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A novel concept for low drift chemical sensing at micro and nano-scale 微纳米尺度低漂移化学传感的新概念
Pub Date : 2010-12-03 DOI: 10.1109/SMICND.2010.5650518
C. Cobianu, B. Șerban, I. Georgescu, S. Costea, C. Bostan
It is the purpose of this paper to present a novel generic concept for low drift chemical sensing which is applicable at micro and nanometer scale, based on a new, all-differential approach. At micrometer level, our principle is explained by means of surface acoustic wave (SAW) chemical sensing, while at nano level, we are using the resonant sensing principle to develop our genuine differential concept. Unlike the traditional differential approaches based on functionalized sensing layer in the sensing loop, and on a uncoated surface in the reference loop, our all differential concept provides a better response subtraction between the two paths, as the sensing loop consists of a functionalized sensing layer, as before, but, the reference loop consists of a functionalized non-sensing layer, with the same ageing and humidity behavior as the sensing layer. Twinned electronic reading is used for both loops, and thus all the common mode signals are subtracted in the differential reading, assuring the minimum base line drift of the sensor. Preliminary results of all differential sensor response to humidity and temperature variations are shown for the SAW sensors, with the sensor signal kept independent of their changes.
本文的目的是基于一种新的全微分方法,提出一种适用于微纳米尺度的低漂移化学传感的通用概念。在微米级,我们的原理是通过表面声波(SAW)化学传感来解释的,而在纳米级,我们正在使用共振传感原理来发展我们真正的微分概念。与传统的基于传感回路中功能化传感层和参考回路中未涂覆表面的差分方法不同,我们的全差分概念在两条路径之间提供了更好的响应减法,因为传感回路由一个功能化的传感层组成,就像以前一样,但是,参考回路由一个功能化的非传感层组成,具有与传感层相同的老化和湿度行为。两个回路都使用双电子读数,因此所有共模信号在差分读数中被减去,确保传感器的基线漂移最小。所有差分传感器对湿度和温度变化的响应的初步结果显示了SAW传感器,传感器信号保持独立于它们的变化。
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引用次数: 3
High temperature SiC Schottky diodes with stable operation for space application 工作稳定的高温SiC肖特基二极管,适用于空间应用
Pub Date : 2010-12-03 DOI: 10.1109/SMICND.2010.5650590
V. Banu, P. Godignon, X. Jordà, M. Vellvehí, J. Millán, P. Brosselard, D. López, J. Barbero
This work presents the long-term stability of the SiC Schottky diodes able to operate in the temperature range −170°C/280°C, specially developed for the space mission BepiColombo. This mission consists in launching two satellites around the Mercury planet. After a travel of 6 years, the satellites will be orbiting around Mercury at least one year. When orbiting around Mercury, the satellites will experience seasonal eclipses. The numbers of cycles −170°C/280°C are in the range of 4,000. The diodes are used as protection devices for the solar cells arrays. To target this application, we have developed 5A/300V breakdown voltage Silicon Carbide Schottky diodes. Long-term tests demonstrated a very good stability of the electrical, mechanical and thermal parameters.
这项工作展示了能够在- 170°C/280°C温度范围内工作的SiC肖特基二极管的长期稳定性,该二极管专门为BepiColombo太空任务开发。这次任务包括发射两颗环绕水星的卫星。经过6年的飞行,这些卫星将绕水星运行至少一年。当卫星绕水星运行时,将经历季节性日食。−170°C/280°C的循环次数范围为4000。二极管用作太阳能电池阵列的保护装置。针对这一应用,我们开发了5A/300V击穿电压碳化硅肖特基二极管。长期试验表明,该装置具有良好的电气、机械和热参数稳定性。
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引用次数: 6
New polyimides containing aliphatic segments and thin films based on them 含脂肪段的新型聚酰亚胺及其薄膜
Pub Date : 2010-12-03 DOI: 10.1109/SMICND.2010.5650689
D. Popovici, C. Hulubei, V. Musteata, M. Brumǎ, A. Muller
A series of polyimides (PI) based on two dianhydrides, namely 5-(2,5-dioxotetra-hydro-3-furanyl)-3-methyl-3-cyclohexene-1,2-dicarboxylicanhydride (DOCDA) and benzophenonetetracarboxylicdianhydride (BTDA), and an aliphatic diamine, namely 1,6 diaminohexane (DAH), have been obtained by solution polycondensation reaction, followed by thermal ring closure of the resulting polyamic acids. The chemical structures were identified by infrared and 1H-NMR spectroscopy and their thermal and electrical properties (dielectric constant and dielectric loss at different frequencies) were investigated. The polymers showed good thermal stability, with no significant weight loss up to 340°C, with 5% weight loss temperature in the range of 345–430°C and glass transition temperatures (Tgs) between 122–190°C. The resulting polyimides gave flexible films by thermal imdization of poly (amic acid) precursors. The AFM analysis revealed a smooth topography of their surfaces, with root-mean-square (Sq) roughness between 0.42–6.32 nm and average roughness (Sa) in the range of 0.33–2.39 nm. The dielectric constants of the PI films varied between 3.05 and 2.68 at 1 MHz frequency. The correlation between the polymers structure and their properties has been discussed.
以5-(2,5-二氧四氢-3-呋喃基)-3-甲基-3-环己烯-1,2-二甲酸二酐(DOCDA)和苯二苯四甲酸四甲酸二酐(BTDA)两种二酐和1,6 -二甲酸二胺(DAH)为原料,通过溶液缩聚反应制得一系列聚酰亚胺(PI),并进行热封环反应。利用红外光谱和核磁共振光谱对其化学结构进行了鉴定,并对其热学和电学性能(介电常数和不同频率下的介电损耗)进行了研究。聚合物表现出良好的热稳定性,在340℃以下无明显失重,在345 ~ 430℃范围内失重5%,玻璃化转变温度(Tgs)在122 ~ 190℃之间。所得聚酰亚胺通过聚酰胺酸前驱体的热成像得到柔性薄膜。AFM分析显示其表面形貌光滑,均方根粗糙度(Sq)在0.42 ~ 6.32 nm之间,平均粗糙度(Sa)在0.33 ~ 2.39 nm之间。在1 MHz频率下,PI薄膜的介电常数在3.05 ~ 2.68之间变化。讨论了聚合物的结构与性能之间的关系。
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引用次数: 0
CNT film grown on nanoporous silicon 纳米多孔硅上生长的碳纳米管薄膜
Pub Date : 2010-12-03 DOI: 10.1109/SMICND.2010.5650256
E. Czerwosz, E. Kowalska, M. Kozłowski, H. Wronka, F. Craciunoiu, M. Miu, A. Dinescu
Results of SEM characterization of CNT film grown on nanoporous silicon (NP-Si) plate covered with 2 step PVD/CVD layer are presented. SEM studies were performed for all stages of CNT film preparation process. It was found that the size of pores in NP-Si affects the final CNT film form and adhesion.
给出了在纳米多孔硅(NP-Si)板上生长的碳纳米管薄膜的SEM表征结果。扫描电镜研究了碳纳米管薄膜制备过程的各个阶段。结果表明,纳米硅孔的大小影响纳米碳纳米管薄膜的最终形成和粘附性。
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引用次数: 0
Mesoporous carbon pipes-suitable materials for photocatalytic supports 介孔碳管——适合于光催化支架的材料
Pub Date : 2010-12-03 DOI: 10.1109/SMICND.2010.5650615
M. Ignat, C. Pastravanu, E. Popovici
Carbon nanotubes, fullerenes, and mesoporous carbon structures constitute a new class of carbon nanomaterials with properties that differ significantly from other forms of carbon such as graphite and diamond. The ability to custom synthesize fiber-like mesoporous carbon with attached functional groups has opened up new avenues to design high surface area catalyst supports and materials with high photochemical activity. Unlike the conventional graphite phase, carbon nanostructures possess metallic or semiconductor properties that can induce catalysis by participating directly in the charge transfer process. Further, the photochemical properties of these materials facilitate modulation of their charge transfer properties and aid in the design of photocatalysts for phenol degradation.
碳纳米管、富勒烯和介孔碳结构构成了一类新的碳纳米材料,其性质与其他形式的碳(如石墨和金刚石)有很大不同。自定义合成具有连接官能团的纤维状介孔碳的能力为设计高表面积催化剂载体和具有高光化学活性的材料开辟了新的途径。与传统的石墨相不同,碳纳米结构具有金属或半导体性质,可以通过直接参与电荷转移过程来诱导催化。此外,这些材料的光化学性质有助于调节它们的电荷转移性质,并有助于设计用于苯酚降解的光催化剂。
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引用次数: 1
Effect of dopant on the thermal and electrical behavior of nanostructured ceria materials 掺杂剂对纳米结构二氧化铈材料热电性能的影响
Pub Date : 2010-12-03 DOI: 10.1109/SMICND.2010.5650675
N. Cioateră, V. Pârvulescu, A. Rolle, R. Vannier
Nanopowders with compositions Ce0.8Gd0.2O2−δ (CG), Ce0.8Sm0.2O2−δ (CS), and Ce0.9Eu0.1O2−δ (CE) have been synthesized by a modified Pechini method. X-ray diffraction (XRD) revealed that all powders calcined at 550°C were single phase, with the cubic fluorite-type structure. The good sintering properties of the synthesized nanopowders allowed us to obtain dense ceramics (>97% theoretical density). The ionic conductivities of doped ceria ceramics were investigated as a function of temperature by using AC impedance spectroscopy in the temperature range 300–800°C. The best conductivity was evidenced for the Ce0.8Sm0.2O2−δ sample.
采用改进的Pechini法制备了Ce0.8Gd0.2O2−δ (CG)、Ce0.8Sm0.2O2−δ (CS)和Ce0.9Eu0.1O2−δ (CE)纳米粉体。x射线衍射(XRD)表明,550℃煅烧后的粉末均为单相,具有立方萤石型结构。合成的纳米粉末具有良好的烧结性能,使我们能够获得致密的陶瓷(>97%的理论密度)。在300 ~ 800℃的温度范围内,利用交流阻抗谱研究了掺杂铈陶瓷的离子电导率随温度的变化规律。Ce0.8Sm0.2O2−δ样品的电导率最高。
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引用次数: 0
DIffractive Microlenses With binary focal points on the optical axis 在光轴上有双焦点的衍射微透镜
Pub Date : 2010-12-03 DOI: 10.1109/SMICND.2010.5650237
M. Mihailescu, A. Sobetkii, M. Pelteacu
The aim of our study was to find a simple design for diffractive microlenses (DMLs) which will generate two focal points on the propagation axis at plane wave incidence. We investigate the influence of the missing central zones in the diffraction pattern. The fabrication steps include e-beam lithography (for mask pattern) and reactive ion etching (for transparent DMLs). To visualize their transparent binary microrelief and the phase profile, we employ the digital holographic microscopy technique. Experimental and simulation results are presented.
我们的研究目的是找到一种简单的衍射微透镜(dml)的设计,它将在平面波入射时在传播轴上产生两个焦点。我们研究了衍射图中中心区域缺失的影响。制造步骤包括电子束光刻(用于掩模图案)和反应离子蚀刻(用于透明dml)。为了可视化它们的透明二元微浮雕和相位轮廓,我们采用了数字全息显微镜技术。给出了实验和仿真结果。
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引用次数: 0
Selection of gas sensing materials using the Hard Soft Acid Base theory; application to Surface Acoustic Wave CO2 detection 软硬酸碱理论在气敏材料选择中的应用在表面声波CO2探测中的应用
Pub Date : 2010-12-03 DOI: 10.1109/SMICND.2010.5650619
B. Șerban, A. K. Sarin Kumar, C. Cobianu, O. Buiu, S. Costea, C. Bostan, N. Varachiu
The Hard Soft Acid Base (HSAB) theory is introduced as a new tool to select or design sensitive materials for carbon dioxide detection with SAW-BAW (Surface Acoustic Waves - Bulk Acoustic Waves) devices. According to HSAB, CO2 is hard acid, thus small organic or inorganic molecules, or polymers which can act as hard bases could be suitable candidates as sensing layers for carbon dioxide detection. As a consequence of this theory, we propose the following polymers as potential candidates for CO2 sensing: simple polyallylamine, N-substituted polyallylamine, polydiallylamine and polyvinylamine, and mixtures of these polymers. The SAW device coated with one of the selected polymers, polyallyamine, shows good sensitivity for CO2 concentration (in the range 500–5000 ppm), long term stability and repeatability.
介绍了硬软酸碱(HSAB)理论作为选择或设计表面声波-体声波(SAW-BAW)检测二氧化碳敏感材料的新工具。根据HSAB的说法,二氧化碳是硬酸,因此可以作为硬碱的小有机或无机分子或聚合物可以作为二氧化碳检测的传感层的合适候选人。根据这一理论,我们提出以下聚合物作为二氧化碳传感的潜在候选者:简单聚烯丙胺,n -取代聚烯丙胺,聚二烯丙胺和聚乙烯胺,以及这些聚合物的混合物。所选择的聚合物聚烯丙胺涂层的SAW装置对CO2浓度(在500 - 5000ppm范围内)具有良好的灵敏度,长期稳定性和可重复性。
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引用次数: 9
Analysis of liquids and viscoelestic films by quartz crystal microbalance 用石英晶体微天平分析液体和粘弹性薄膜
Pub Date : 2010-12-03 DOI: 10.1109/SMICND.2010.5650488
I. Dulama, G. Cimpoca, C. Radulescu, I. Popescu, I. Bancuta, M. Cimpoca, I. Cernica
In this paper we present a very new technique for analytical methods which utilize the quartz crystal microbalance (QCM). This is rapid expansion in application and understanding-oriented work. Using the QCM in the liquid phase and applying it to non-rigid over layers have created new experimental opportunities. In research, the most common QCM crystal applications include metal deposition monitors, chemical reaction monitors, biomedical sensors, and environmental monitoring applications.
本文介绍了一种利用石英晶体微天平(QCM)进行分析的新技术。这是应用和理解导向工作的快速扩展。在液相中使用QCM并将其应用于非刚性覆盖层创造了新的实验机会。在研究中,最常见的QCM晶体应用包括金属沉积监测、化学反应监测、生物医学传感器和环境监测应用。
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引用次数: 3
300mA adjustable LDO with 10µA ground current 300mA可调LDO,接地电流为10µA
Pub Date : 2010-12-03 DOI: 10.1109/SMICND.2010.5650532
C. Stănescu, R. Iacob, C. Dinca, C. Caracas, O. Profirescu
This paper presents an adjustable 300mA CMOS LDO built in a double-metal 0.5µm 16V CMOS technology. It uses a low-current bandgap which needs only 1.5µA. It includes a symmetrical op amp configured as voltage follower, having a built-in adaptive bias behavior. The circuit consumes 10µA without load, less than 40 µA at full load, and uses a 1.25V voltage reference. Dropout voltage at 300mA is typical 200mV. Input voltage range is 2.3V to 7V.
本文介绍了一种可调300mA CMOS LDO,采用双金属0.5µm 16V CMOS技术。它采用低电流带隙,只需要1.5µa。它包括一个对称运放,配置为电压跟随器,具有内置的自适应偏置行为。该电路空载时功耗为10µA,满载时功耗小于40µA,参考电压为1.25V。300mA时的压降电压一般为200mV。输入电压范围2.3V ~ 7V。
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引用次数: 0
期刊
CAS 2010 Proceedings (International Semiconductor Conference)
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