Pub Date : 2024-07-03DOI: 10.1007/s11182-024-03207-z
K. Koteswara Rao, M. C. Rao, Vikas Dubey
The synthesis and the structural and luminescence studies of samarium-doped calcium aluminate phosphors are reported. These phosphors are synthesized by the solid-state reaction method with a variable concentration of doping ions (0.5–3.0 mol%). The synthesized phosphors are characterized by the X-ray diffraction (XRD), scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) techniques. The XRD studies show that the doped phosphors have a cubic structure. The SEM images reveal that the Sm3+- doped Ca3Al2O6 phosphor represents a combination of some rod-like and flower-like structures. The FTIR studies confirm the formation of a Ca3Al2O6:Sm3+ phosphor. The photoluminescence (PL) emission measurements upon excitation by 273 nm (ultraviolet light) show the characteristic emission peaks of Sm3+ at 579, 589, 600 and 619 nm. The characteristic orange-red emission is observed for samarium ion. The excitation spectra of the Ca3Al2O6:Sm3+ phosphor mainly consist of a more intense charge transfer band (CTB) of Sm3+ located at 273 and 395 nm with some peaks centred at 319 and 362 nm. The CIE coordinates are calculated by the spectrophotometric method using the spectral energy distribution of the Ca3Al2O6:Sm3+ sample. The prepared phosphors can act as a single host for orange-red light emission in display devices.
{"title":"Intense Orange Red Emission from Sm3+-Activated Ca3Al2O6 Phosphor for Display Device Application","authors":"K. Koteswara Rao, M. C. Rao, Vikas Dubey","doi":"10.1007/s11182-024-03207-z","DOIUrl":"https://doi.org/10.1007/s11182-024-03207-z","url":null,"abstract":"<p>The synthesis and the structural and luminescence studies of samarium-doped calcium aluminate phosphors are reported. These phosphors are synthesized by the solid-state reaction method with a variable concentration of doping ions (0.5–3.0 mol%). The synthesized phosphors are characterized by the X-ray diffraction (XRD), scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) techniques. The XRD studies show that the doped phosphors have a cubic structure. The SEM images reveal that the Sm<sup>3+</sup>- doped Ca<sub>3</sub>Al<sub>2</sub>O<sub>6</sub> phosphor represents a combination of some rod-like and flower-like structures. The FTIR studies confirm the formation of a Ca<sub>3</sub>Al<sub>2</sub>O<sub>6</sub>:Sm<sup>3+</sup> phosphor. The photoluminescence (PL) emission measurements upon excitation by 273 nm (ultraviolet light) show the characteristic emission peaks of Sm<sup>3+</sup> at 579, 589, 600 and 619 nm. The characteristic orange-red emission is observed for samarium ion. The excitation spectra of the Ca<sub>3</sub>Al<sub>2</sub>O<sub>6</sub>:Sm<sup>3+</sup> phosphor mainly consist of a more intense charge transfer band (CTB) of Sm<sup>3+</sup> located at 273 and 395 nm with some peaks centred at 319 and 362 nm. The CIE coordinates are calculated by the spectrophotometric method using the spectral energy distribution of the Ca<sub>3</sub>Al<sub>2</sub>O<sub>6</sub>:Sm<sup>3+</sup> sample. The prepared phosphors can act as a single host for orange-red light emission in display devices.</p>","PeriodicalId":770,"journal":{"name":"Russian Physics Journal","volume":null,"pages":null},"PeriodicalIF":0.6,"publicationDate":"2024-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141522756","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-03DOI: 10.1103/physreva.110.012204
R. Guy Woolley
The Power-Zienau-Woolley Hamiltonian for the quantum electrodynamics of atoms and molecules is written in terms of purely transverse electromagnetic field variables and so-called polarization fields for the charged particles. It is well known that the attempt at finding solutions to the coupled equations that arise from the Hamiltonian is marred by the occurrence of infinite “self-energies” for both particles and the field. Because of the occurrence of the Dirac function in the nonzero Poisson-brackets/commutation relation for the fields, and in the definition of the polarization fields, these variables, classical and quantum, must be identified as distributions, in the mathematical sense. The Schwartz “impossibility theorem” shows that there is no general multiplication rule for distributions, so one has to find a framework that gives meaning to the Hamiltonian The energy of the electric polarization field is analyzed in the Colombeau algebra and shown to be finite; in particular Coulomb's law () with a finite self-energy () is obtained. How these ideas could be extended to the free-field Hamiltonian is discussed. A finite zero-point energy for the electromagnetic field is to be expected. Relevant mathematical results are summarized in an Appendix.
{"title":"Infinities in molecular quantum electrodynamics and generalized functions","authors":"R. Guy Woolley","doi":"10.1103/physreva.110.012204","DOIUrl":"https://doi.org/10.1103/physreva.110.012204","url":null,"abstract":"The Power-Zienau-Woolley Hamiltonian for the quantum electrodynamics of atoms and molecules is written in terms of purely transverse electromagnetic field variables and so-called polarization fields for the charged particles. It is well known that the attempt at finding solutions to the coupled equations that arise from the Hamiltonian is marred by the occurrence of infinite “self-energies” for both particles and the field. Because of the occurrence of the Dirac <math xmlns=\"http://www.w3.org/1998/Math/MathML\"><mi>δ</mi></math> function in the nonzero Poisson-brackets/commutation relation for the fields, and in the definition of the polarization fields, these variables, classical and quantum, must be identified as distributions, in the mathematical sense. The Schwartz “impossibility theorem” shows that there is no general multiplication rule for distributions, so one has to find a framework that gives meaning to the Hamiltonian The energy of the electric polarization field is analyzed in the Colombeau algebra and shown to be finite; in particular Coulomb's law (<math xmlns=\"http://www.w3.org/1998/Math/MathML\"><mrow><mn>1</mn><mo>/</mo><mi>r</mi><mo>,</mo><mi>r</mi><mo>></mo><mn>0</mn></mrow></math>) with a <i>finite</i> self-energy (<math xmlns=\"http://www.w3.org/1998/Math/MathML\"><mrow><mi>r</mi><mo>=</mo><mn>0</mn></mrow></math>) is obtained. How these ideas could be extended to the free-field Hamiltonian is discussed. A <i>finite</i> zero-point energy for the electromagnetic field is to be expected. Relevant mathematical results are summarized in an Appendix.","PeriodicalId":20146,"journal":{"name":"Physical Review A","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2024-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141514196","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-03DOI: 10.1103/physreva.110.012605
Manuel Guatto, Gian Antonio Susto, Francesco Ticozzi
Obtaining reliable state preparation protocols is a key step toward practical implementation of many quantum technologies, and one of the main tasks in quantum control. In this work, different reinforcement learning approaches are used to derive a feedback law for state preparation of a desired state in a target system. In particular, we focus on the robustness of the obtained strategies with respect to different types and amount of noise. Comparing the results indicates that the learned controls are more robust to unmodeled perturbations with respect to simple feedback strategy based on optimized population transfer, and that training on a simulated nominal model retains the same advantages displayed by controllers trained on real data. The possibility of effective off-line training of robust controllers promises significant advantages toward practical implementation.
{"title":"Improving robustness of quantum feedback control with reinforcement learning","authors":"Manuel Guatto, Gian Antonio Susto, Francesco Ticozzi","doi":"10.1103/physreva.110.012605","DOIUrl":"https://doi.org/10.1103/physreva.110.012605","url":null,"abstract":"Obtaining reliable state preparation protocols is a key step toward practical implementation of many quantum technologies, and one of the main tasks in quantum control. In this work, different reinforcement learning approaches are used to derive a feedback law for state preparation of a desired state in a target system. In particular, we focus on the robustness of the obtained strategies with respect to different types and amount of noise. Comparing the results indicates that the learned controls are more robust to unmodeled perturbations with respect to simple feedback strategy based on optimized population transfer, and that training on a simulated nominal model retains the same advantages displayed by controllers trained on real data. The possibility of effective off-line training of robust controllers promises significant advantages toward practical implementation.","PeriodicalId":20146,"journal":{"name":"Physical Review A","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2024-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141514198","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-03DOI: 10.1103/physrevc.110.019903
Z. Q. Li (李志泉), S. Y. Wang (王守宇), L. Liu (刘雷), Y. M. Zhang (张亚梅), B. Qi (亓斌), S. Wang (王硕), D. P. Sun (孙大鹏), C. Liu (刘晨), P. Zhang (张盼), N. B. Zhang (张乃波), H. Jia (贾慧), Q. Hu (胡琪), C. Y. Niu (牛阳), Z. Q. Chen (陈志强), P. Lv (吕品), C. Y. Li (李传洋), X. G. Wu (吴晓光), G. S. Li (李广生), C. Y. He (贺创业), Y. Zheng (郑云), C. B. Li (李聪博), H. W. Li (李红伟), P. W. Luo (罗朋威)
DOI:https://doi.org/10.1103/PhysRevC.110.019903
DOI:https://doi.org/10.1103/PhysRevC.110.019903
{"title":"Erratum: High-spin states of the semimagic nucleus Pr141 [Phys. Rev. C 91, 064319 (2015)]","authors":"Z. Q. Li (李志泉), S. Y. Wang (王守宇), L. Liu (刘雷), Y. M. Zhang (张亚梅), B. Qi (亓斌), S. Wang (王硕), D. P. Sun (孙大鹏), C. Liu (刘晨), P. Zhang (张盼), N. B. Zhang (张乃波), H. Jia (贾慧), Q. Hu (胡琪), C. Y. Niu (牛阳), Z. Q. Chen (陈志强), P. Lv (吕品), C. Y. Li (李传洋), X. G. Wu (吴晓光), G. S. Li (李广生), C. Y. He (贺创业), Y. Zheng (郑云), C. B. Li (李聪博), H. W. Li (李红伟), P. W. Luo (罗朋威)","doi":"10.1103/physrevc.110.019903","DOIUrl":"https://doi.org/10.1103/physrevc.110.019903","url":null,"abstract":"<span>DOI:</span><span>https://doi.org/10.1103/PhysRevC.110.019903</span>","PeriodicalId":20122,"journal":{"name":"Physical Review C","volume":null,"pages":null},"PeriodicalIF":3.1,"publicationDate":"2024-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141504606","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-03DOI: 10.1007/s11182-024-03194-1
M. B. Sedelnikova, A. D. Kashin, P. V. Uvarkin, Y. P. Sharkeev, A. V. Ugodchikova, N. A. Luginin, M. A. Khimich, K. V. Ivanov
The paper presents the comprehensive analysis of the structure, properties, and corrosion of micro-arc coatings with ZrO2 and TiO2 particles after the low-energy high-current electron beam (LEHCEB) treatment. The coating morphology, microstructure, phase and elemental compositions are investigated by the scanning electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray powder diffraction. After the LEHCEB treatment, the coating structure with ZrO2 particles changes from friable and porous to denser with closed spheroidal pores. It is shown that the adhesive strength of the coating with ZrO2 particles increases with the critical load growth from 10 to 18 N. Moreover, the treatment enhances its corrosion resistance, as evidenced by a reduction in the corrosion current from 7.48∙10–7 to 1.05∙10–8 A/cm2 and an increase in polarization resistance from 0.9·104 to 5.77∙106 Ω·cm2. In contrast, the coatings with TiO2 particles exhibit a more porous structure due to the volatilization of low-melting components (sodium silicates), as evidenced by a reduction in the concentration of Na and Si elements in their composition. The adhesive strength and corrosion resistance of the coatings with TiO2 particles deteriorate after the treatment.
本文全面分析了经低能大电流电子束(LEHCEB)处理后的 ZrO2 和 TiO2 粒子微弧涂层的结构、性能和腐蚀情况。通过扫描电子显微镜、能量色散 X 射线光谱和 X 射线粉末衍射研究了涂层的形貌、微观结构、相和元素组成。经 LEHCEB 处理后,含有 ZrO2 颗粒的涂层结构从易碎多孔变为致密封闭的球形孔。此外,该处理还增强了涂层的耐腐蚀性,具体表现为腐蚀电流从 7.48∙10-7 降低到 1.05∙10-8 A/cm2,极化电阻从 0.9-104 增加到 5.77∙106 Ω-cm2。相比之下,由于低熔点成分(硅酸钠)的挥发,含有 TiO2 颗粒的涂层显示出更多孔的结构,这从其成分中 Na 和 Si 元素浓度的降低可以看出。经过处理后,带有 TiO2 颗粒的涂层的粘合强度和耐腐蚀性能都有所下降。
{"title":"Structure and Properties of Composite Coatings with Zro2 and Tio2 Particles After Lehceb Treatment","authors":"M. B. Sedelnikova, A. D. Kashin, P. V. Uvarkin, Y. P. Sharkeev, A. V. Ugodchikova, N. A. Luginin, M. A. Khimich, K. V. Ivanov","doi":"10.1007/s11182-024-03194-1","DOIUrl":"https://doi.org/10.1007/s11182-024-03194-1","url":null,"abstract":"<p>The paper presents the comprehensive analysis of the structure, properties, and corrosion of micro-arc coatings with ZrO<sub>2</sub> and TiO<sub>2</sub> particles after the low-energy high-current electron beam (LEHCEB) treatment. The coating morphology, microstructure, phase and elemental compositions are investigated by the scanning electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray powder diffraction. After the LEHCEB treatment, the coating structure with ZrO<sub>2</sub> particles changes from friable and porous to denser with closed spheroidal pores. It is shown that the adhesive strength of the coating with ZrO<sub>2</sub> particles increases with the critical load growth from 10 to 18 N. Moreover, the treatment enhances its corrosion resistance, as evidenced by a reduction in the corrosion current from 7.48∙10<sup>–7</sup> to 1.05∙10<sup>–8</sup> A/cm<sup>2</sup> and an increase in polarization resistance from 0.9·10<sup>4</sup> to 5.77∙10<sup>6</sup> Ω·cm<sup>2</sup>. In contrast, the coatings with TiO<sub>2</sub> particles exhibit a more porous structure due to the volatilization of low-melting components (sodium silicates), as evidenced by a reduction in the concentration of Na and Si elements in their composition. The adhesive strength and corrosion resistance of the coatings with TiO<sub>2</sub> particles deteriorate after the treatment.</p>","PeriodicalId":770,"journal":{"name":"Russian Physics Journal","volume":null,"pages":null},"PeriodicalIF":0.6,"publicationDate":"2024-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141522749","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-03DOI: 10.1088/1475-7516/2024/07/009
X.P. Geng, L.T. Yang, Q. Yue, K.J. Kang, Y.J. Li, H.P. An, Greeshma C, J.P. Chang, Y.H. Chen, J.P. Cheng, W.H. Dai, Z. Deng, C.H. Fang, H. Gong, Q.J. Guo, T. Guo, X.Y. Guo, L. He, S.M. He, J.W. Hu, H.X. Huang, T.C. Huang, L. Jiang, S. Karmakar, H.B. Li, H.Y. Li, J.M. Li, J. Li, Q.Y. Li, R.M.J. Li, X.Q. Li, Y.L. Li, Y.F. Liang, B. Liao, F.K. Lin, S.T. Lin, J.X. Liu, S.K. Liu, Y.D. Liu, Y. Liu, Y.Y. Liu, H. Ma, Y.C. Mao, Q.Y. Nie, J.H. Ning, H. Pan, N.C. Qi, J. Ren, X.C. Ruan, M.K. Singh, T.X. Sun, C.J. Tang, Y. Tian, G.F. Wang, J.Z. Wang, L. Wang, Q. Wang, Y.F. Wang, Y.X. Wang, H.T. Wong, S.Y. Wu, Y.C. Wu, H.Y. Xing, R. Xu, Y. Xu, T. Xue, Y.L. Yan, N. Yi, C.X. Yu, H.J. Yu, J.F. Yue, M. Zeng, Z. Zeng, B.T. Zhang, F.S. Zhang, L. Zhang, Z.H. Zhang, Z.Y. Zhang, J.Z. Zhao, K.K. Zhao, M.G. Zhao, J.F. Zhou, Z.Y. Zhou, J.J. Zhu and The CDEX collaboration
CDEX-50 is a next-generation project of the China Dark Matter Experiment (CDEX) that aims to search for dark matter using a 50-kg germanium detector array. This paper comprises a thorough summary of the CDEX-50 dark matter experiment, including an investigation of potential background sources and the development of a background model. Based on the baseline model, the projected sensitivity of weakly interacting massive particle (WIMP) is also presented. The expected background level within the energy region of interest, set to 2–2.5 keVee, is ∼0.01 counts keVee-1 kg-1 day-1. At 90% confidence level, the expected sensitivity to spin-independent WIMP-nucleon couplings is estimated to reach a cross-section of 5.1 × 10-45 cm2 for a WIMP mass of 5 GeV/c2 with an exposure objective of 150 kg·year and an analysis threshold of 160 eVee. This science goal will correspond to the most sensitive results for WIMPs with a mass of 2.2–8 GeV/c2.
{"title":"Projected WIMP sensitivity of the CDEX-50 dark matter experiment","authors":"X.P. Geng, L.T. Yang, Q. Yue, K.J. Kang, Y.J. Li, H.P. An, Greeshma C, J.P. Chang, Y.H. Chen, J.P. Cheng, W.H. Dai, Z. Deng, C.H. Fang, H. Gong, Q.J. Guo, T. Guo, X.Y. Guo, L. He, S.M. He, J.W. Hu, H.X. Huang, T.C. Huang, L. Jiang, S. Karmakar, H.B. Li, H.Y. Li, J.M. Li, J. Li, Q.Y. Li, R.M.J. Li, X.Q. Li, Y.L. Li, Y.F. Liang, B. Liao, F.K. Lin, S.T. Lin, J.X. Liu, S.K. Liu, Y.D. Liu, Y. Liu, Y.Y. Liu, H. Ma, Y.C. Mao, Q.Y. Nie, J.H. Ning, H. Pan, N.C. Qi, J. Ren, X.C. Ruan, M.K. Singh, T.X. Sun, C.J. Tang, Y. Tian, G.F. Wang, J.Z. Wang, L. Wang, Q. Wang, Y.F. Wang, Y.X. Wang, H.T. Wong, S.Y. Wu, Y.C. Wu, H.Y. Xing, R. Xu, Y. Xu, T. Xue, Y.L. Yan, N. Yi, C.X. Yu, H.J. Yu, J.F. Yue, M. Zeng, Z. Zeng, B.T. Zhang, F.S. Zhang, L. Zhang, Z.H. Zhang, Z.Y. Zhang, J.Z. Zhao, K.K. Zhao, M.G. Zhao, J.F. Zhou, Z.Y. Zhou, J.J. Zhu and The CDEX collaboration","doi":"10.1088/1475-7516/2024/07/009","DOIUrl":"https://doi.org/10.1088/1475-7516/2024/07/009","url":null,"abstract":"CDEX-50 is a next-generation project of the China Dark Matter Experiment (CDEX) that aims to search for dark matter using a 50-kg germanium detector array. This paper comprises a thorough summary of the CDEX-50 dark matter experiment, including an investigation of potential background sources and the development of a background model. Based on the baseline model, the projected sensitivity of weakly interacting massive particle (WIMP) is also presented. The expected background level within the energy region of interest, set to 2–2.5 keVee, is ∼0.01 counts keVee-1 kg-1 day-1. At 90% confidence level, the expected sensitivity to spin-independent WIMP-nucleon couplings is estimated to reach a cross-section of 5.1 × 10-45 cm2 for a WIMP mass of 5 GeV/c2 with an exposure objective of 150 kg·year and an analysis threshold of 160 eVee. This science goal will correspond to the most sensitive results for WIMPs with a mass of 2.2–8 GeV/c2.","PeriodicalId":15445,"journal":{"name":"Journal of Cosmology and Astroparticle Physics","volume":null,"pages":null},"PeriodicalIF":6.4,"publicationDate":"2024-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141521334","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The electrical transport property of layered MoSe2 has a strong response to high pressure by enhancing the inter-layer interaction. However, the narrowed bandgap under high pressure will cause the bipolar effect (i.e., the thermally excited minority carriers contribute to a Seebeck coefficient with the opposite sign to the majority carriers) at high temperatures to degrade the thermoelectric (TE) performance. Hence, suppressing the bipolar effect is important to optimize the TE performance of MoSe2 under high pressure and high temperature (HPHT). In this study, the degradation of TE performance caused by the bipolar effect under HPHT in MoSe2 is investigated. It is found that in MoSe2, the electrical conductivity was improved significantly by pressure; however, the bipolar effect led to a significantly degraded Seebeck coefficient at high temperatures. By injecting massive carriers beforehand, the bipolar effect was suppressed to make a dominant type of p-type charge carries, achieving an increased Seebeck coefficient with increasing temperature, resulting in an improved power factor from 29.3 μW m−1 K−2 in MoSe2 to 285.7 μW m−1 K−2 in Mo0.98Nb0.02Se2 at 5.5 GPa, 1110 K. Combined with the reduced thermal conductivity by point defect scattering on phonons, a maximum ZT value of 0.11 at 5.5 GPa, 1110 K. This work highlights the significance of suppressing the bipolar effect under HPHT for optimizing TE performance in such layered semiconductors.
通过增强层间相互作用,层状 MoSe2 的电气传输特性对高压有很强的响应。然而,高压下带隙变窄会导致高温下的双极效应(即热激发的少数载流子产生与多数载流子符号相反的塞贝克系数),从而降低热电(TE)性能。因此,抑制双极效应对于优化 MoSe2 在高压高温(HPHT)条件下的 TE 性能非常重要。本研究探讨了双极效应导致 MoSe2 在高压高温下 TE 性能下降的问题。研究发现,MoSe2 的电导率在压力作用下得到了显著改善;然而,双极效应导致其在高温下的塞贝克系数明显降低。通过事先注入大量载流子,双极效应被抑制,从而使 p 型电荷载流子占主导地位,实现了塞贝克系数随温度升高而增大,使功率因数从 MoSe2 的 29.3 μW m-1 K-2 提高到 Mo0.02Se2 的 285.7 μW m-1 K-2。在 5.5 GPa、1110 K 条件下,功率因数从 MoSe2 中的 29.3 μW m-1 K-2 提高到 Mo0.98Nb0.02Se2 中的 285.7 μW m-1 K-2;再加上点缺陷对声子的散射降低了热导率,在 5.5 GPa、1110 K 条件下,ZT 值达到最大值 0.11。
{"title":"Enhanced thermoelectric performance of MoSe2 under high pressure and high temperature by suppressing bipolar effect","authors":"Dianzhen Wang, Cun You, Yufei Ge, Fei Wang, Xinglin Wang, Xiao Liang, Qiang Zhou, Qiang Tao, Yanli Chen, Pinwen Zhu","doi":"10.1063/5.0217965","DOIUrl":"https://doi.org/10.1063/5.0217965","url":null,"abstract":"The electrical transport property of layered MoSe2 has a strong response to high pressure by enhancing the inter-layer interaction. However, the narrowed bandgap under high pressure will cause the bipolar effect (i.e., the thermally excited minority carriers contribute to a Seebeck coefficient with the opposite sign to the majority carriers) at high temperatures to degrade the thermoelectric (TE) performance. Hence, suppressing the bipolar effect is important to optimize the TE performance of MoSe2 under high pressure and high temperature (HPHT). In this study, the degradation of TE performance caused by the bipolar effect under HPHT in MoSe2 is investigated. It is found that in MoSe2, the electrical conductivity was improved significantly by pressure; however, the bipolar effect led to a significantly degraded Seebeck coefficient at high temperatures. By injecting massive carriers beforehand, the bipolar effect was suppressed to make a dominant type of p-type charge carries, achieving an increased Seebeck coefficient with increasing temperature, resulting in an improved power factor from 29.3 μW m−1 K−2 in MoSe2 to 285.7 μW m−1 K−2 in Mo0.98Nb0.02Se2 at 5.5 GPa, 1110 K. Combined with the reduced thermal conductivity by point defect scattering on phonons, a maximum ZT value of 0.11 at 5.5 GPa, 1110 K. This work highlights the significance of suppressing the bipolar effect under HPHT for optimizing TE performance in such layered semiconductors.","PeriodicalId":8094,"journal":{"name":"Applied Physics Letters","volume":null,"pages":null},"PeriodicalIF":4.0,"publicationDate":"2024-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141521521","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. Weis, M. Lejman, J. Faure, V. Ta Phuoc, L. Cario, D. Boschetto
In this Letter, we investigate coherent phonon dynamics in the incommensurate LaVS3 crystal by femtosecond pump-probe spectroscopy. Two coherent phonon modes are systematically observed in the transient reflectivity, centered at 1.8 and 2.85 THz, respectively, while a third mode centered at 4.5 THz is observed only at high pump fluence. The experimental results obtained at two different polarization configurations as well as a comparison with recent theoretical results allow to assign the two main modes to the interlayer shearing mode and to an intralayer mode, respectively. Two possible assignments are discussed for the third mode, by invoking a possible emergence of nonlinear phonon processes.
{"title":"Coherent phonons in incommensurate LaVS3 crystal","authors":"M. Weis, M. Lejman, J. Faure, V. Ta Phuoc, L. Cario, D. Boschetto","doi":"10.1063/5.0211057","DOIUrl":"https://doi.org/10.1063/5.0211057","url":null,"abstract":"In this Letter, we investigate coherent phonon dynamics in the incommensurate LaVS3 crystal by femtosecond pump-probe spectroscopy. Two coherent phonon modes are systematically observed in the transient reflectivity, centered at 1.8 and 2.85 THz, respectively, while a third mode centered at 4.5 THz is observed only at high pump fluence. The experimental results obtained at two different polarization configurations as well as a comparison with recent theoretical results allow to assign the two main modes to the interlayer shearing mode and to an intralayer mode, respectively. Two possible assignments are discussed for the third mode, by invoking a possible emergence of nonlinear phonon processes.","PeriodicalId":8094,"journal":{"name":"Applied Physics Letters","volume":null,"pages":null},"PeriodicalIF":4.0,"publicationDate":"2024-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141521941","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-03DOI: 10.1088/1361-648X/ad5ee8
R Mehta, Bivas Rana, Susmita Saha
Quasiperiodic magnonic crystals, in contrast to their periodic counterparts,
lack strict periodicity which gives rise to complex and localised spin wave spectra
characterized by numerous band gaps and fractal features. Despite their intrinsic
structural complexity, quasiperiodic nature of these magnonic crystals enables better
tunability of spin wave spectra over their periodic counterparts and therefore holds
promise for the applications in reprogrammable magnonic devices. In this article, we
provide an overview of magnetization reversal and precessional magnetization dynamics
studied so far in various quasiperiodic magnonic crystals, illustrating how their
quasiperiodic nature gives rise to tailored band structure, enabling unparalleled control
over spin waves. The review is concluded by highlighting the possible potential
applications of these quasiperiodic magnonic crystals, exploring potential avenues for
future exploration followed by a brief summary.
{"title":"Magnetization Dynamics in Quasiperiodic Magnonic Crystals.","authors":"R Mehta, Bivas Rana, Susmita Saha","doi":"10.1088/1361-648X/ad5ee8","DOIUrl":"https://doi.org/10.1088/1361-648X/ad5ee8","url":null,"abstract":"<p><p>Quasiperiodic magnonic crystals, in contrast to their periodic counterparts,
lack strict periodicity which gives rise to complex and localised spin wave spectra
characterized by numerous band gaps and fractal features. Despite their intrinsic
structural complexity, quasiperiodic nature of these magnonic crystals enables better
tunability of spin wave spectra over their periodic counterparts and therefore holds
promise for the applications in reprogrammable magnonic devices. In this article, we
provide an overview of magnetization reversal and precessional magnetization dynamics
studied so far in various quasiperiodic magnonic crystals, illustrating how their
quasiperiodic nature gives rise to tailored band structure, enabling unparalleled control
over spin waves. The review is concluded by highlighting the possible potential
applications of these quasiperiodic magnonic crystals, exploring potential avenues for
future exploration followed by a brief summary.</p>","PeriodicalId":16776,"journal":{"name":"Journal of Physics: Condensed Matter","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2024-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141498316","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-03DOI: 10.1103/physrevc.110.019902
Kosai Tanabe, Kazuko Sugawara-Tanabe
DOI:https://doi.org/10.1103/PhysRevC.110.019902
DOI:https://doi.org/10.1103/PhysRevC.110.019902
{"title":"Erratum: Stability of the wobbling motion in an odd-mass nucleus and the analysis of Pr135 [Phys. Rev. C 95, 064315 (2017)]","authors":"Kosai Tanabe, Kazuko Sugawara-Tanabe","doi":"10.1103/physrevc.110.019902","DOIUrl":"https://doi.org/10.1103/physrevc.110.019902","url":null,"abstract":"<span>DOI:</span><span>https://doi.org/10.1103/PhysRevC.110.019902</span>","PeriodicalId":20122,"journal":{"name":"Physical Review C","volume":null,"pages":null},"PeriodicalIF":3.1,"publicationDate":"2024-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141504604","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}