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Energy production and denitrogenation performance by sludge biochar based constructed wetlands-microbial fuel cells system: Overcoming carbon constraints in water
IF 12.8 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-12-21 DOI: 10.1016/j.watres.2024.123024
Boda Ouyang, Zhiyong Zhang, Fuzhi Chen, Fei Li, Ming-Lai Fu, Huachun Lan, Baoling Yuan
As freshwater demand grows globally, using reclaimed water in natural water bodies has become essential. Constructed wetlands (CWs) are widely used for advanced wastewater treatment due to their environmental benefits. However, low carbon/nitrogen (C/N) ratios in wastewater limit nitrogen removal, often leading to eutrophication. This study explores the use of sewage sludge biochar (SB) and activated carbon (AC) as electrodes in microbial fuel cell-constructed wetlands (MFC-CW) to enhance nitrogen removal and energy generation. Results indicated that the sludge biochar closed-circuit CW (MSBS-CW) achieved considerable total nitrogen removal (95.85%) and maximum power density (9.05 mW/m²). Furthermore, high-throughput sequencing and functional gene analysis revealed substantial shifts in the microbial community within MSBS-CW, particularly in the electroactive bacteria (Geobacter), autotrophic denitrifying bacterium (Hydrogenophaga, Thiobacillus) and anaerobic ammonium oxidation bacteria (Candidatus_Brocadia). Electrochemical and material characterization showed that SB enhanced the cathode's electrochemical performance and the anode's biocompatibility, thereby improving denitrification and energy generation. This study demonstrates that sludge biochar is an effective low-cost electrode material for MFC-CW systems, offering a sustainable solution for nitrogen removal and energy production under carbon-constrained conditions.
{"title":"Energy production and denitrogenation performance by sludge biochar based constructed wetlands-microbial fuel cells system: Overcoming carbon constraints in water","authors":"Boda Ouyang, Zhiyong Zhang, Fuzhi Chen, Fei Li, Ming-Lai Fu, Huachun Lan, Baoling Yuan","doi":"10.1016/j.watres.2024.123024","DOIUrl":"https://doi.org/10.1016/j.watres.2024.123024","url":null,"abstract":"As freshwater demand grows globally, using reclaimed water in natural water bodies has become essential. Constructed wetlands (CWs) are widely used for advanced wastewater treatment due to their environmental benefits. However, low carbon/nitrogen (C/N) ratios in wastewater limit nitrogen removal, often leading to eutrophication. This study explores the use of sewage sludge biochar (SB) and activated carbon (AC) as electrodes in microbial fuel cell-constructed wetlands (MFC-CW) to enhance nitrogen removal and energy generation. Results indicated that the sludge biochar closed-circuit CW (MSBS-CW) achieved considerable total nitrogen removal (95.85%) and maximum power density (9.05 mW/m²). Furthermore, high-throughput sequencing and functional gene analysis revealed substantial shifts in the microbial community within MSBS-CW, particularly in the electroactive bacteria (<em>Geobacter</em>), autotrophic denitrifying bacterium (<em>Hydrogenophaga, Thiobacillus</em>) and anaerobic ammonium oxidation bacteria (<em>Candidatus_Brocadia</em>). Electrochemical and material characterization showed that SB enhanced the cathode's electrochemical performance and the anode's biocompatibility, thereby improving denitrification and energy generation. This study demonstrates that sludge biochar is an effective low-cost electrode material for MFC-CW systems, offering a sustainable solution for nitrogen removal and energy production under carbon-constrained conditions.","PeriodicalId":443,"journal":{"name":"Water Research","volume":"27 1","pages":""},"PeriodicalIF":12.8,"publicationDate":"2024-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142867371","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Artisanal and small-scale limestone mining affects soil parameters in Sohra (Meghalaya), India
IF 2.9 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2024-12-21 DOI: 10.1007/s10661-024-13573-3
R. Eugene Lamare, O. P. Singh

In this study, we assessed the changes in the physical and chemical characteristics of the soil samples collected from the artisanal and small-scale limestone mining site in Sohra (Cherrapunjee), Meghalaya, by comparing them with the non-mining site. Eleven distinct soil parameters, namely pH, electrical conductivity (EC), texture (ST), moisture content (MC), bulk density (BD), total porosity (TP), water holding capacity (WHC), organic carbon (OC), total nitrogen (TN), available phosphorus (AP), and exchangeable potassium (EK), were evaluated seasonally (winter, pre-monsoon, and post-monsoon) for 2 years. The results showed that limestone mining has significantly affected the soil quality. The effect is evident by the substantial increases in EC values, sand content, and alkaline soils coupled with noticeably low concentrations of OC and TN. In addition, prominent changes were perceived in the soil MC and EK content, as well as in WHC, BD, and TP percent. Results from ANOVA revealed significant differences (p < 0.05) in mean values at different sampling seasons and sites. The multivariate statistical analysis results showed that the computed correlation coefficient (r) matrix data ranged from − 1.00 to 0.974. A strong positive correlation was highest between OC and TN (0.974), followed by OC with EK (0.828). Principal component (PC) analysis revealed two major components, PC 1 and PC 2, having eigenvalues of 6.276 and 1.747, respectively. Cumulatively, these two components explained 80.23% of the total variance. The loading factor in PC 1 is high and is attributed to OC (.974), TN (.970), and EK (.903). However, in PC 2, the loading factor is positively pooled by MC (0.894) and TP (0.765). The present study concludes that artisanal and small-scale limestone mining altered the soil’s physical and chemical properties, and these changes are likely to have a subsequent deteriorating impact on the area’s biodiversity, landscape, and natural ecosystem. Therefore, to minimize the impact and ensure sustainable soil management in the area, approaches for effective mitigation and remediation measures, including formulating steps for the conservation and enhancement of the soil’s environmental quality, are recommended.

{"title":"Artisanal and small-scale limestone mining affects soil parameters in Sohra (Meghalaya), India","authors":"R. Eugene Lamare,&nbsp;O. P. Singh","doi":"10.1007/s10661-024-13573-3","DOIUrl":"10.1007/s10661-024-13573-3","url":null,"abstract":"<div><p>In this study, we assessed the changes in the physical and chemical characteristics of the soil samples collected from the artisanal and small-scale limestone mining site in Sohra (Cherrapunjee), Meghalaya, by comparing them with the non-mining site. Eleven distinct soil parameters, namely pH, electrical conductivity (EC), texture (ST), moisture content (MC), bulk density (BD), total porosity (TP), water holding capacity (WHC), organic carbon (OC), total nitrogen (TN), available phosphorus (AP), and exchangeable potassium (EK), were evaluated seasonally (winter, pre-monsoon, and post-monsoon) for 2 years. The results showed that limestone mining has significantly affected the soil quality. The effect is evident by the substantial increases in EC values, sand content, and alkaline soils coupled with noticeably low concentrations of OC and TN. In addition, prominent changes were perceived in the soil MC and EK content, as well as in WHC, BD, and TP percent. Results from ANOVA revealed significant differences (<i>p</i> &lt; 0.05) in mean values at different sampling seasons and sites. The multivariate statistical analysis results showed that the computed correlation coefficient (<i>r</i>) matrix data ranged from − 1.00 to 0.974. A strong positive correlation was highest between OC and TN (0.974), followed by OC with EK (0.828). Principal component (PC) analysis revealed two major components, PC 1 and PC 2, having eigenvalues of 6.276 and 1.747, respectively. Cumulatively, these two components explained 80.23% of the total variance. The loading factor in PC 1 is high and is attributed to OC (.974), TN (.970), and EK (.903). However, in PC 2, the loading factor is positively pooled by MC (0.894) and TP (0.765). The present study concludes that artisanal and small-scale limestone mining altered the soil’s physical and chemical properties, and these changes are likely to have a subsequent deteriorating impact on the area’s biodiversity, landscape, and natural ecosystem. Therefore, to minimize the impact and ensure sustainable soil management in the area, approaches for effective mitigation and remediation measures, including formulating steps for the conservation and enhancement of the soil’s environmental quality, are recommended.</p></div>","PeriodicalId":544,"journal":{"name":"Environmental Monitoring and Assessment","volume":"197 1","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142859666","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A decade of declines in toothed whale densities following the Deepwater Horizon oil spill
IF 8.1 1区 地球科学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2024-12-21 DOI: 10.1038/s43247-024-01920-8
Kaitlin E. Frasier, Macey A. Kadifa, Alba Solsona Berga, John A. Hildebrand, Sean M. Wiggins, Lance P. Garrison, Héloïse Frouin-Mouy, Adolfo Gracia, Arturo Serrano, Lynne E. W. Hodge, Carrie C. Wall, Matthieu Le Hénaff, Melissa S. Soldevilla
Shortly after the Deepwater Horizon oil spill began in April 2010, a widely spaced passive acoustic monitoring array was deployed in the northeastern Gulf of Mexico to document the impacts of this unprecedentedly large and deep offshore oil spill on oceanic marine mammals. The array was subsequently maintained for over a decade. Here we document decadal density declines for seven of eight monitored species groups, including sperm whales (up to 31%), beaked whales (up to 83%), and small delphinids (up to 43%). Declines were observed both within and outside of the surface oil footprint. Though not conclusively linked to the oil spill, the broad spatial and temporal scale of these declines observed for disparate marine mammal species is consistent with Deepwater Horizon impacts. These declines have exceeded and outlasted post-spill damage assessment predictions, suggesting that the offshore ecosystem impacts of Deepwater Horizon may have been larger than previously thought. Whale and delphinid numbers in the Gulf of Mexico have declined by up to 83% in the ten years following the Deepwater Horizon oil spill, according to analysis of passive acoustic monitoring data.
{"title":"A decade of declines in toothed whale densities following the Deepwater Horizon oil spill","authors":"Kaitlin E. Frasier,&nbsp;Macey A. Kadifa,&nbsp;Alba Solsona Berga,&nbsp;John A. Hildebrand,&nbsp;Sean M. Wiggins,&nbsp;Lance P. Garrison,&nbsp;Héloïse Frouin-Mouy,&nbsp;Adolfo Gracia,&nbsp;Arturo Serrano,&nbsp;Lynne E. W. Hodge,&nbsp;Carrie C. Wall,&nbsp;Matthieu Le Hénaff,&nbsp;Melissa S. Soldevilla","doi":"10.1038/s43247-024-01920-8","DOIUrl":"10.1038/s43247-024-01920-8","url":null,"abstract":"Shortly after the Deepwater Horizon oil spill began in April 2010, a widely spaced passive acoustic monitoring array was deployed in the northeastern Gulf of Mexico to document the impacts of this unprecedentedly large and deep offshore oil spill on oceanic marine mammals. The array was subsequently maintained for over a decade. Here we document decadal density declines for seven of eight monitored species groups, including sperm whales (up to 31%), beaked whales (up to 83%), and small delphinids (up to 43%). Declines were observed both within and outside of the surface oil footprint. Though not conclusively linked to the oil spill, the broad spatial and temporal scale of these declines observed for disparate marine mammal species is consistent with Deepwater Horizon impacts. These declines have exceeded and outlasted post-spill damage assessment predictions, suggesting that the offshore ecosystem impacts of Deepwater Horizon may have been larger than previously thought. Whale and delphinid numbers in the Gulf of Mexico have declined by up to 83% in the ten years following the Deepwater Horizon oil spill, according to analysis of passive acoustic monitoring data.","PeriodicalId":10530,"journal":{"name":"Communications Earth & Environment","volume":" ","pages":"1-11"},"PeriodicalIF":8.1,"publicationDate":"2024-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s43247-024-01920-8.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142862475","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Assessing the accuracy of various statistical models for forecasting PM(_{2.5}): a case study from diverse regions of Gandhinagar and Ahmedabad
IF 2.9 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2024-12-21 DOI: 10.1007/s10661-024-13550-w
Sajeed I. Ghanchi, Dishant M. Pandya, Manan Shah

PM(_{2.5}) is the most hazardous air pollutant due to its smaller size, which allows deeper bodily penetration. Three diverse regions from Gujarat, India, namely Sector 10, Maninagar, and Vatva, which have green space, high population concentration, and industries, respectively, were chosen to forecast PM(_{2.5}) concentration for the next day. Four statistical models, including Multiple Linear Regression (MLR), Principal Component Regression (PCR), Simple Exponential Smoothing (SES), and Autoregressive Integrated Moving Average (ARIMA), were chosen to forecast PM(_{2.5}) levels. For this study, data of various pollutants and meteorological parameters were collected from February 2019 to September 2023. Analysis of the seasonal patterns of PM(_{2.5}) revealed elevated concentrations during post-monsoon and winter, in contrast to reduced levels during summer and monsoon. Statistical analysis revealed that the concentration of PM(_{2.5}) in Sector 10 is much lower than in the other two regions. The analysis of the test results, utilising various accuracy measures like RMSE, MAE, MAPE, IA, and others, indicated that Sector 10 achieved the highest precision in its results. While assessing the models’ accuracy on the test data, the ARIMA model demonstrated the highest level of precision. The average RMSE, MAE, and MAPE values for the ARIMA model were 12.63, 8.59, and 0.24, respectively. In the comparison of the performance between these statistical models and the neural network-based Multilayer Perceptron (MLP) model, it was observed that the statistical model demonstrated superior performance over the MLP model.

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引用次数: 0
Predicting the Effects of Ozone on Long‐Term Growth of Aspen Trees Using Response Functions Developed From Seedlings Grown in Field Chambers
IF 11.6 1区 环境科学与生态学 Q1 BIODIVERSITY CONSERVATION Pub Date : 2024-12-21 DOI: 10.1111/gcb.70003
Jeffrey D. Herrick, S. Douglas Kaylor, Jean‐Jacques B. Dubois
Tropospheric ozone (O3) is among the most pervasive and harmful air pollutants known to affect ecosystems. In the United States, the Environmental Protection Agency and other agencies are tasked with protecting plants and ecosystems from harmful O3 exposures. Controlled exposure experiments conducted in field open‐top chambers (OTCs) with small tree seedlings have been used to estimate empirical models of tree growth in response to O3 exposure for more than 16 species. While this experimental method makes it possible to obtain detailed exposure‐response data, it remains uncertain whether predictions of empirical models parameterized using those data are sufficiently accurate when applied to trees grown in uncontrolled natural environments for long periods. We used O3 exposure‐response relationships developed from several OTC studies of trembling aspen (Populus tremuloides Michx.) seedlings to predict the growth of the same species in the Aspen FACE “free‐air” O3 exposure experiment in Rhinelander, Wisconsin, over 11 years. We acquired individual tree growth data and hourly O3 exposure from the ambient and elevated O3 plots in the Aspen FACE experiment, computed annual exposure using the same metrics of O3 exposure as were used in the OTC seedling experiments, and generated predictions of growth in the Aspen FACE exposures. A simple empirical model parameterized using the OTC seedling data accurately predicted the percent above‐ground biomass loss due to O3 exposure in the Aspen FACE trees for all 11 years. In the Aspen FACE experiment, the effect of O3 exposure was established in early years and continued to be observed in later years without worsening. Our study suggests that O3 exposure‐response relationships obtained from OTC seedling studies can be used to make inferences about effects on larger trees. These results imply that researchers can use these relationships with confidence when estimating risks of O3 pollution across the United States.
{"title":"Predicting the Effects of Ozone on Long‐Term Growth of Aspen Trees Using Response Functions Developed From Seedlings Grown in Field Chambers","authors":"Jeffrey D. Herrick, S. Douglas Kaylor, Jean‐Jacques B. Dubois","doi":"10.1111/gcb.70003","DOIUrl":"https://doi.org/10.1111/gcb.70003","url":null,"abstract":"Tropospheric ozone (O<jats:sub>3</jats:sub>) is among the most pervasive and harmful air pollutants known to affect ecosystems. In the United States, the Environmental Protection Agency and other agencies are tasked with protecting plants and ecosystems from harmful O<jats:sub>3</jats:sub> exposures. Controlled exposure experiments conducted in field open‐top chambers (OTCs) with small tree seedlings have been used to estimate empirical models of tree growth in response to O<jats:sub>3</jats:sub> exposure for more than 16 species. While this experimental method makes it possible to obtain detailed exposure‐response data, it remains uncertain whether predictions of empirical models parameterized using those data are sufficiently accurate when applied to trees grown in uncontrolled natural environments for long periods. We used O<jats:sub>3</jats:sub> exposure‐response relationships developed from several OTC studies of trembling aspen (<jats:styled-content style=\"fixed-case\"><jats:italic>Populus tremuloides</jats:italic></jats:styled-content> Michx.) seedlings to predict the growth of the same species in the Aspen FACE “free‐air” O<jats:sub>3</jats:sub> exposure experiment in Rhinelander, Wisconsin, over 11 years. We acquired individual tree growth data and hourly O<jats:sub>3</jats:sub> exposure from the ambient and elevated O<jats:sub>3</jats:sub> plots in the Aspen FACE experiment, computed annual exposure using the same metrics of O<jats:sub>3</jats:sub> exposure as were used in the OTC seedling experiments, and generated predictions of growth in the Aspen FACE exposures. A simple empirical model parameterized using the OTC seedling data accurately predicted the percent above‐ground biomass loss due to O<jats:sub>3</jats:sub> exposure in the Aspen FACE trees for all 11 years. In the Aspen FACE experiment, the effect of O<jats:sub>3</jats:sub> exposure was established in early years and continued to be observed in later years without worsening. Our study suggests that O<jats:sub>3</jats:sub> exposure‐response relationships obtained from OTC seedling studies can be used to make inferences about effects on larger trees. These results imply that researchers can use these relationships with confidence when estimating risks of O<jats:sub>3</jats:sub> pollution across the United States.","PeriodicalId":175,"journal":{"name":"Global Change Biology","volume":"89 1","pages":""},"PeriodicalIF":11.6,"publicationDate":"2024-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142867062","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mechanistic insights into carbonate radical-driven reactions: Selectivity and the hydrogen atom abstraction route
IF 13.6 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-12-21 DOI: 10.1016/j.jhazmat.2024.136930
Yu Li, Jun Teng, Jia Wu, Sai Zhang, Zhiwei Zhao, Li Li
Carbonate radical (CO<sub>3</sub><sup>•</sup><sup><img alt="single bond" src="https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif" style="vertical-align:middle"/></sup>) is inevitably produced in advanced oxidation processes (AOPs) when addressing real-world aqueous environments, yet it often goes unnoticed due to its relatively lower reactivity. In this study, we emphasized the pivotal role of CO<sub>3</sub><sup>•<img alt="single bond" src="https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif" style="vertical-align:middle"/></sup> in targeting the elimination of contaminants by contrasting it with conventional reactive oxygen species (ROSs) and assessing the removal of sulfamethazine (SMT). Similar to singlet oxygen (<sup>1</sup>O<sub>2</sub>), CO<sub>3</sub><sup>•<img alt="single bond" src="https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif" style="vertical-align:middle"/></sup> shows a preference for electron-rich organic compounds. In addition, hydrogen atom abstraction (HAA) was determined as the primary pathway in CO<sub>3</sub><sup>•<img alt="single bond" src="https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif" style="vertical-align:middle"/></sup>-driven reactions, with a lower free energy barrier (∆G<sup>‡</sup>) compared to the addition process, while single electron transfer (SET) was found to be thermodynamically unfavorable in all selected aromatics with varying substituents, using DFT calculations. The H atoms within amino groups (<img alt="single bond" src="https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif" style="vertical-align:middle"/>NH<sub>2</sub> and <img alt="single bond" src="https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif" style="vertical-align:middle"/>NH<img alt="single bond" src="https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif" style="vertical-align:middle"/>) were shown to be the most susceptible to abstraction by CO<sub>3</sub><sup>•<img alt="single bond" src="https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif" style="vertical-align:middle"/></sup>, which is more facile than hydroxyl radical (<sup>•</sup>OH) due to the shorter N<img alt="single bond" src="https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif" style="vertical-align:middle"/>H bond cleavage length. Finally, the degradation intermediates of SMT by CO<sub>3</sub><sup>•<img alt="single bond" src="https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif" style="vertical-align:middle"/></sup> were identified, with SO<sub>2</sub> extraction, the cleavage of S<img alt="single bond" src="https://sdfestaticassets-us-east-1.sciencedirectassets.co
{"title":"Mechanistic insights into carbonate radical-driven reactions: Selectivity and the hydrogen atom abstraction route","authors":"Yu Li, Jun Teng, Jia Wu, Sai Zhang, Zhiwei Zhao, Li Li","doi":"10.1016/j.jhazmat.2024.136930","DOIUrl":"https://doi.org/10.1016/j.jhazmat.2024.136930","url":null,"abstract":"Carbonate radical (CO&lt;sub&gt;3&lt;/sub&gt;&lt;sup&gt;•&lt;/sup&gt;&lt;sup&gt;&lt;img alt=\"single bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif\" style=\"vertical-align:middle\"/&gt;&lt;/sup&gt;) is inevitably produced in advanced oxidation processes (AOPs) when addressing real-world aqueous environments, yet it often goes unnoticed due to its relatively lower reactivity. In this study, we emphasized the pivotal role of CO&lt;sub&gt;3&lt;/sub&gt;&lt;sup&gt;•&lt;img alt=\"single bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif\" style=\"vertical-align:middle\"/&gt;&lt;/sup&gt; in targeting the elimination of contaminants by contrasting it with conventional reactive oxygen species (ROSs) and assessing the removal of sulfamethazine (SMT). Similar to singlet oxygen (&lt;sup&gt;1&lt;/sup&gt;O&lt;sub&gt;2&lt;/sub&gt;), CO&lt;sub&gt;3&lt;/sub&gt;&lt;sup&gt;•&lt;img alt=\"single bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif\" style=\"vertical-align:middle\"/&gt;&lt;/sup&gt; shows a preference for electron-rich organic compounds. In addition, hydrogen atom abstraction (HAA) was determined as the primary pathway in CO&lt;sub&gt;3&lt;/sub&gt;&lt;sup&gt;•&lt;img alt=\"single bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif\" style=\"vertical-align:middle\"/&gt;&lt;/sup&gt;-driven reactions, with a lower free energy barrier (∆G&lt;sup&gt;‡&lt;/sup&gt;) compared to the addition process, while single electron transfer (SET) was found to be thermodynamically unfavorable in all selected aromatics with varying substituents, using DFT calculations. The H atoms within amino groups (&lt;img alt=\"single bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif\" style=\"vertical-align:middle\"/&gt;NH&lt;sub&gt;2&lt;/sub&gt; and &lt;img alt=\"single bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif\" style=\"vertical-align:middle\"/&gt;NH&lt;img alt=\"single bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif\" style=\"vertical-align:middle\"/&gt;) were shown to be the most susceptible to abstraction by CO&lt;sub&gt;3&lt;/sub&gt;&lt;sup&gt;•&lt;img alt=\"single bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif\" style=\"vertical-align:middle\"/&gt;&lt;/sup&gt;, which is more facile than hydroxyl radical (&lt;sup&gt;•&lt;/sup&gt;OH) due to the shorter N&lt;img alt=\"single bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif\" style=\"vertical-align:middle\"/&gt;H bond cleavage length. Finally, the degradation intermediates of SMT by CO&lt;sub&gt;3&lt;/sub&gt;&lt;sup&gt;•&lt;img alt=\"single bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif\" style=\"vertical-align:middle\"/&gt;&lt;/sup&gt; were identified, with SO&lt;sub&gt;2&lt;/sub&gt; extraction, the cleavage of S&lt;img alt=\"single bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.co","PeriodicalId":361,"journal":{"name":"Journal of Hazardous Materials","volume":"31 1","pages":""},"PeriodicalIF":13.6,"publicationDate":"2024-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142867170","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Surveillance and environmental risk of very mobile pollutants in urban stormwater and rainwater in a water-stressed city
IF 13.6 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-12-21 DOI: 10.1016/j.jhazmat.2024.136959
Francesc Labad, Sergio Santana-Viera, Jiaqi Xu, Xavier Borrell-Diaz, Marc Teixidó, Sandra Pérez
Urban stormwater and rainwater in water-stressed cities serve as critical vectors for the transport and dispersion of pollutants, including very mobile compounds These pollutants, which can be influenced by factors such as land use, rainfall intensity, and urban infrastructure, pose significant risks to both human and environmental health. Although several priority pollutants have traditionally been detected in urban stormwater, little is known about the presence of very mobile compounds that may threaten urban drinking water supplies and pose environmental risks to aquatic species. In this study, 131 urban rain and stormwater samples were collected from three districts of Barcelona (Spain) and analysed for 26 very mobile pollutants that are often overlooked in conventional monitoring efforts. The findings reveal that stormwater and rainwater are major contributors to the spread of pollutants in water-stressed cities, with particular emphasis on substances like lifestyle products, pharmaceuticals, and industrial chemicals. Among the 23 compounds detected, 12 were reported for the first time to occur in urban stormwater with concentrations as high as 271 µg L-1. Measurements of dissolved organic carbon, electrical conductivity, and the presence of wastewater-borne pollutants within the correlation analysis, suggested the contribution of sanitary sewer overflows (SSO) to urban stormwater. Finally, an environmental risk assessment (worst-case scenario) was performed, showing a moderate risk of target analytes such as acesulfame and 1-naphthalenesulfonic acid (ERQ > 0.1). The results highlight the need for improved surveillance systems, more sustainable stormwater management practices, and strategies for mitigating the environmental risk posed by very mobile pollutants in regions facing water scarcity.
{"title":"Surveillance and environmental risk of very mobile pollutants in urban stormwater and rainwater in a water-stressed city","authors":"Francesc Labad, Sergio Santana-Viera, Jiaqi Xu, Xavier Borrell-Diaz, Marc Teixidó, Sandra Pérez","doi":"10.1016/j.jhazmat.2024.136959","DOIUrl":"https://doi.org/10.1016/j.jhazmat.2024.136959","url":null,"abstract":"Urban stormwater and rainwater in water-stressed cities serve as critical vectors for the transport and dispersion of pollutants, including very mobile compounds These pollutants, which can be influenced by factors such as land use, rainfall intensity, and urban infrastructure, pose significant risks to both human and environmental health. Although several priority pollutants have traditionally been detected in urban stormwater, little is known about the presence of very mobile compounds that may threaten urban drinking water supplies and pose environmental risks to aquatic species. In this study, 131 urban rain and stormwater samples were collected from three districts of Barcelona (Spain) and analysed for 26 very mobile pollutants that are often overlooked in conventional monitoring efforts. The findings reveal that stormwater and rainwater are major contributors to the spread of pollutants in water-stressed cities, with particular emphasis on substances like lifestyle products, pharmaceuticals, and industrial chemicals. Among the 23 compounds detected, 12 were reported for the first time to occur in urban stormwater with concentrations as high as 271<!-- --> <!-- -->µg<!-- --> <!-- -->L<sup>-1</sup>. Measurements of dissolved organic carbon, electrical conductivity, and the presence of wastewater-borne pollutants within the correlation analysis, suggested the contribution of sanitary sewer overflows (SSO) to urban stormwater. Finally, an environmental risk assessment (worst-case scenario) was performed, showing a moderate risk of target analytes such as acesulfame and 1-naphthalenesulfonic acid (ERQ &gt; 0.1). The results highlight the need for improved surveillance systems, more sustainable stormwater management practices, and strategies for mitigating the environmental risk posed by very mobile pollutants in regions facing water scarcity.","PeriodicalId":361,"journal":{"name":"Journal of Hazardous Materials","volume":"14 1","pages":""},"PeriodicalIF":13.6,"publicationDate":"2024-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142867334","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Reproductive toxicity and molecular mechanisms of benzo[a]pyrene exposure on ovary, testis, and brood pouch of sex-role-reversed seahorses (Hippocampus erectus)
IF 8.9 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2024-12-21 DOI: 10.1016/j.envpol.2024.125569
Yuanyuan Xue, Fang Wang, Xiaolei Su, Mingzhu Li, Hansheng Yan, Shiyi Zheng, Yicong Ma, Jie Dong, Yali Liu, Qiang Lin, Kai Wang
As a flagship taxa for marine ecosystems, seahorses possess a unique reproductive strategy of “male pregnancy”. They are severely threatened by marine petroleum-based pollution but the molecular mechanism involved remains unclear. We evaluated the toxic effects and mechanisms of sub-acute exposure to benzo[a]pyrene (BaP), a representative polycyclic aromatic hydrocarbon (PAH), at three environmental related dosages (0.5, 5, and 50 μg/L) on the reproductive organs of sex-role-reversed lined seahorses (Hippocampus erectus). BaP induced ovary, testis and brood pouch tissue damage in a concentration-dependent manner. Transcriptomic results suggested that reproductive organs of the seahorse could undergo biotransformation and detoxification of BaP via the P450 enzyme system; the differential expression of key genes related to these pathways determined the differences in the accumulation of toxic substances in the reproductive organs. Moreover, toxic substances directly induced differential tissue damage in situ by activating tissue-specific signaling pathways: BaP-induced ovarian apoptosis and failure by upregulation of the pro-apoptotic genes, vadc1, traf2b, tnfsf10, and pycard (P < 0.05); inhibition of testicular function through disruption of genes associated with “ECM-receptor interaction”, “Tight junction”, and “Spermatogenesis” pathways; and interference with brood pouch immune responses, significantly suppressing the expression of ripk1, il-1b, casp3a, apaf1, calr, and canx (P < 0.05), thereby impairing “Apoptosis”, “Phagosome”, and “Necroptosis” processes, ultimately compromising brood pouch maintenance. Toxic substances exacerbate damage to the reproductive organs in seahorses by disrupting Ca2+ homeostasis. At environmentally-relevant concentrations of BaP, the reproductive efficiency of seahorses may be severely affected, increasing the risk of a decline in the abundance and diversity of wild populations.
{"title":"Reproductive toxicity and molecular mechanisms of benzo[a]pyrene exposure on ovary, testis, and brood pouch of sex-role-reversed seahorses (Hippocampus erectus)","authors":"Yuanyuan Xue, Fang Wang, Xiaolei Su, Mingzhu Li, Hansheng Yan, Shiyi Zheng, Yicong Ma, Jie Dong, Yali Liu, Qiang Lin, Kai Wang","doi":"10.1016/j.envpol.2024.125569","DOIUrl":"https://doi.org/10.1016/j.envpol.2024.125569","url":null,"abstract":"As a flagship taxa for marine ecosystems, seahorses possess a unique reproductive strategy of “male pregnancy”. They are severely threatened by marine petroleum-based pollution but the molecular mechanism involved remains unclear. We evaluated the toxic effects and mechanisms of sub-acute exposure to benzo[a]pyrene (BaP), a representative polycyclic aromatic hydrocarbon (PAH), at three environmental related dosages (0.5, 5, and 50 μg/L) on the reproductive organs of sex-role-reversed lined seahorses (<em>Hippocampus erectus</em>). BaP induced ovary, testis and brood pouch tissue damage in a concentration-dependent manner. Transcriptomic results suggested that reproductive organs of the seahorse could undergo biotransformation and detoxification of BaP via the P450 enzyme system; the differential expression of key genes related to these pathways determined the differences in the accumulation of toxic substances in the reproductive organs. Moreover, toxic substances directly induced differential tissue damage <em>in situ</em> by activating tissue-specific signaling pathways: BaP-induced ovarian apoptosis and failure by upregulation of the pro-apoptotic genes, <em>vadc1</em>, <em>traf2b</em>, <em>tnfsf10</em>, and <em>pycard</em> (<em>P</em> &lt; 0.05); inhibition of testicular function through disruption of genes associated with “ECM-receptor interaction”, “Tight junction”, and “Spermatogenesis” pathways; and interference with brood pouch immune responses, significantly suppressing the expression of <em>ripk1</em>, <em>il-1b</em>, <em>casp3a</em>, <em>apaf1</em>, <em>calr</em>, and <em>canx</em> (<em>P</em> &lt; 0.05), thereby impairing “Apoptosis”, “Phagosome”, and “Necroptosis” processes, ultimately compromising brood pouch maintenance. Toxic substances exacerbate damage to the reproductive organs in seahorses by disrupting Ca<sup>2+</sup> homeostasis. At environmentally-relevant concentrations of BaP, the reproductive efficiency of seahorses may be severely affected, increasing the risk of a decline in the abundance and diversity of wild populations.","PeriodicalId":311,"journal":{"name":"Environmental Pollution","volume":"31 1","pages":""},"PeriodicalIF":8.9,"publicationDate":"2024-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142867097","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
On the challenges of civic engagement in the mobility transition - A conceptual analysis of the linkages between car dependence and collective action
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-12-21 DOI: 10.1016/j.jclepro.2024.144533
Viktoria Allert, Gerhard Reese
In complex transition processes, such as the mobility transition, active citizens have the power to change and to demand change of the incumbent mobility system. For individuals, a substantial challenge lies in breaking up and transforming dominant, unsustainable practices and structures in place. Shifting consumption patterns and routines can contribute to changing such practices, but in democratic societies in particular, stronger levers lie in collective, political participation processes: Individuals can partake by electing representatives who can challenge the car-centric mobility system, or by engaging in citizen initiatives and protests to back up niche innovations and demand policy changes. However, citizen engagement for a sustainable mobility transition faces several structural challenges rooted in the characteristics of the car-centric mobility system.In this paper, we theorize how these characteristics of the car-centric regime influence psychological processes underlying motivation for collective action participation. Based on the Social Identity Model of Pro-Environmental Action (Fritsche et al., 2018), we highlight how motivational factors like a common social identity, collective efficacy beliefs and ingroup norms and goals develop in relation to the specificities of the context the collective action occurs in. We exemplify how the systemic level interacts with individual, within-actor processes and thereby provide a critical perspective on collective action research in transport. This paper explores and delineates intersections between transition studies and collective action research and sketches an interdisciplinary research agenda to advance our understanding of engagement of citizens in mobility activism.
{"title":"On the challenges of civic engagement in the mobility transition - A conceptual analysis of the linkages between car dependence and collective action","authors":"Viktoria Allert, Gerhard Reese","doi":"10.1016/j.jclepro.2024.144533","DOIUrl":"https://doi.org/10.1016/j.jclepro.2024.144533","url":null,"abstract":"In complex transition processes, such as the mobility transition, active citizens have the power to change and to demand change of the incumbent mobility system. For individuals, a substantial challenge lies in breaking up and transforming dominant, unsustainable practices and structures in place. Shifting consumption patterns and routines can contribute to changing such practices, but in democratic societies in particular, stronger levers lie in collective, political participation processes: Individuals can partake by electing representatives who can challenge the car-centric mobility system, or by engaging in citizen initiatives and protests to back up niche innovations and demand policy changes. However, citizen engagement for a sustainable mobility transition faces several structural challenges rooted in the characteristics of the car-centric mobility system.In this paper, we theorize how these characteristics of the car-centric regime influence psychological processes underlying motivation for collective action participation. Based on the Social Identity Model of Pro-Environmental Action (Fritsche et al., 2018), we highlight how motivational factors like a common social identity, collective efficacy beliefs and ingroup norms and goals develop in relation to the specificities of the context the collective action occurs in. We exemplify how the systemic level interacts with individual, within-actor processes and thereby provide a critical perspective on collective action research in transport. This paper explores and delineates intersections between transition studies and collective action research and sketches an interdisciplinary research agenda to advance our understanding of engagement of citizens in mobility activism.","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"77 1","pages":""},"PeriodicalIF":11.1,"publicationDate":"2024-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142867284","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Interpreting Machine Learning Predictions of Pb2+ Adsorption onto Biochars Produced by a Fluidized Bed System
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-12-21 DOI: 10.1016/j.jclepro.2024.144551
Suya Shi, Yaji Huang, Han Shen, Tengfei Zheng, Xinye Wang, Mengzhu Yu, Lingqin Liu
Employing machine learning to predict the Pb2+ adsorption capacity of biochars is an innovative pursuit in hazardous materials. This study compared artificial neural network (ANN), support vector regression (SVR) and random forest (RF) for Pb2+ adsorption capacity by biochar from a fluidized bed system. Besides developing correlations for comparison, the RF model (R2 = 0.984, RMSE=0.054) outperformed both ANN (R2 = 0.908, RMSE=0.316) and SVR (R2 =0.667) in predicting higher adsorption capacity. Based on the superior performance, the Shapley Additive Explanations (SHAP) were employed on RF. SHAP global explanations indicated that adsorption conditions contributed 69.03% and biochar characteristics contributed 30.21%to adsorption capacity, highlighting Dosage (D) and Carbon (C) as the crucial factors. Regarding biochar characteristics, element compositions contributed 76.59%. The single samples demonstrated that the final predictions align with the experimental results. The synergistic effect of dependence plot explains the Pb2+ adsorption under varying parameter conditions, such as D<1g/L, C<45%, Pbin>100mg/L, H<2.5, t>12h, T>25°C, pH>9, H/C>0.4, the SHAP value is positive, contributing to an increase in adsorption capacity. Furthermore, a graphical user interface (GUI) leveraging SHAP model parameters predicts adsorbent performance, providing novel insights into optimizing biochars production. The obtained findings narrow the search for optimal biochars adsorbents and might guide laboratory experiments and engineering application of Pb2+ removal using biochars.
{"title":"Interpreting Machine Learning Predictions of Pb2+ Adsorption onto Biochars Produced by a Fluidized Bed System","authors":"Suya Shi, Yaji Huang, Han Shen, Tengfei Zheng, Xinye Wang, Mengzhu Yu, Lingqin Liu","doi":"10.1016/j.jclepro.2024.144551","DOIUrl":"https://doi.org/10.1016/j.jclepro.2024.144551","url":null,"abstract":"Employing machine learning to predict the Pb<sup>2+</sup> adsorption capacity of biochars is an innovative pursuit in hazardous materials. This study compared artificial neural network (ANN), support vector regression (SVR) and random forest (RF) for Pb<sup>2+</sup> adsorption capacity by biochar from a fluidized bed system. Besides developing correlations for comparison, the RF model (R<sup>2</sup> = 0.984, RMSE=0.054) outperformed both ANN (R<sup>2</sup> = 0.908, RMSE=0.316) and SVR (R<sup>2</sup> =0.667) in predicting higher adsorption capacity. Based on the superior performance, the Shapley Additive Explanations (SHAP) were employed on RF. SHAP global explanations indicated that adsorption conditions contributed 69.03% and biochar characteristics contributed 30.21%to adsorption capacity, highlighting Dosage (D) and Carbon (C) as the crucial factors. Regarding biochar characteristics, element compositions contributed 76.59%. The single samples demonstrated that the final predictions align with the experimental results. The synergistic effect of dependence plot explains the Pb<sup>2+</sup> adsorption under varying parameter conditions, such as D&lt;1g/L, C&lt;45%, Pb<sub>in</sub>&gt;100mg/L, H&lt;2.5, t&gt;12h, T&gt;25°C, pH&gt;9, H/C&gt;0.4, the SHAP value is positive, contributing to an increase in adsorption capacity. Furthermore, a graphical user interface (GUI) leveraging SHAP model parameters predicts adsorbent performance, providing novel insights into optimizing biochars production. The obtained findings narrow the search for optimal biochars adsorbents and might guide laboratory experiments and engineering application of Pb<sup>2+</sup> removal using biochars.","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"53 1","pages":""},"PeriodicalIF":11.1,"publicationDate":"2024-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142867285","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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