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Synthesis and Characterization of Methyl Ammonium Lead Halide Perovskite MAPbI3 for Applications in Photodetector Devices 甲基铵铅卤化钙钛矿MAPbI3的合成与表征及其在光电探测器器件中的应用
Pub Date : 2021-12-10 DOI: 10.31257/2018/jkp/2021/130203
Mohammad Malik Abood, Aref S. Baron, Osama Abdul Azeez Dakhil
Methyl ammonium lead iodide (CH3NH3PbI3) Perovskite was synthesized by a mixing method in one and two steps. The ethanol solvent was also used to dissolve CH3NH3I that is compared with isopropanol solvent. The characterizations of synthesized perovskite samples include the structural properties, morphological characteristics, and optical properties. The intensity and orientation in X-ray diffraction patterns appear clearly in ethanol solvent. Additionally, the ethanol solvent increases the grain size of perovskite which is homogeneous of the surface morphology. It causes a decrease in the wavelength of absorbance edge in addition to an increase in the energy bandgap value. The photodetector parameters for MAPbI3 perovskites cover the PbS nanocrystal which was prepared on the FTO glass dissolved by Isopropanol and DMF where the responsivity Rλ= 0.0037 and the quantum efficiency QE=1.016% was under λ nm =650 nm and Vbias=0V. These values were decreased by using Ethanol solvent.
采用一步法和两步混合法制备了碘化铅甲基铵钙钛矿。用乙醇溶剂溶解CH3NH3I,并与异丙醇溶剂进行比较。合成的钙钛矿样品的表征包括结构特性、形态特性和光学特性。在乙醇溶剂中,x射线衍射图的强度和取向清晰可见。此外,乙醇溶剂增加了钙钛矿的晶粒尺寸,使其表面形貌均匀。它引起吸光度边波长的减小和能带值的增大。MAPbI3钙钛矿的光电探测器参数覆盖了在异丙醇和DMF溶解的FTO玻璃上制备的PbS纳米晶体,其响应率Rλ= 0.0037,量子效率QE=1.016%, λ nm =650 nm, Vbias=0V。使用乙醇溶剂后,这些值有所降低。
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引用次数: 0
Absorption Characteristics of Magnesium Oxide and Aluminium Oxide NPs/ Rhodamine 6G/ Polyvinyl Alcohol Films 氧化镁和氧化铝NPs/罗丹明6G/聚乙烯醇膜的吸收特性
Pub Date : 2021-12-10 DOI: 10.31257/2018/jkp/2021/130207
Fairooz Faeq Kareem, Asrar Abd. Saeed, Mahasin F. Hadi, Farah Jawad Kadhum
Pure Polyvinyl Alcohol (PVA) film and PVA polymer film/ Rhodamine 6G(Rh6G) dye film in different volume ratios of (6, 12,18, 24 and 30) ml of Rh6G were prepared via casting method. The addition of Magnesium Oxide (MgO) and Aluminium Oxide (Al2O3) nanoparticles as a filler to the polymer matrix. The results demonstrated that there was a 10 nm red shift in the absorption spectra of Rh6G in PVA/ Rh6G polymer matrix due to add doping ratio of Rh6G dye solution to the transparent PVA matrix. Also, there was a 5 nm red shift in polymer matrix filled with Al2O3 NPs; this means that Al2O3 NPs absorb the water and that consequently enhance the optical properties of polymer matrix. The intensity of Rh6G doped PVA polymer film was seen to be enhanced when adding MgO NPs or Al2O3 NPs, noted that intensity of adding Al2O3 NPs more than it when adding MgO NP. The electronic transition was found to be π→π*.
采用浇铸法制备了纯聚乙烯醇(PVA)膜和不同体积比(6、12、18、24、30)ml Rh6G的PVA聚合物膜/罗丹明6G(Rh6G)染料膜。在聚合物基体中加入氧化镁(MgO)和氧化铝(Al2O3)纳米颗粒作为填料。结果表明,由于Rh6G染料溶液在透明PVA基体中掺杂比例的增加,Rh6G在PVA/ Rh6G聚合物基体中的吸收光谱出现了10 nm的红移。在填充Al2O3纳米粒子的聚合物基体中,出现了5 nm的红移;这意味着Al2O3纳米粒子吸收了水,从而增强了聚合物基体的光学性能。添加MgO NPs或Al2O3 NPs均能增强Rh6G掺杂PVA聚合物膜的强度,其中Al2O3 NPs的强度大于MgO NP。电子跃迁为π→π*。
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引用次数: 0
Substrate Temperature Effect on the Optical Properties of ZrO2 Films Prepared by Thermal Evaporation 衬底温度对热蒸发制备ZrO2薄膜光学性能的影响
Pub Date : 2021-12-10 DOI: 10.31257/2018/jkp/2021/130205
Ahmed H. Wanas
The pure substance of Zirconium oxide  (ZrO2) was deposited on substrate of glass with various substrate temperatures using thermal evaporation under the pressure of (2×10-5 bar) and with a deposition rate of (0.5 nm/S) with an average thickness of (300 nm). The optical properties of these prepared films were concentrated as a function of the substrate temperature. It was found that the values ​​of each of the refractive index, packing density, together with the extinction coefficient increased with the increase in the substrate temperature of the prepared films.
在(2×10-5 bar)压力下,通过热蒸发将纯氧化锆(ZrO2)沉积在不同衬底温度下的玻璃衬底上,沉积速率为(0.5 nm/S),平均厚度为(300 nm)。所制备薄膜的光学性质随衬底温度的变化而集中。结果表明,随着衬底温度的升高,薄膜的折射率、堆积密度和消光系数均增大。
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引用次数: 0
Design and simulation of Surface Plasmon Resonance based Solid Core Photonic crystal fiber biosensor 基于表面等离子体共振的固体核光子晶体光纤生物传感器的设计与仿真
Pub Date : 2021-12-10 DOI: 10.31257/2018/jkp/2021/130208
Ahmed H. Hadi, Firas S. Mohammed, Sudad Salman AL-Basaam
The purpose of a surface plasmon resonance (SPR)-based photonic crystal fiber (PCF) biosensor is to achieve a maximal sensitivity for the detection of unknown analytes. Outside of the PCF, the chemically stable and inert plasmonic material gold (Au) was utilized. A solid core photonic crystal fibre (SC-PCF) with an endlessly single-mode was designed in this work, with both the centred core and holes in the cladding structured by circles. The SC-PCF was designed with a single solid center core surrounded by a six-ring hexagonal cladding. SC-PCF was measured utilizing the finite element method (FEM) and the perfectly matched layer (PML) boundary condition. The FEM was used to investigate the performance using COMSOL Multiphysics software. The proposed biosensor shows  amplitude sensitivity of (167 to 886.38) RIU−1  within the sensing range of (1.3435 to 1.3471). Due to structural simplicity and excellent sensing properties, the proposed PCF can be regarded as a good biosensor.
基于表面等离子体共振(SPR)的光子晶体光纤(PCF)生物传感器的目的是实现对未知分析物检测的最大灵敏度。在PCF外,利用了化学稳定的惰性等离子体材料金(Au)。本文设计了一种具有无限单模的实心光子晶体光纤(SC-PCF),其中心芯和包层中的孔都是圆形结构。SC-PCF被设计成一个由六环六边形包层包围的单一实心核心。采用有限元法和完全匹配层边界条件对SC-PCF进行了测量。采用COMSOL Multiphysics软件对其性能进行了有限元分析。所提出的生物传感器在(1.3435至1.3471)的传感范围内显示出(167至886.38)RIU−1的振幅灵敏度。由于结构简单和优异的传感性能,所提出的PCF可以被认为是一种良好的生物传感器。
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引用次数: 0
Structural and Optical Characteristics of Carboxymethylcellulose / Polyacrylic Acid Polymer Blend 羧甲基纤维素/聚丙烯酸共混物的结构和光学特性
Pub Date : 2021-12-10 DOI: 10.31257/2018/jkp/2021/130204
Yaqoob M. Jawad, Mahasin F. Hadi Al- Kadhemy
The blending technology makes it possible to rebuild high molecular weights of partial polymers, thus to improve the product performance together with improvement of specific properties. Pure Carboxymethylcellulose (CMC) film and CMC (80%) doped Polyacrylic Acid (PAA) (20%) films were prepared by using a solution casting method. The influence of PAA polymer addition on the structural and optical properties of CMC polymer was investigated systematically. From X-ray diffraction patterns, adding a polymer PAA to a polymer CMC can lead to the appearance of peaks in polymer blend. FESEM image for CMC/ PAA film showed the formation of small spherical grains for PAA into CMC that insured the existence of some peaks in XRD pattern of PAA in CMC film which means the improvement of the microstructure of the polymer matrix. No chemical interactions were observed between CMC and PAA polymers from results of FTIR spectrum, so that incorporation of PAA into CMC polymer will results physical reaction only. The results of the UV spectrum have shown that the absorbance, absorption coefficient, extinction coefficient, refractive index, real and imaginary dielectric constants were increased in blend polymer compared with the pure polymer. The energy gap and transmittance of blend polymer compared with the pure polymer were reduced.
共混技术使部分聚合物的高分子量重建成为可能,从而在提高产品性能的同时改善了特定性能。采用溶液浇铸法制备了纯羧甲基纤维素(CMC)薄膜和CMC(80%)掺杂聚丙烯酸(PAA)(20%)薄膜。系统地研究了PAA聚合物的加入对CMC聚合物结构和光学性能的影响。从x射线衍射图来看,在聚合物CMC中加入聚合物PAA会导致聚合物共混物出现峰。CMC/ PAA膜的FESEM图像显示,PAA在CMC膜中形成了小的球形颗粒,这保证了CMC膜中PAA的XRD谱图中存在一些峰,说明聚合物基体的微观结构得到了改善。从FTIR光谱结果来看,CMC和PAA聚合物之间没有化学相互作用,因此PAA掺入CMC聚合物只会产生物理反应。紫外光谱结果表明,与纯聚合物相比,共混聚合物的吸光度、吸收系数、消光系数、折射率、实介电常数和虚介电常数均有所提高。与纯聚合物相比,共混聚合物的能隙和透光率均有所降低。
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引用次数: 0
The Structural and Optical Properties of Cobalt dioxide (CoO2 )Thin Films deposited via (SCSP) Technique for photovoltaic applications 利用(SCSP)技术沉积的光伏用二氧化钴薄膜的结构和光学性质
Pub Date : 2021-07-17 DOI: 10.31257/2018/jkp/2021/130104
M. Al-Helaly, Nathera A. Al-tememee
The research included the preparation and then studying the structural and optical properties of the cobalt dioxide (CoO2)films. The latter films were prepared using a semi-computerized spray pyrolysis technique (SCSPT),. The X-ray diffraction gave polycrystalline nature with crystal system trigonal (hexagonal axes), and the Energy Dispersive X-ray spectroscopy (EDX) showed that all films contain the elements (Co and O) indicating formation of (CoO2) films with high purity. FTIR measurements showed of chemical bonds of CoO2 clearly. Scanning Electron Microscopy (SEM ) Showed clearly that the formed thin films under the optimum conditions were homogeneous, dense and compact, and Atomic Force Microscopy(AFM) results showed that the topography of the film surface where surface roughness was found to be 7.91 nm, root mean square was 9.69 nm., and the average granularity diameter was 78.00 nm. The optical properties (absorbance, absorption coefficient, extinction coefficient, refractive index, optical Conductivity, the real ε_(1 ) and imaginary ε_2 part of the dielectric constant )were decreased with increasing the wavelength, while the transmittance increases with increasing wavelength. The optical energy gap was (1.98eV) and this is a good optical energy gap values for photovoltaic applications.
研究内容包括制备和研究二氧化钴薄膜的结构和光学性质。后一种薄膜采用半计算机化喷雾热解技术(SCSPT)制备。x射线衍射结果表明,薄膜为三(六)轴多晶系;x射线能谱分析(EDX)表明,所有薄膜均含有Co和O元素,表明形成了高纯度的(CoO2)薄膜。FTIR测量清楚地显示了CoO2的化学键。扫描电镜(SEM)结果表明,在最佳条件下制备的薄膜均匀、致密、致密;原子力显微镜(AFM)结果表明,薄膜表面形貌为7.91 nm,表面粗糙度为9.69 nm。,平均粒度直径为78.00 nm。光学性质(吸光度、吸收系数、消光系数、折射率、电导率、介电常数的实部ε_(1)和虚部ε_2)随波长的增加而降低,而透过率随波长的增加而增加。光能隙为(1.98eV),这是一个适合光伏应用的光能隙值。
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引用次数: 0
Elastic Scattering of Electron and Positron by Radium and Radon Atoms 镭和氡原子对电子和正电子的弹性散射
Pub Date : 2021-06-10 DOI: 10.31257/2018/jkp/2021/130101
A. Yassir, A. Hussain, F. A. Ali
The Differential Cross Sections (DCS's), Total Cross Sections (TCS's) and Momentum Transfer Cross Sections (MTCS's) of electron and positron scattering by radium and radon atoms were calculated in the range of energy (5–500) eV using a total potential consisting of combining the static, exchange and polarization potentials at long distances. In addition, the correlation potential of Perdew–Zunger at short distances for electrons was used, as well as the correlation potential of Jain for positrons. The exchange potential for positrons was neglected. In this study, a good agreement with other experimental values and theoretical values of many investigators was found.
在能量(5-500)eV范围内,利用长距离静态、交换和极化势组合而成的总势计算了镭和氡原子散射电子和正电子的微分截面(DCS)、总截面(TCS)和动量传递截面(MTCS)。此外,还利用了Perdew-Zunger的短距离电子相关电位和Jain的正电子相关电位。正电子的交换势被忽略了。在本研究中,我们发现与许多研究者的其他实验值和理论值有很好的一致性。
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引用次数: 0
Fabrication and Characterization of Dye Sensitized Solar Cells Based on TiO2 二氧化钛染料敏化太阳能电池的制备与表征
Pub Date : 2021-06-10 DOI: 10.31257/2018/jkp/2021/130105
Ghufran M. Abbas, Aref S. Baron
Thin films of TiO2 nanostructures were prepared on FTO bases with different temperatures 140 ° C and 160 °C for 4 h. The XRD results showed that that there was an increase in the intensity of the peaks of the prepared (quadrangular) samples and a decrease in the FWHM was observed due to the increase in temperature as well as increase in the grain size in which the distance between the grains was decreased. According to the UV-Vis results, the energy band gap Eg was calculated from the reflectivity spectrum using the Kobelka - Monk equation. The increase in temperature has reduced the energy band gap, which shifting it towards the blue direction. FESEM, an increase in the surface thickness of the thin film due to an increase in the preparation temperature. The solar cell efficiency was decreased with increased in temperature. Where it was found the efficiency reduce rom 0.17% to 0.004% for As for 140 ° C and 160 ° C respectively
在140℃和160℃的不同温度下,在FTO基底上制备TiO2纳米结构薄膜4 h。XRD结果表明,随着温度的升高,制备的样品(四边形)峰的强度增加,FWHM减小,晶粒尺寸增大,晶粒间距减小。根据UV-Vis结果,利用Kobelka - Monk方程从反射率谱计算了能带隙Eg。温度的升高减小了能带隙,使其向蓝色方向移动。在FESEM中,由于制备温度的升高,薄膜的表面厚度增加。太阳能电池的效率随着温度的升高而降低。在140°C和160°C时,效率分别从0.17%下降到0.004%
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引用次数: 0
Theoretical study of Linke's Turbidity at Some Iraqi Sites Based on Solar Radiation 基于太阳辐射的伊拉克林克浊度理论研究
Pub Date : 2021-06-10 DOI: 10.31257/2018/jkp/2021/130102
ali shkhair younus, S. N. A. Wahid
Turbidity was calculated by solar irradiance (Linke's Turbidity) for sixteen Iraqi sites. These sites were distributed among middle, north and south of Iraq. We have updated these results of turbidity by depending on direct solar radiation, diffuse solar radiation, total solar radiation, and solar constant as inputs for mathematical models in computer programs. The latter calculations taking into account the hours of actual sun shine, hours of theoretical sun shine of the sun, the angle of the sun's rays, and the angle of the sun during the months of the year. The results showed that turbidity in the Iraqi sites which considered in this research depends mainly on the months of the year regardless of the fact that this site is located in the north, middle or south of Iraq. The amount of turbidity is at its greatest value during the winter season, specifically the month of December, where the average turbidity varied for those sites. In latter month the turbidity was ranged from (4.85 to 5.73), while in January it ranged from (4.75 to 5.72), then it began to decrease until the value of turbidity in most sites reached its lowest level in September, where the average turbidity of the studied sites varied (except for the site of Najaf) in this month (2.82 - 3.10) While the Najaf site was unique in registering the lowest average amount of turbidity in June by (3.25). The results showed that the turbidity in all sites included in this research ranges between (2.82 - 5.73) during the year.
通过太阳辐照度(林克浊度)计算了伊拉克16个地点的浊度。这些场址分布在伊拉克中部、北部和南部。我们通过将太阳直接辐射、太阳漫射辐射、太阳总辐射和太阳常数作为计算机程序中数学模型的输入,更新了这些浊度的结果。后者的计算考虑了一年中的实际日照时数、理论日照时数、太阳光线的角度和太阳的角度。结果表明,本研究所考虑的伊拉克地点的浊度主要取决于一年中的月份,而不管该地点位于伊拉克北部、中部或南部。浊度在冬季达到最大值,特别是在12月份,这些地点的平均浊度变化很大。二月浊度为(4.85 ~ 5.73),一月浊度为(4.75 ~ 5.72),之后开始下降,直到9月份大部分站点的浊度值达到最低,9月份除纳杰夫站点外,其他站点的平均浊度值在2.82 ~ 3.10之间变化,而纳杰夫站点在6月份的平均浊度值最低,为(3.25)。结果显示,年内所有研究地点的浊度在(2.82 - 5.73)之间。
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引用次数: 0
Theoretical analysis of short backfire antenna by using Moment of method 利用矩量法对短逆火天线进行理论分析
Pub Date : 2021-06-10 DOI: 10.31257/2018/jkp/2021/130103
Ali K. Al-zuwain, Z. Ahmed, Wa'il A. Godaymi
The short backfire antenna is one of the important types of antennas due to its high directional and other characteristics. Therefore, this research deals with, a theoretical study to calculate the radiative structures of a short backfire antenna as an axially symmetric body using the moment method. The main goal is to theoretically calculate the radiation fields and compare them with previous practical researches. Where the mathematical analysis with the used software was verified by comparing the results and noting the extent of the match. The other goal is to study the effect of the antenna dimensions on its performance by studying the effect of adding a rim to the edge of the large back reflector, as well as studying the change of the radius of the two reflectors (large and small), where it was confirmed that the best value for the radius of the large reflectors and small (Rm=1λ) (Rs= 0.25 λ) respectively.
短逆火天线以其高指向性等特点成为一种重要的天线类型。因此,本文对采用矩量法计算短逆火天线作为轴对称体的辐射结构进行了理论研究。主要目的是对辐射场进行理论计算,并与以往的实际研究结果进行比较。其中使用的软件进行数学分析,通过比较结果并注意匹配程度来验证。另一个目标是研究天线尺寸对其性能的影响,通过研究在大型后反射器边缘增加边缘的影响,以及研究两个反射器(大反射器和小反射器)半径的变化,确定了大反射器和小反射器(Rm=1λ) (Rs= 0.25 λ)的半径的最佳值。
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引用次数: 0
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Journal of Kufa - Physics
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