of the Proto-Tethys Ocean: Evidence from geochronology, geochemistry and Sr-Nd-Hf isotopes of plutonic rocks in the southern East Kunlun Orogen 原特提斯洋早古生代幕式弧岩浆活动:来自东昆仑造山带南部深成岩年代学、地球化学和Sr-Nd-Hf同位素的证据
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-01-26 DOI: 10.1016/j.gr.2025.12.022
Xiang Ren , Yunpeng Dong , Inna Safonova , Shengsi Sun , Dengfeng He , Xiaoyan Zhao , Yuangang Yue , Bo Hui , Qiuming Pei , Baoping Gan
The southern East Kunlun Orogen (EKO) experienced protracted orogeny linked to the Proto-Tethys and Paleo-Tethys oceans. However, the evolution of the Proto-Tethys Ocean remains much less understood leaving the question of the timing of subduction initiation and magmatism. Here, we studied three early Paleozoic plutons exposed in the southern EKO: Kekesha (KKS) and Xialawen (XLW) gabbro-dioritic plutons and Longwakalu (LWKL) granitic pluton for geochronology, geochemistry and Sr-Nd-Hf isotopes. A KKS quartz diorite, XLW hornblende gabbro, and LWKL granite crystallized at 494, 470 and 477 Ma, respectively. The KKS gabbro-granodiorite series and XLW hornblende gabbros are enriched in light rare earth elements and large ion lithophile elements, but depleted in high strength field elements. The LWKL granites possess adakitic features: high Na2O content, Sr/Y and La/YbN ratios and differentiated heavy REEs. Isotopically, XLW hornblende gabbros and LWKL granites are less enriched isotopes (εNd(t) = −4.3 to −3.9; εHf(t) = −4.6 to +2.0) than KKS gabbro and granodiorite (εNd(t) = −7.0; εHf(t) = −7.2 to −4.8). Sr-Nd isotopic modeling suggests that KKS and XLW plutons were derived through partial melting of mantle wedge modified by different amounts of subducted terrigenous-dominated sediment derived melts. The LWKL adakitic granites were formed by high-pressure reworking of underplated arc-type intermediate rocks. The emplacement of early Paleozoic gabbro-granodiorite series and adakitic granites was related to subduction of the Proto-Tethys Ocean which started no later than ca. 500 Ma. Our new data along with available ages suggest that the supra-subduction magmatism of the Proto-Tethys Ocean in the southern EKO is episodic with peaks at ca. 495, 470, and 430 Ma. The first two episodes of magmatism mainly represent melting of enriched mantle wedge, and the third is the main pulse of magmatism formed by simultaneous melting of multiple sources of crustal rocks, subducted oceanic slab and mantle wedge.
东昆仑造山带南部经历了与原特提斯洋和古特提斯洋有关的长期造山运动。然而,对原特提斯洋的演化仍然知之甚少,留下了俯冲开始和岩浆活动的时间问题。在此基础上,对鄂东南部3个早古生代的克克沙(KKS)和下阿拉文(XLW)辉长闪长岩和龙瓦卡鲁(LWKL)花岗岩体进行了年代学、地球化学和Sr-Nd-Hf同位素研究。KKS石英闪长岩、XLW角闪辉长岩和LWKL花岗岩分别在494、470和477 Ma结晶。KKS辉长-花岗闪长岩系列和XLW角闪长辉长岩富集轻稀土元素和大离子亲石元素,缺乏强场元素。LWKL花岗岩具有高Na2O含量、高Sr/Y、高La/YbN比值和分异重稀土元素特征。同位素上,XLW角闪辉长岩和LWKL花岗岩富集程度较低(εNd(t) = −4.3 ~−3.9;εHf(t) = −4.6 ~ +2.0)优于KKS辉长岩和花岗闪长岩(εNd(t) = −7.0;εHf(t) = −7.2 ~−4.8)。Sr-Nd同位素模拟表明,KKS和XLW岩体是由不同数量的陆源主导的俯冲沉积物衍生熔体修饰的地幔楔的部分熔融形成的。LWKL埃达克花岗岩是由下镀弧型中间岩高压改造而成。早古生代辉长-花岗闪长岩系列和埃达质花岗岩的侵位与不迟于约500 Ma的原特提斯洋俯冲有关。我们的新数据和现有的年龄表明,EKO南部原特提斯洋的超俯冲岩浆活动是幕式的,峰值大约在495,470和430 Ma。前两期岩浆活动主要代表富集地幔楔的熔融作用,第三期岩浆活动是多源地壳岩、俯冲洋板和地幔楔同时熔融作用形成的岩浆活动主脉冲。
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引用次数: 0
Oil mobility evaluation and light hydrocarbon restoration in shale reservoirs: a review 页岩储层油流性评价与轻烃恢复研究进展
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-01-18 DOI: 10.1016/j.gr.2025.12.010
Yue Feng , Xianming Xiao , Enze Wang , Chengang Lu , Changrong Li , Gang Li , Yineng Tan
Organic matter-rich shale, a widely developed fine-grained sedimentary rock, hosts critical unconventional petroleum resources. Accurately assessing the resource potential and economic value of shale oil reservoirs is crucial for energy strategy decision-making, yet two challenges persist: evaluating oil mobility, and addressing light hydrocarbon evaporation. This study provides a review of these two critical dimensions. Laboratory testing forms the foundation of oil mobility assessment. In practice, method selection should be guided by the specific geological settings, data availability, and economic considerations. Notably, artificial intelligence offers the potential to generate accurate predictions even from limited datasets. This study establishes a generalizable framework validated through a case study on oil mobility evaluation under small-sample dataset scenarios. The second part divides the light hydrocarbon loss process from coring to experimental data acquisition into four distinct stages. The loss is continuously influenced by time-related degradation, with each stage characterized by different controlling factors. Nonetheless, the oil properties of shale and its own attributes remain consistent overarching influences. Minimizing additional losses through comprehensive and practical strategies represents the most effective solution. Future advances in experimental technologies, refined frameworks, and the deep mining and integration of data will enhance assessment accuracy. The findings of this study are expected to provide a solid theoretical foundation for the precise evaluation of resources in shale systems and the efficient delineation of prospective exploration targets.
富含有机质的页岩是一种广泛发育的细粒沉积岩,蕴藏着重要的非常规石油资源。准确评估页岩油储层的资源潜力和经济价值对于能源战略决策至关重要,但仍然存在两个挑战:评估原油流动性和解决轻烃蒸发问题。本研究提供了对这两个关键维度的回顾。实验室测试是油品流动性评价的基础。在实践中,方法的选择应以具体的地质环境、数据的可用性和经济考虑为指导。值得注意的是,人工智能提供了即使从有限的数据集生成准确预测的潜力。本研究建立了一个可推广的框架,并通过小样本数据集情景下的原油流动性评价案例进行了验证。第二部分将从取心到实验数据采集的轻烃损失过程划分为四个不同的阶段。损失持续受到时间相关退化的影响,每个阶段都有不同的控制因素。尽管如此,页岩油的性质及其本身的属性仍然是最重要的影响因素。通过全面和实用的策略来减少额外损失是最有效的解决办法。未来在实验技术、精细化框架以及数据深度挖掘和整合方面的进步将提高评估的准确性。研究结果将为页岩系统资源的精准评价和远景勘探目标的有效圈定提供坚实的理论基础。
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引用次数: 0
Late Cretaceous sauropod dinosaur undertracks in floodplain deposits of Sanfranciscana Basin, Brazil, and their paleoecological significance 巴西圣弗朗西斯卡纳盆地洪泛平原沉积物中晚白垩世蜥脚类恐龙足迹及其古生态学意义
IF 1.7 3区 地球科学 Q2 PALEONTOLOGY Pub Date : 2026-06-01 Epub Date: 2026-01-16 DOI: 10.1016/j.palwor.2026.201078
Luciano Alessandretti , Lucas Veríssimo Warren , Heitor Francischini , Caio César Rangel , Beatriz Christofoletti , Leandro Gustavo da Silva Albino , Leonardo Cardoso Moura , Daniel Sedorko
Dinosaur undertracks are described in the Upper Cretaceous Capacete Formation of the Sanfranciscana Basin, southeastern Brazil. These vertebrate traces are preserved in fine-grained deposits deposited in muddy and vegetated floodplain settings associated with a meandering river system active during the Campanian–Maastrichtian. Based on sedimentologic data, morphostructural analysis, and comparisons with analogous Cretaceous ichnofossils, we interpret these structures as undertracks produced by sauropods. Notably, although other occurrences of footprints and undertracks are known in younger units, no dinosaur fossils have yet been recovered in the Upper Cretaceous of the Sanfranciscana Basin. However, they are widespread in chronocorrelated units from the Bauru Basin, deposited by fluvial distributary and lacustrine systems under arid to semi-arid climatic conditions. During the Late Cretaceous, these two basins were putatively separated due to the uplift of the Alto Paranaíba High (APH) in the central part of the South American Platform. Our new sedimentologic and paleontologic data from the Sanfranciscana Basin, combined with regional paleogeography and paleoclimate reconstructions, suggest that a rain shadow effect played a key role in influencing precipitation patterns in the northern side of the APH. In this scenario of orographic rainfall, sauropod populations likely migrated from the Bauru Basin in the Southern Hot Arid Belt to the Sanfranciscana Basin in the Equatorial Humid Belt, possibly driven by droughts and shortages of food and water. This inferred migratory pathway likely involved a lowland-upland-lowland journey of dinosaur herds through the APH, eventually leading them to the humid floodplains of the Sanfranciscana Basin, where resources such as food and water were more abundant.
在巴西东南部圣弗朗西斯卡纳盆地的上白垩纪Capacete组中描述了恐龙的足迹。这些脊椎动物的痕迹被保存在细小的沉积物中,这些沉积物沉积在泥泞和植被覆盖的洪泛区,与坎帕尼亚-马斯特里赫特时期活跃的蜿蜒河流系统有关。根据沉积学资料、形态结构分析以及与类似白垩纪鱼化石的比较,我们认为这些结构是蜥脚类动物留下的足迹。值得注意的是,尽管在更年轻的恐龙群中也发现了其他的脚印和足迹,但在旧金山盆地的上白垩纪还没有发现恐龙化石。然而,它们广泛存在于宝鲁盆地的时间相关单元中,这些单元是在干旱至半干旱气候条件下由河流支流和湖泊系统沉积的。在晚白垩世,由于南美地台中部的Alto Paranaíba High (APH)的隆升,推测这两个盆地是分开的。本文利用旧金山盆地沉积学和古生物学的新资料,结合区域古地理和古气候的重建,表明雨影效应在影响APH北侧降水格局中发挥了关键作用。在这种地形降雨的情况下,蜥脚类动物可能会从南部热干旱带的博鲁盆地迁移到赤道湿润带的旧金山盆地,这可能是由于干旱和食物和水的短缺。这种推断的迁徙路径可能涉及恐龙群通过APH的低地-高地-低地之旅,最终将它们带到旧金山盆地潮湿的洪泛平原,那里的食物和水等资源更为丰富。
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引用次数: 0
Global assimilation of NRL MODIS aerosol optical thickness and its impact on aerosol direct radiative effect over a full year NRL MODIS气溶胶光学厚度的全球同化及其对全年气溶胶直接辐射效应的影响
IF 4.4 2区 地球科学 Q1 METEOROLOGY & ATMOSPHERIC SCIENCES Pub Date : 2026-06-01 Epub Date: 2026-01-30 DOI: 10.1016/j.atmosres.2026.108819
Min Zhao , Tie Dai , Yueming Cheng , Daisuke Goto , Keiya Yumimoto , Guangyu Shi
This study investigates the accuracy of aerosol optical thickness (AOT) forecasts and analyses during a whole year, by assimilating AOT retrievals from the Naval Research Laboratory (NRL) Moderate Resolution Imaging Spectroradiometer (MODIS) into the aerosol-coupled Non-hydrostatic ICosahedral Atmospheric Model. We explore the impact of data assimilation on aerosol direct radiative effect (DRE), taking into account the interactions between aerosol particles and radiation. Evaluation against the assimilated MODIS AOT data shows an improvement in the AOT fields. The root mean square error (RMSE) dropped from 0.027 in the free-run to 0.018 (a 33% reduction) for the forecast and to 0.017 (a 37% reduction) for the analysis, while the correlation coefficient rose from 0.640 (free-run) to 0.911 (forecast) and 0.986 (analysis), respectively. Furthermore, the most significant improvements were observed during the peak biomass burning period from August to October. This enhanced performance is further certified independently by Aerosol Robotic Network (AERONET) observations, which show a reduction in RMSE from 0.050 (free-run) to 0.038 (forecast) and 0.040 (analysis), alongside a marked rise in correlation coefficient to 0.810 and 0.884, respectively. The forecast DRE under clear-sky condition at the TOA is −2.69 ± 2.02 W/m2 and at the surface is −4.04 ± 2.96 W/m2. Under all-sky conditions, aerosol DRE are influenced by clouds, the forecast DRE under all-sky condition at the TOA is −1.45 ± 1.26 W/m2 and at the surface is −2.74 ± 1.98 W/m2.
本文利用美国海军研究实验室(NRL)中分辨率成像光谱仪(MODIS)反演的气溶胶光学厚度(AOT)数据,对气溶胶耦合非流体静力二十面体大气模式进行了全年气溶胶光学厚度(AOT)预报和分析的准确性进行了研究。考虑到气溶胶粒子与辐射之间的相互作用,我们探讨了资料同化对气溶胶直接辐射效应(DRE)的影响。根据同化的MODIS AOT数据进行评价,AOT领域有所改善。均方根误差(RMSE)从自由运行的0.027下降到预测的0.018(减少33%)和分析的0.017(减少37%),而相关系数分别从0.640(自由运行)上升到0.911(预测)和0.986(分析)。其中,8 ~ 10月生物质燃烧高峰期改善最为显著。气溶胶机器人网络(AERONET)的观测结果进一步证明了这种增强的性能,RMSE从0.050(自由运行)降低到0.038(预测)和0.040(分析),相关系数分别显著上升到0.810和0.884。晴空条件下TOA预报DRE为−2.69±2.02 W/m2,地面预报DRE为−4.04±2.96 W/m2。在全天条件下,气溶胶DRE受云的影响,全天条件下的预报DRE在TOA为- 1.45±1.26 W/m2,在地面为- 2.74±1.98 W/m2。
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引用次数: 0
Revisiting the Urban heat and pollution Islands over the Kolkata metropolitan area, India 重访印度加尔各答大都市区的城市热岛和污染岛
IF 4.1 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-01-31 DOI: 10.1016/j.pce.2026.104330
Pragya Pandey , Bhishma Tyagi , Pradeep Kumar , Saroj Kumar Sahu , Kuldeep Sharma
Urban environments alter local climate and air quality through concentrated emissions of heat and pollutants, giving rise to effects such as Urban Heat Island (UHI) and Urban Pollution Island (UPI). These microclimatic phenomena have seen growth due to industrialisation and urbanisation. Their coupled interaction in the context of Indian cities, however, remains poorly understood. In this study, we have investigated the evolution of UHI and UPI over a megacity of India, Kolkata, with a focus on Kolkata Metropolitan Area (KMA) by analysing Remote Sensing (MODIS) and in situ measurements (CPCB) of Land Surface Temperature (LST), UHI, Aerosol Optical Depth (AOD), Direct and Diffuse Solar Radiation, and Particulate Matter (PM2.5 and PM10) for a collective period of 2001–2024. UHI and UPI were observed over KMA, with both Nighttime LST (NLST) and Daytime LST (DLST) as well as AOD having significantly higher values over the urban region by +1.79 °C, +2.92 °C, and 0.18, respectively, than in rural areas. The results also suggested that the magnitudes of UHI and UPI are increasing over the years for KMA. As a result of increasing UPI, the study observed a simultaneous reduction of direct solar radiation by 22.64 W/m2 and an increase of diffuse radiation by 18.82 W/m2 over urban areas for the study period. The study suggests that the UPI and UHI may influence each other through direct and diffuse radiative forcing, and that the modulation of urban surface energy balance may occur due to these changes, which may be a link to unprecedented weather events over the region. The results provide a scientific basis for developing policies on regional climate adaptation and air quality management in Indian cities.
城市环境通过集中排放热量和污染物改变当地气候和空气质量,产生城市热岛(UHI)和城市污染岛(UPI)等效应。由于工业化和城市化,这些小气候现象有所增加。然而,它们在印度城市背景下的耦合相互作用仍然知之甚少。在这项研究中,我们通过分析遥感(MODIS)和现场测量(CPCB)的陆地表面温度(LST)、城市热岛、气溶胶光学深度(AOD)、太阳直接辐射和漫射辐射以及颗粒物(PM2.5和PM10),研究了印度大城市加尔各答的城市热岛和UPI的演变,重点研究了加尔各答大都市区(KMA) 2001-2024年的变化。在KMA观测到UHI和UPI,夜间LST (NLST)和日间LST (DLST)以及AOD在城市地区的值分别显著高于农村地区+1.79°C, +2.92°C和0.18°C。结果还表明,KMA的UHI和UPI的大小逐年增加。由于UPI的增加,研究发现在研究期间,城市地区的太阳直接辐射减少了22.64 W/m2,散射辐射增加了18.82 W/m2。研究表明,UPI和UHI可能通过直接辐射强迫和扩散辐射强迫相互影响,这些变化可能导致城市地表能量平衡的调节,这可能与该地区前所未有的天气事件有关。研究结果为制定印度城市区域气候适应和空气质量管理政策提供了科学依据。
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引用次数: 0
Mechanistic insights into biotite weathering: effects of structural and physicochemical factors on Na-TPB-induced potassium leaching 黑云母风化机理研究:结构和物理化学因素对na - tpb诱导钾浸出的影响
IF 5.8 2区 地球科学 Q2 CHEMISTRY, PHYSICAL Pub Date : 2026-06-01 Epub Date: 2026-02-11 DOI: 10.1016/j.clay.2026.108163
Seongyeop Kim, Yeongkyoo Kim
Understanding the mechanisms of biotite weathering is critical for elucidating geochemical cycling and soil formation. This study provides key mechanistic insights by systematically investigating artificial biotite weathering using a sodium tetraphenylborate (Na-TPB)-based method and evaluating the effects of reaction conditions—namely, the number of extraction cycles, temperature, particle size, structural iron oxidation state, and initial biotite composition, including the number of extraction cycles, temperature, particle size, structural iron oxidation state, and initial biotite composition on weathering pathways, using two biotite samples (BR and CA) with different initial Mg/(Mg + Fe) ratios and halogen contents. The results demonstrated that increasing the number of K+ extraction cycles led to greater weathering than prolonging the reaction time, as this created a sustained, steep K+ concentration gradient. A critical finding was that the pre-oxidation of structural iron significantly retarded K+ leaching by altering the biotite's internal electrostatic forces. This was quantitatively confirmed by X-ray photoelectron spectroscopy (XPS), which showed a clear correlation between increased surface Fe3+/Fe2+ ratios and slower weathering kinetics. Furthermore, iron oxidation appeared to promote the formation of irregular mixed-layer structures (biotite–vermiculite layers), a plausible mechanistic consequence of heterogeneous structural cation redistribution. Comparative experiments of different initial compositions revealed that the CA biotite exhibited greater weathering resistance than the BR sample. This is because its distinct initial composition (higher halogen content and Fe3+/Fe2+ ratio) enhanced K+ retention. These findings highlight the decisive roles of structural iron oxidation and initial chemical composition in controlling biotite weathering rates and pathways and the formation of secondary mineral phases.
了解黑云母风化机制对阐明地球化学循环和土壤形成具有重要意义。本研究采用基于四苯基硼酸钠(Na-TPB)的方法系统地研究了人工黑云母风化过程,并评估了反应条件的影响,即萃取循环次数、温度、粒度、结构铁氧化态和初始黑云母组成,包括萃取循环次数、温度、粒度、结构铁氧化态,从而提供了关键的机理见解。以初始Mg/(Mg + Fe)比和卤素含量不同的两种黑云母(BR和CA)样品为研究对象,研究了它们对风化路径的影响。结果表明,与延长反应时间相比,增加K+提取循环次数会导致更大的风化作用,因为这会产生持续的、陡峭的K+浓度梯度。一个重要的发现是,结构铁的预氧化通过改变黑云母的内部静电力显著延缓了K+的浸出。x射线光电子能谱(XPS)定量地证实了这一点,表明表面Fe3+/Fe2+比值的增加与风化动力学的减慢之间存在明显的相关性。此外,铁氧化似乎促进了不规则混合层结构(黑云母-蛭石层)的形成,这是异质结构阳离子重新分配的合理机制。不同初始组分对比实验表明,CA黑云母比BR样品具有更强的抗风化性。这是因为其独特的初始成分(较高的卤素含量和Fe3+/Fe2+比)增强了K+的保留。这些发现强调了结构铁氧化和初始化学成分在控制黑云母风化速率和路径以及次生矿物相形成中的决定性作用。
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引用次数: 0
The Rio Salitre Volcano-Sedimentary Succession, São Francisco Craton, Eastern Brazil: Record of a Siderian-Orosirian tectonic cycle 巴西东部<s:1>圣弗朗西斯科克拉通bbb20盐层火山-沉积演替:锡德-奥罗世构造旋回的记录
IF 3.2 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-02-28 DOI: 10.1016/j.precamres.2026.108067
Carina G. Lopes-Mira , Fernando F. Alkmim , Cristiano C. Lana
The basement of the São Francisco Craton in eastern Brazil records a complex history of growth and deformation that extends from the Paleoarchean up to the Orosirian Period. It hosts a segment of the Minas-Bahia Orogen, likely developed during the Orosirian assembly of the Central African block, a continental mass that would encompass the São Francisco-Congo, Borborema, Trans-Saharian, Rio de la Plata, and Kalahari shield provinces of South America and Africa. Aiming to unravel the tectonic scenarios of the Minas-Bahia Orogen generation, we conducted a stratigraphic, structural, geochemical, and geochronological study of the Rio Salitre belt of the Gavião microcontinent, the largest terrane of the Minas-Bahia Orogen exposed in the northern São Francisco craton. The Rio Salitre succession comprises a basal sedimentary unit (A), a middle volcano-sedimentary package (B), and an upper clastic sedimentary assemblage (C). Intruded by small granitic bodies and diabase dikes of unknown age, and unconformably covered by Meso- to Neoproterozoic strata, the Rio Salitre succession experienced two phases of deformation, a WNW-ESE contraction, followed by a left-lateral transtensional shearing that led to the development of a large-scale synformal keel, bound on all sides by basement uplifts. U-Pb zircon dating reveals Neoarchean (2666 ± 13 Ma) and Orosirian (1936 ± 21 Ma) maximum depositional ages, respectively, for Units A and C, and a Rhyacian depositional age of c. 2200 Ma for Unit B calc-alkaline to shoshonitic metatuffs. Our results point to a three-stage tectonic evolution of the Gavião microcontinent. Unit A represents the fill of an interior depocenter likely connected to a continental margin after 2666 Ma, whereas Unit B records its conversion into an extensional back-arc basin in the time interval of 2200 and 2100 Ma. Eventually, the Rio Salitre Basin evolved into a retro-foreland depocenter and received the clastic wedge of Unit C, accumulated after the collision of the various components of the Minas Bahia orogen. Our findings support a correlation between the Rio Salitre succession and classic Paleoproterozoic units of the São Francisco, Congo, and Kalahari cratons, thus favoring the existence of the Orosirian Central African paleocontinent.
巴西东部奥弗朗西斯科克拉通的基底记录了一个复杂的生长和变形历史,从古太古代一直延伸到奥罗世。它拥有米纳斯-巴伊亚造山带的一部分,可能是在中非块体的奥罗西亚组合期间发展起来的,这是一个大陆块,将包括南美洲和非洲的弗朗西斯科-刚果,博尔博雷马,跨撒哈拉,里约热内卢de la Plata和喀拉哈里盾省。为了揭示米纳斯-巴伊亚造山带的构造情景,我们对暴露在弗朗西斯科克拉通北部的米纳斯-巴伊亚造山带中最大的地体加维微大陆的里约热内卢盐碱带进行了地层学、构造、地球化学和年代学研究。bbb10盐层序列由基底沉积单元(a)、中部火山-沉积包体(B)和上部碎屑沉积组合(C)组成。受年龄未知的小花岗岩体和辉绿岩脉侵入,并被中-新元古代地层不整合覆盖,bbb - salitite序列经历了两个阶段的变形,即WNW-ESE收缩,然后是左侧张拉剪切,导致大规模的同型龙骨发育,四面被基底隆升束缚。U-Pb锆石测年显示,A单元和C单元的最大沉积年龄分别为新太古代(2666±13 Ma)和奥陶纪(1936±21 Ma), B单元钙碱性-玄武质变质岩的最大沉积年龄为约2200 Ma。我们的研究结果表明,加维微大陆的构造演化分为三个阶段。A单元代表2666 Ma之后可能与大陆边缘相连的内部沉积中心的充填,而B单元记录了2200 - 2100 Ma之间向伸展弧后盆地的转变。最终,里约热内卢盐碱盆地演化为后前陆沉积中心,并接受了Minas Bahia造山带各组分碰撞后形成的C单元碎屑楔。我们的研究结果支持里约热内卢- Salitre演替与弗朗西斯科、刚果和卡拉哈里克拉通的经典古元古代单元之间的相关性,从而支持奥罗世-中非古大陆的存在。
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