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Intense Orange Red Emission from Sm3+-Activated Ca3Al2O6 Phosphor for Display Device Application 用于显示设备应用的 Sm3+ 激活型 Ca3Al2O6 磷光体发出的强烈橘红色荧光
IF 0.6 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2024-07-03 DOI: 10.1007/s11182-024-03207-z
K. Koteswara Rao, M. C. Rao, Vikas Dubey

The synthesis and the structural and luminescence studies of samarium-doped calcium aluminate phosphors are reported. These phosphors are synthesized by the solid-state reaction method with a variable concentration of doping ions (0.5–3.0 mol%). The synthesized phosphors are characterized by the X-ray diffraction (XRD), scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) techniques. The XRD studies show that the doped phosphors have a cubic structure. The SEM images reveal that the Sm3+- doped Ca3Al2O6 phosphor represents a combination of some rod-like and flower-like structures. The FTIR studies confirm the formation of a Ca3Al2O6:Sm3+ phosphor. The photoluminescence (PL) emission measurements upon excitation by 273 nm (ultraviolet light) show the characteristic emission peaks of Sm3+ at 579, 589, 600 and 619 nm. The characteristic orange-red emission is observed for samarium ion. The excitation spectra of the Ca3Al2O6:Sm3+ phosphor mainly consist of a more intense charge transfer band (CTB) of Sm3+ located at 273 and 395 nm with some peaks centred at 319 and 362 nm. The CIE coordinates are calculated by the spectrophotometric method using the spectral energy distribution of the Ca3Al2O6:Sm3+ sample. The prepared phosphors can act as a single host for orange-red light emission in display devices.

报告了掺杂钐的铝酸钙荧光粉的合成、结构和发光研究。这些荧光粉是通过固态反应法合成的,掺杂离子的浓度可变(0.5-3.0 摩尔%)。通过 X 射线衍射(XRD)、扫描电子显微镜(SEM)和傅立叶变换红外光谱(FTIR)技术对合成的荧光粉进行了表征。X 射线衍射研究表明,掺杂荧光粉具有立方结构。扫描电镜图像显示,Sm3+-掺杂的 Ca3Al2O6 磷光体是一些棒状和花状结构的组合。傅立叶变换红外光谱研究证实了 Ca3Al2O6:Sm3+ 荧光粉的形成。在 273 nm(紫外线)激发下进行的光致发光(PL)发射测量显示,Sm3+ 在 579、589、600 和 619 nm 处有特征发射峰。钐离子则发出橙红色的发射光。Ca3Al2O6:Sm3+ 荧光粉的激发光谱主要由位于 273 和 395 纳米的 Sm3+ 的较强电荷转移带(CTB)和位于 319 和 362 纳米的一些峰组成。CIE 坐标是利用 Ca3Al2O6:Sm3+ 样品的光谱能量分布,通过分光光度法计算得出的。所制备的荧光粉可作为显示设备中橙红光发射的单一宿主。
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引用次数: 0
Infinities in molecular quantum electrodynamics and generalized functions 分子量子电动力学中的无穷性和广义函数
IF 2.9 2区 物理与天体物理 Q2 Physics and Astronomy Pub Date : 2024-07-03 DOI: 10.1103/physreva.110.012204
R. Guy Woolley
The Power-Zienau-Woolley Hamiltonian for the quantum electrodynamics of atoms and molecules is written in terms of purely transverse electromagnetic field variables and so-called polarization fields for the charged particles. It is well known that the attempt at finding solutions to the coupled equations that arise from the Hamiltonian is marred by the occurrence of infinite “self-energies” for both particles and the field. Because of the occurrence of the Dirac δ function in the nonzero Poisson-brackets/commutation relation for the fields, and in the definition of the polarization fields, these variables, classical and quantum, must be identified as distributions, in the mathematical sense. The Schwartz “impossibility theorem” shows that there is no general multiplication rule for distributions, so one has to find a framework that gives meaning to the Hamiltonian The energy of the electric polarization field is analyzed in the Colombeau algebra and shown to be finite; in particular Coulomb's law (1/r,r>0) with a finite self-energy (r=0) is obtained. How these ideas could be extended to the free-field Hamiltonian is discussed. A finite zero-point energy for the electromagnetic field is to be expected. Relevant mathematical results are summarized in an Appendix.
原子和分子量子电动力学的鲍尔-齐瑙-伍利哈密顿方程(Power-Zienau-Woolley Hamiltonian)是用带电粒子的纯横向电磁场变量和所谓的极化场写成的。众所周知,由于粒子和磁场都存在无限的 "自能",因此在试图寻找由哈密顿方程产生的耦合方程的解时,会受到影响。由于场的非零泊松比列/换向关系中出现了狄拉克δ函数,而且在极化场的定义中也出现了狄拉克δ函数,因此从数学意义上讲,这些变量,无论是经典变量还是量子变量,都必须被确定为分布。施瓦茨 "不可能定理 "表明,不存在分布的一般乘法规则,因此我们必须找到一个框架,赋予哈密顿的意义。在科隆博代数中分析了电偏振场的能量,并证明它是有限的;特别是得到了具有有限自能(r=0)的库仑定律(1/r,r>0)。讨论了如何将这些观点扩展到自由场哈密顿。电磁场的有限零点能是可以预期的。附录中总结了相关的数学结果。
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引用次数: 0
Improving robustness of quantum feedback control with reinforcement learning 利用强化学习提高量子反馈控制的鲁棒性
IF 2.9 2区 物理与天体物理 Q2 Physics and Astronomy Pub Date : 2024-07-03 DOI: 10.1103/physreva.110.012605
Manuel Guatto, Gian Antonio Susto, Francesco Ticozzi
Obtaining reliable state preparation protocols is a key step toward practical implementation of many quantum technologies, and one of the main tasks in quantum control. In this work, different reinforcement learning approaches are used to derive a feedback law for state preparation of a desired state in a target system. In particular, we focus on the robustness of the obtained strategies with respect to different types and amount of noise. Comparing the results indicates that the learned controls are more robust to unmodeled perturbations with respect to simple feedback strategy based on optimized population transfer, and that training on a simulated nominal model retains the same advantages displayed by controllers trained on real data. The possibility of effective off-line training of robust controllers promises significant advantages toward practical implementation.
获得可靠的状态准备协议是实现许多量子技术实用化的关键一步,也是量子控制的主要任务之一。在这项工作中,我们采用了不同的强化学习方法来推导目标系统中理想状态的状态准备反馈法则。我们特别关注所获得的策略在不同类型和数量的噪声面前的鲁棒性。比较结果表明,与基于优化群体转移的简单反馈策略相比,学习到的控制策略对未建模的扰动具有更强的鲁棒性。对鲁棒控制器进行有效离线训练的可能性有望为实际应用带来显著优势。
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引用次数: 0
Erratum: High-spin states of the semimagic nucleus Pr141 [Phys. Rev. C 91, 064319 (2015)] 勘误:半魔核 Pr141 的高自旋态 [Phys. Rev. C 91, 064319 (2015)]
IF 3.1 2区 物理与天体物理 Q1 Physics and Astronomy Pub Date : 2024-07-03 DOI: 10.1103/physrevc.110.019903
Z. Q. Li (李志泉), S. Y. Wang (王守宇), L. Liu (刘雷), Y. M. Zhang (张亚梅), B. Qi (亓斌), S. Wang (王硕), D. P. Sun (孙大鹏), C. Liu (刘晨), P. Zhang (张盼), N. B. Zhang (张乃波), H. Jia (贾慧), Q. Hu (胡琪), C. Y. Niu (牛阳), Z. Q. Chen (陈志强), P. Lv (吕品), C. Y. Li (李传洋), X. G. Wu (吴晓光), G. S. Li (李广生), C. Y. He (贺创业), Y. Zheng (郑云), C. B. Li (李聪博), H. W. Li (李红伟), P. W. Luo (罗朋威)
DOI:https://doi.org/10.1103/PhysRevC.110.019903
DOI:https://doi.org/10.1103/PhysRevC.110.019903
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引用次数: 0
Structure and Properties of Composite Coatings with Zro2 and Tio2 Particles After Lehceb Treatment 雷西卜处理后含有 Zro2 和 Tio2 粒子的复合涂层的结构和性能
IF 0.6 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2024-07-03 DOI: 10.1007/s11182-024-03194-1
M. B. Sedelnikova, A. D. Kashin, P. V. Uvarkin, Y. P. Sharkeev, A. V. Ugodchikova, N. A. Luginin, M. A. Khimich, K. V. Ivanov

The paper presents the comprehensive analysis of the structure, properties, and corrosion of micro-arc coatings with ZrO2 and TiO2 particles after the low-energy high-current electron beam (LEHCEB) treatment. The coating morphology, microstructure, phase and elemental compositions are investigated by the scanning electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray powder diffraction. After the LEHCEB treatment, the coating structure with ZrO2 particles changes from friable and porous to denser with closed spheroidal pores. It is shown that the adhesive strength of the coating with ZrO2 particles increases with the critical load growth from 10 to 18 N. Moreover, the treatment enhances its corrosion resistance, as evidenced by a reduction in the corrosion current from 7.48∙10–7 to 1.05∙10–8 A/cm2 and an increase in polarization resistance from 0.9·104 to 5.77∙106 Ω·cm2. In contrast, the coatings with TiO2 particles exhibit a more porous structure due to the volatilization of low-melting components (sodium silicates), as evidenced by a reduction in the concentration of Na and Si elements in their composition. The adhesive strength and corrosion resistance of the coatings with TiO2 particles deteriorate after the treatment.

本文全面分析了经低能大电流电子束(LEHCEB)处理后的 ZrO2 和 TiO2 粒子微弧涂层的结构、性能和腐蚀情况。通过扫描电子显微镜、能量色散 X 射线光谱和 X 射线粉末衍射研究了涂层的形貌、微观结构、相和元素组成。经 LEHCEB 处理后,含有 ZrO2 颗粒的涂层结构从易碎多孔变为致密封闭的球形孔。此外,该处理还增强了涂层的耐腐蚀性,具体表现为腐蚀电流从 7.48∙10-7 降低到 1.05∙10-8 A/cm2,极化电阻从 0.9-104 增加到 5.77∙106 Ω-cm2。相比之下,由于低熔点成分(硅酸钠)的挥发,含有 TiO2 颗粒的涂层显示出更多孔的结构,这从其成分中 Na 和 Si 元素浓度的降低可以看出。经过处理后,带有 TiO2 颗粒的涂层的粘合强度和耐腐蚀性能都有所下降。
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引用次数: 0
Projected WIMP sensitivity of the CDEX-50 dark matter experiment CDEX-50 暗物质实验的预计 WIMP 敏感度
IF 6.4 2区 物理与天体物理 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2024-07-03 DOI: 10.1088/1475-7516/2024/07/009
X.P. Geng, L.T. Yang, Q. Yue, K.J. Kang, Y.J. Li, H.P. An, Greeshma C, J.P. Chang, Y.H. Chen, J.P. Cheng, W.H. Dai, Z. Deng, C.H. Fang, H. Gong, Q.J. Guo, T. Guo, X.Y. Guo, L. He, S.M. He, J.W. Hu, H.X. Huang, T.C. Huang, L. Jiang, S. Karmakar, H.B. Li, H.Y. Li, J.M. Li, J. Li, Q.Y. Li, R.M.J. Li, X.Q. Li, Y.L. Li, Y.F. Liang, B. Liao, F.K. Lin, S.T. Lin, J.X. Liu, S.K. Liu, Y.D. Liu, Y. Liu, Y.Y. Liu, H. Ma, Y.C. Mao, Q.Y. Nie, J.H. Ning, H. Pan, N.C. Qi, J. Ren, X.C. Ruan, M.K. Singh, T.X. Sun, C.J. Tang, Y. Tian, G.F. Wang, J.Z. Wang, L. Wang, Q. Wang, Y.F. Wang, Y.X. Wang, H.T. Wong, S.Y. Wu, Y.C. Wu, H.Y. Xing, R. Xu, Y. Xu, T. Xue, Y.L. Yan, N. Yi, C.X. Yu, H.J. Yu, J.F. Yue, M. Zeng, Z. Zeng, B.T. Zhang, F.S. Zhang, L. Zhang, Z.H. Zhang, Z.Y. Zhang, J.Z. Zhao, K.K. Zhao, M.G. Zhao, J.F. Zhou, Z.Y. Zhou, J.J. Zhu and The CDEX collaboration
CDEX-50 is a next-generation project of the China Dark Matter Experiment (CDEX) that aims to search for dark matter using a 50-kg germanium detector array. This paper comprises a thorough summary of the CDEX-50 dark matter experiment, including an investigation of potential background sources and the development of a background model. Based on the baseline model, the projected sensitivity of weakly interacting massive particle (WIMP) is also presented. The expected background level within the energy region of interest, set to 2–2.5 keVee, is ∼0.01 counts keVee-1 kg-1 day-1. At 90% confidence level, the expected sensitivity to spin-independent WIMP-nucleon couplings is estimated to reach a cross-section of 5.1 × 10-45 cm2 for a WIMP mass of 5 GeV/c2 with an exposure objective of 150 kg·year and an analysis threshold of 160 eVee. This science goal will correspond to the most sensitive results for WIMPs with a mass of 2.2–8 GeV/c2.
CDEX-50是中国暗物质实验(CDEX)的下一代项目,旨在利用50公斤重的锗探测器阵列搜索暗物质。本文对CDEX-50暗物质实验进行了全面总结,包括潜在背景源的调查和背景模型的建立。在基线模型的基础上,还介绍了弱相互作用大质量粒子(WIMP)的预计灵敏度。在所关注的能量区域(设定为 2-2.5 keVee)内的预期背景水平为 ∼0.01 计数 keVee-1 kg-1 day-1。在 90% 的置信度下,对自旋无关的 WIMP 核耦合的预期灵敏度估计将达到 5.1 × 10-45 平方厘米,WIMP 质量为 5 GeV/c2,曝光目标为 150 千克/年,分析阈值为 160 eVee。这一科学目标将对应于质量为 2.2-8 GeV/c2 的 WIMP 的最灵敏结果。
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引用次数: 0
Enhanced thermoelectric performance of MoSe2 under high pressure and high temperature by suppressing bipolar effect 通过抑制双极效应提高 MoSe2 在高压高温下的热电性能
IF 4 2区 物理与天体物理 Q2 PHYSICS, APPLIED Pub Date : 2024-07-03 DOI: 10.1063/5.0217965
Dianzhen Wang, Cun You, Yufei Ge, Fei Wang, Xinglin Wang, Xiao Liang, Qiang Zhou, Qiang Tao, Yanli Chen, Pinwen Zhu
The electrical transport property of layered MoSe2 has a strong response to high pressure by enhancing the inter-layer interaction. However, the narrowed bandgap under high pressure will cause the bipolar effect (i.e., the thermally excited minority carriers contribute to a Seebeck coefficient with the opposite sign to the majority carriers) at high temperatures to degrade the thermoelectric (TE) performance. Hence, suppressing the bipolar effect is important to optimize the TE performance of MoSe2 under high pressure and high temperature (HPHT). In this study, the degradation of TE performance caused by the bipolar effect under HPHT in MoSe2 is investigated. It is found that in MoSe2, the electrical conductivity was improved significantly by pressure; however, the bipolar effect led to a significantly degraded Seebeck coefficient at high temperatures. By injecting massive carriers beforehand, the bipolar effect was suppressed to make a dominant type of p-type charge carries, achieving an increased Seebeck coefficient with increasing temperature, resulting in an improved power factor from 29.3 μW m−1 K−2 in MoSe2 to 285.7 μW m−1 K−2 in Mo0.98Nb0.02Se2 at 5.5 GPa, 1110 K. Combined with the reduced thermal conductivity by point defect scattering on phonons, a maximum ZT value of 0.11 at 5.5 GPa, 1110 K. This work highlights the significance of suppressing the bipolar effect under HPHT for optimizing TE performance in such layered semiconductors.
通过增强层间相互作用,层状 MoSe2 的电气传输特性对高压有很强的响应。然而,高压下带隙变窄会导致高温下的双极效应(即热激发的少数载流子产生与多数载流子符号相反的塞贝克系数),从而降低热电(TE)性能。因此,抑制双极效应对于优化 MoSe2 在高压高温(HPHT)条件下的 TE 性能非常重要。本研究探讨了双极效应导致 MoSe2 在高压高温下 TE 性能下降的问题。研究发现,MoSe2 的电导率在压力作用下得到了显著改善;然而,双极效应导致其在高温下的塞贝克系数明显降低。通过事先注入大量载流子,双极效应被抑制,从而使 p 型电荷载流子占主导地位,实现了塞贝克系数随温度升高而增大,使功率因数从 MoSe2 的 29.3 μW m-1 K-2 提高到 Mo0.02Se2 的 285.7 μW m-1 K-2。在 5.5 GPa、1110 K 条件下,功率因数从 MoSe2 中的 29.3 μW m-1 K-2 提高到 Mo0.98Nb0.02Se2 中的 285.7 μW m-1 K-2;再加上点缺陷对声子的散射降低了热导率,在 5.5 GPa、1110 K 条件下,ZT 值达到最大值 0.11。
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引用次数: 0
Coherent phonons in incommensurate LaVS3 crystal 不相容 LaVS3 晶体中的相干声子
IF 4 2区 物理与天体物理 Q2 PHYSICS, APPLIED Pub Date : 2024-07-03 DOI: 10.1063/5.0211057
M. Weis, M. Lejman, J. Faure, V. Ta Phuoc, L. Cario, D. Boschetto
In this Letter, we investigate coherent phonon dynamics in the incommensurate LaVS3 crystal by femtosecond pump-probe spectroscopy. Two coherent phonon modes are systematically observed in the transient reflectivity, centered at 1.8 and 2.85 THz, respectively, while a third mode centered at 4.5 THz is observed only at high pump fluence. The experimental results obtained at two different polarization configurations as well as a comparison with recent theoretical results allow to assign the two main modes to the interlayer shearing mode and to an intralayer mode, respectively. Two possible assignments are discussed for the third mode, by invoking a possible emergence of nonlinear phonon processes.
在这封信中,我们通过飞秒泵浦探针光谱学研究了不互称的 LaVS3 晶体中的相干声子动力学。在瞬态反射率中系统地观察到了两个相干声子模式,分别以 1.8 和 2.85 太赫兹为中心,而第三个以 4.5 太赫兹为中心的模式只有在高泵浦通量下才能观察到。根据在两种不同偏振配置下获得的实验结果以及与最新理论结果的比较,可以将这两种主要模式分别归结为层间剪切模式和层内模式。通过非线性声子过程的可能出现,讨论了第三种模式的两种可能归属。
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引用次数: 0
Magnetization Dynamics in Quasiperiodic Magnonic Crystals. 准周期磁性晶体中的磁化动力学。
IF 2.3 4区 物理与天体物理 Q3 PHYSICS, CONDENSED MATTER Pub Date : 2024-07-03 DOI: 10.1088/1361-648X/ad5ee8
R Mehta, Bivas Rana, Susmita Saha

Quasiperiodic magnonic crystals, in contrast to their periodic counterparts, lack strict periodicity which gives rise to complex and localised spin wave spectra characterized by numerous band gaps and fractal features. Despite their intrinsic structural complexity, quasiperiodic nature of these magnonic crystals enables better tunability of spin wave spectra over their periodic counterparts and therefore holds promise for the applications in reprogrammable magnonic devices. In this article, we provide an overview of magnetization reversal and precessional magnetization dynamics studied so far in various quasiperiodic magnonic crystals, illustrating how their quasiperiodic nature gives rise to tailored band structure, enabling unparalleled control over spin waves. The review is concluded by highlighting the possible potential applications of these quasiperiodic magnonic crystals, exploring potential avenues for future exploration followed by a brief summary.

与周期性晶体相比,准周期性磁性晶体缺乏严格的周期性,因而产生了以众多带隙和分形特征为特点的复杂局部自旋波谱。尽管这些磁性晶体具有内在的结构复杂性,但与周期性晶体相比,它们的准周期性使自旋波谱具有更好的可调性,因此有望应用于可重新编程的磁性器件。在这篇文章中,我们概述了迄今为止在各种准周期磁性晶体中研究的磁化反转和前向磁化动力学 ,说明了它们的 准周期性质如何产生定制的带状结构,从而实现对自旋波的无与伦比的控制 。综述最后强调了这些准周期磁性晶体可能的潜在 应用,探讨了未来探索的潜在途径,并作了简要总结。
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引用次数: 0
Erratum: Stability of the wobbling motion in an odd-mass nucleus and the analysis of Pr135 [Phys. Rev. C 95, 064315 (2017)] 勘误:奇质量原子核摇摆运动的稳定性及对 Pr135 的分析 [Phys. Rev. C 95, 064315 (2017)]
IF 3.1 2区 物理与天体物理 Q1 Physics and Astronomy Pub Date : 2024-07-03 DOI: 10.1103/physrevc.110.019902
Kosai Tanabe, Kazuko Sugawara-Tanabe
DOI:https://doi.org/10.1103/PhysRevC.110.019902
DOI:https://doi.org/10.1103/PhysRevC.110.019902
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引用次数: 0
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