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Revealing Photo-electrochemical, Piezoelectric, and Ferroelectric Properties of γ-SnTe Monolayer via Density Functional Theory
IF 3.1 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-04-10 DOI: 10.1016/j.commatsci.2025.113879
Nguyen Hoang Linh , Nguyen Xuan Dong , Tran The Quang , Dinh The Hung , Do Van Truong
In this work, Density Functional Theory (DFT) calculations were performed to explore the photo-electrochemical, piezoelectric, and ferroelectric properties of the γ-SnTe monolayer. The optimized structure is confirmed to be dynamically and mechanically stable, exhibiting isotropic elastic behavior with an elastic modulus of 18.92 N/m and a shear modulus of 7.56 N/m. Electronic band structure analysis reveals that the γ-SnTe monolayer is an indirect semiconductor with a band gap of 2.56 eV, and the separation between charge carriers is clearly observed, with an effective mass mobility of approximately 0.44 m0. Under biaxial strain, the band states continuously shift, optimizing redox potentials for surface chemical reactions. The material also demonstrates high piezoelectric coefficients, enabling efficient conversion of mechanical energy into electrical energy. Additionally, ferroelectricity is confirmed with a residual polarization of Pz = 5 pC/m and a low-energy switching barrier, making γ-SnTe highly suitable for low-power memory devices. These findings establish the γ-SnTe monolayer as a promising multifunctional material with potential applications in green energy technologies, electromechanical systems, and next-generation memory devices.
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引用次数: 0
Electronic and magnetic phase transitions, optimized MAE/ TC, and high thermoelectric response in Y2NiIrO6: Strain effects
IF 3.1 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-04-10 DOI: 10.1016/j.commatsci.2025.113880
Usman Saeed , A. Islam , Bassem F. Felemban , Hafiz Tauqeer Ali , S. Nazir
<div><div>We explore the biaxial ([110]) strain consequences on the distinct features of the pristine (prist.) Y<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>NiIrO<span><math><msub><mrow></mrow><mrow><mn>6</mn></mrow></msub></math></span> motif using <em>ab</em>-<em>initio</em> calculations. The anomalous <span><math><mrow><msub><mrow><mi>J</mi></mrow><mrow><mi>e</mi><mi>f</mi><mi>f</mi><mo>.</mo></mrow></msub><mo>=</mo><mfrac><mrow><mn>1</mn></mrow><mrow><mn>2</mn></mrow></mfrac></mrow></math></span> state of Ir<span><math><msup><mrow></mrow><mrow><mo>+</mo><mn>4</mn></mrow></msup></math></span>, leads the system into a Mott-insulating (MI) state attaining an energy gap (<span><math><msub><mrow><mi>E</mi></mrow><mrow><mi>g</mi></mrow></msub></math></span>) of 0.21 eV with a ferrimagnetic (FiM) phase, which is ultimately caused by anti-ferromagnetic (AFM) coupling between the half-filled Ni<span><math><mrow><msup><mrow></mrow><mrow><mo>+</mo><mn>2</mn></mrow></msup><mn>3</mn><msup><mrow><mi>d</mi></mrow><mrow><mn>8</mn></mrow></msup></mrow></math></span> and partially-filled Ir<span><math><mrow><msup><mrow></mrow><mrow><mo>+</mo><mn>4</mn></mrow></msup><mn>5</mn><msup><mrow><mi>d</mi></mrow><mrow><mn>5</mn></mrow></msup></mrow></math></span> orbitals, via oxygen 2<span><math><msup><mrow><mi>p</mi></mrow><mrow><mn>2</mn></mrow></msup></math></span> states. Remarkably, lattice thermal conductivity (<span><math><msub><mrow><mi>κ</mi></mrow><mrow><mi>L</mi></mrow></msub></math></span>) is computed utilizing the Slack model, which significantly lowers the figure of merit (ZT) from 0.75 (excluding <span><math><msub><mrow><mi>κ</mi></mrow><mrow><mi>L</mi></mrow></msub></math></span>) to 0.34 (including <span><math><msub><mrow><mi>κ</mi></mrow><mrow><mi>L</mi></mrow></msub></math></span>) at 300 K. Interestingly, a reasonable ZT of 0.58 is achieved above room temperature (500 K). Moreover, the computed partial spin moments (<span><math><msub><mrow><mi>m</mi></mrow><mrow><mi>s</mi></mrow></msub></math></span>) for the Ni<span><math><msup><mrow></mrow><mrow><mo>+</mo><mn>2</mn></mrow></msup></math></span> and Ir<span><math><msup><mrow></mrow><mrow><mo>+</mo><mn>4</mn></mrow></msup></math></span> ions holding high spin and low spin states of S <span><math><mrow><mo>=</mo><mn>1</mn></mrow></math></span> and <span><math><mfrac><mrow><mn>1</mn></mrow><mrow><mn>2</mn></mrow></mfrac></math></span> are + 1.67 and <span><math><mrow><mo>−</mo><mn>0</mn><mo>.</mo><mn>53</mn><msub><mrow><mi>μ</mi></mrow><mrow><mi>B</mi></mrow></msub></mrow></math></span>, respectively. The easy magnetic axis is determined to be the <span><math><mi>b</mi></math></span>-axis, which produces a significant magnetic anisotropy energy (MAE) constant of <span><math><mrow><mn>1</mn><mo>.</mo><mn>7</mn><mo>×</mo><mn>1</mn><msup><mrow><mn>0</mn></mrow><mrow><mn>8</mn></mrow></msup></mrow></math></span> erg/cm<sup>3</sup> keeping a Curie temperature (<span><math><ms
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The anomalous &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;J&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;e&lt;/mi&gt;&lt;mi&gt;f&lt;/mi&gt;&lt;mi&gt;f&lt;/mi&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mfrac&gt;&lt;mrow&gt;&lt;mn&gt;1&lt;/mn&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;/mrow&gt;&lt;/mfrac&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt; state of Ir&lt;span&gt;&lt;math&gt;&lt;msup&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mo&gt;+&lt;/mo&gt;&lt;mn&gt;4&lt;/mn&gt;&lt;/mrow&gt;&lt;/msup&gt;&lt;/math&gt;&lt;/span&gt;, leads the system into a Mott-insulating (MI) state attaining an energy gap (&lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;E&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;g&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;) of 0.21 eV with a ferrimagnetic (FiM) phase, which is ultimately caused by anti-ferromagnetic (AFM) coupling between the half-filled Ni&lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;msup&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mo&gt;+&lt;/mo&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;/mrow&gt;&lt;/msup&gt;&lt;mn&gt;3&lt;/mn&gt;&lt;msup&gt;&lt;mrow&gt;&lt;mi&gt;d&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;8&lt;/mn&gt;&lt;/mrow&gt;&lt;/msup&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt; and partially-filled Ir&lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;msup&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mo&gt;+&lt;/mo&gt;&lt;mn&gt;4&lt;/mn&gt;&lt;/mrow&gt;&lt;/msup&gt;&lt;mn&gt;5&lt;/mn&gt;&lt;msup&gt;&lt;mrow&gt;&lt;mi&gt;d&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;5&lt;/mn&gt;&lt;/mrow&gt;&lt;/msup&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt; orbitals, via oxygen 2&lt;span&gt;&lt;math&gt;&lt;msup&gt;&lt;mrow&gt;&lt;mi&gt;p&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;/mrow&gt;&lt;/msup&gt;&lt;/math&gt;&lt;/span&gt; states. Remarkably, lattice thermal conductivity (&lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;κ&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;L&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;) is computed utilizing the Slack model, which significantly lowers the figure of merit (ZT) from 0.75 (excluding &lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;κ&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;L&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;) to 0.34 (including &lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;κ&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;L&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;) at 300 K. Interestingly, a reasonable ZT of 0.58 is achieved above room temperature (500 K). Moreover, the computed partial spin moments (&lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;m&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;s&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;) for the Ni&lt;span&gt;&lt;math&gt;&lt;msup&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mo&gt;+&lt;/mo&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;/mrow&gt;&lt;/msup&gt;&lt;/math&gt;&lt;/span&gt; and Ir&lt;span&gt;&lt;math&gt;&lt;msup&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mo&gt;+&lt;/mo&gt;&lt;mn&gt;4&lt;/mn&gt;&lt;/mrow&gt;&lt;/msup&gt;&lt;/math&gt;&lt;/span&gt; ions holding high spin and low spin states of S &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mn&gt;1&lt;/mn&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt; and &lt;span&gt;&lt;math&gt;&lt;mfrac&gt;&lt;mrow&gt;&lt;mn&gt;1&lt;/mn&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;/mrow&gt;&lt;/mfrac&gt;&lt;/math&gt;&lt;/span&gt; are + 1.67 and &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mo&gt;−&lt;/mo&gt;&lt;mn&gt;0&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;53&lt;/mn&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;μ&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;B&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;, respectively. The easy magnetic axis is determined to be the &lt;span&gt;&lt;math&gt;&lt;mi&gt;b&lt;/mi&gt;&lt;/math&gt;&lt;/span&gt;-axis, which produces a significant magnetic anisotropy energy (MAE) constant of &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mn&gt;1&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;7&lt;/mn&gt;&lt;mo&gt;×&lt;/mo&gt;&lt;mn&gt;1&lt;/mn&gt;&lt;msup&gt;&lt;mrow&gt;&lt;mn&gt;0&lt;/mn&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;8&lt;/mn&gt;&lt;/mrow&gt;&lt;/msup&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt; erg/cm&lt;sup&gt;3&lt;/sup&gt; keeping a Curie temperature (&lt;span&gt;&lt;math&gt;&lt;ms","PeriodicalId":10650,"journal":{"name":"Computational Materials Science","volume":"253 ","pages":"Article 113880"},"PeriodicalIF":3.1,"publicationDate":"2025-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143807196","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The effect of post-weld heat treatment on the formability of aluminum to steel friction stir welded blanks
IF 2.6 3区 材料科学 Q2 ENGINEERING, MANUFACTURING Pub Date : 2025-04-10 DOI: 10.1007/s12289-025-01898-4
Muhamad Zulkhairi Rizlan, Ahmad Baharuddin Abdullah, Zuhailawati Hussain

Formability is the ability of a material to undergo plastic deformation without being damaged. In sheet metal forming, materials are known to experience deformation in biaxial stretch mode. In order to simulate the common failure strains in sheet metal forming process, numerous formability test methods can be used. A material’s formability can be altered in several ways, one of which is post-weld heat treatment. In this study, the effect of post-weld heat treatment on the formability of aluminum alloy 6061 and SAE1020 mild steel tailor welded blanks fabricated by friction stir welding was evaluated using limiting dome height test. It was found that the specimens which underwent post-weld heat treatment recorded a lower springback and higher value of plane strain, indicating a better formability. The improved formability is attributed to microstructural homogenization, defects elimination, residual stresses relieve and IMC layer growth control from the post-weld heat treatment process.

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引用次数: 0
Pulse-Charging Energy Storage for Triboelectric Nanogenerator Based on Frequency Modulation
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2025-04-10 DOI: 10.1007/s40820-025-01714-3
Kwon-Hyung Lee, Min-Gyun Kim, Woosuk Kang, Hyun-Moon Park, Youngmin Cho, Jeongsoo Hong, Tae-Hee Kim, Seung-Hyeok Kim, Seok-Kyu Cho, Donghyeon Kang, Sang-Woo Kim, Changshin Jo, Sang-Young Lee

Highlights

  • A system-level strategy is presented to achieve high charging efficiency in triboelectric nanogenerator (TENG)-supercapacitor (SC) hybrid devices, with a focus on frequency response design.

  • This study reveals that the high-frequency characteristics of SCs and the prolonged output pulse duration of TENGs are critical for achieving high charging efficiency.

  • A three-dimensional hollow-structured MXene is synthesized as a high-frequency SC electrode material, demonstrating a twofold increase in charging efficiency compared to conventional SCs.

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引用次数: 0
Correction: Physical and mechanical properties of wood treated with chitosan-caffeine formulations
IF 2.4 3区 农林科学 Q1 FORESTRY Pub Date : 2025-04-10 DOI: 10.1007/s00107-025-02256-6
Magdalena Woźniak, Jerzy Majka, Patrycja Kwaśniewska-Sip, Tomasz Krystofiak, Barbara Lis, Edward Roszyk, Grzegorz Cofta, Izabela Ratajczak
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引用次数: 0
Analysis of biological adhesion and biomineralization products on the Yangtze Estuary II shipwreck
IF 3.1 2区 农林科学 Q1 FORESTRY Pub Date : 2025-04-10 DOI: 10.1007/s00226-025-01651-9
Meng Zhao, Hao Zhou, He Huang, Jing Zhao, Qiang Li, Hongjie Luo

Biological deposition is commonly observed on wooden shipwrecks. This study employs analytical techniques, including optical microscopy (OM), scanning electron microscope equipped with an energy dispersive spectrometer (SEM-EDS), X-ray diffraction (XRD) and Fourier infrared transform spectroscopy (FTIR), to investigate the microscopic morphology and structural composition of barnacles and their adhesion to the wooden surface of the Yangtze Estuary II shipwreck. Results indicate that microorganisms like diatoms and Trichoderma spp. were present at the interface between the barnacles and the wooden surface. These microorganisms played a crucial role in the formation of SiO2, CaHPO4•2(H2O), FeO(OH) and CaCO3. Specifically, the bio-mineralized cell walls of diatoms and their cellular contents, including polyphosphates, provided the necessary Si and P for SiO2 and CaHPO4•2(H2O), respectively. Furthermore, during their metabolic processes, diatoms and Trichoderma spp. supply dissolved Fe ions, which contribute to the formation of FeO(OH) on the wooden surface. This study elucidates four types of bio-mineralized products resulting from microbial activity on the salvaged wooden shipwreck.

{"title":"Analysis of biological adhesion and biomineralization products on the Yangtze Estuary II shipwreck","authors":"Meng Zhao,&nbsp;Hao Zhou,&nbsp;He Huang,&nbsp;Jing Zhao,&nbsp;Qiang Li,&nbsp;Hongjie Luo","doi":"10.1007/s00226-025-01651-9","DOIUrl":"10.1007/s00226-025-01651-9","url":null,"abstract":"<div><p>Biological deposition is commonly observed on wooden shipwrecks. This study employs analytical techniques, including optical microscopy (OM), scanning electron microscope equipped with an energy dispersive spectrometer (SEM-EDS), X-ray diffraction (XRD) and Fourier infrared transform spectroscopy (FTIR), to investigate the microscopic morphology and structural composition of barnacles and their adhesion to the wooden surface of the Yangtze Estuary II shipwreck. Results indicate that microorganisms like diatoms and <i>Trichoderma</i> spp. were present at the interface between the barnacles and the wooden surface. These microorganisms played a crucial role in the formation of SiO<sub>2</sub>, CaHPO<sub>4</sub>•2(H<sub>2</sub>O), FeO(OH) and CaCO<sub>3</sub>. Specifically, the bio-mineralized cell walls of diatoms and their cellular contents, including polyphosphates, provided the necessary Si and P for SiO<sub>2</sub> and CaHPO<sub>4</sub>•2(H<sub>2</sub>O), respectively. Furthermore, during their metabolic processes, diatoms and <i>Trichoderma</i> spp. supply dissolved Fe ions, which contribute to the formation of FeO(OH) on the wooden surface. This study elucidates four types of bio-mineralized products resulting from microbial activity on the salvaged wooden shipwreck.</p></div>","PeriodicalId":810,"journal":{"name":"Wood Science and Technology","volume":"59 3","pages":""},"PeriodicalIF":3.1,"publicationDate":"2025-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143809366","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Engineered Neutrophil Nanovesicles for Inhibiting Corneal Neovascularization by Synergistic Anti-Inflammatory, Anti-VEGF, and Chemoexcited Photodynamic Therapy (Adv. Mater. 14/2025)
IF 27.4 1区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2025-04-10 DOI: 10.1002/adma.202570113
Xiaoxue Liu, Yingxuan Bi, Chaoqun Wei, Ye Zhang, Xiaoyu Liu, Xinghan Guo, Longfei Zhao, Jingjing Zhang, Changlong Wang, Hua Gao

Chemoexcited Photodynamic Therapy

Inspired by the ancient Chinese myth of “Hou Yi Shooting the Suns,” the cover features a striking representation where the largest sun symbolizes the healthy eye, while others represent diseased eyes impacted by neovascularization. The arrows, representing the synthesized NCCR drug, target corneal neovascularization, offering a potential treatment to restore sight and improve eye health. More details can be found in article number 2411030 by Changlong Wang, Hua Gao, and co-workers.

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引用次数: 0
Intermetallic Compounds for Hydrogen Storage: Current Status and Future Perspectives (Small 14/2025)
IF 13 2区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2025-04-10 DOI: 10.1002/smll.202570107
Amrit Raj Paul, Sunil Mehla, Suresh Bhargava

Intermetallic Compounds

In article number 2408889, Suresh Bhargava and co-workers showed that intermetallic compounds offer great potential for hydrogen storage. This review examines their synthesis, structural properties, and key factors like void volume, lattice structure, and hydride formation enthalpy, providing insights into optimising their performance for low-temperature hydrogen storage applications.

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引用次数: 0
Longevous Protic Hybrid Supercapacitors Using Bimetallic Prussian Blue Analogue/rGO-Based Nanocomposite Against MXene Anode (Small 14/2025)
IF 13 2区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2025-04-10 DOI: 10.1002/smll.202570108
Ruth Stephanie, Chan Yeong Park, Moon Seop Hyun, Amal Al Ghaferi, Hee Han, Ebrahim Alhajri, Nilesh R Chodankar, Tae Jung Park

Supercapacitors

In article number 2406369, Ebrahim Alhajri, Nilesh R Chodankar, Tae Jung Park, and co-workers designed a longevous protic hybrid supercapacitor based on 2D Ti3C2Tx MXene anode and Prussian Blue Analogue nanocomposite NiHCC/rGO cathode was designed, and the device demonstrated maximum specific energy and power of 38 Wh kg−1 and 20.67 kW kg−1, respectively, with no loss of capacitance throughout 15,000 cycles of charge-discharge test.

{"title":"Longevous Protic Hybrid Supercapacitors Using Bimetallic Prussian Blue Analogue/rGO-Based Nanocomposite Against MXene Anode (Small 14/2025)","authors":"Ruth Stephanie,&nbsp;Chan Yeong Park,&nbsp;Moon Seop Hyun,&nbsp;Amal Al Ghaferi,&nbsp;Hee Han,&nbsp;Ebrahim Alhajri,&nbsp;Nilesh R Chodankar,&nbsp;Tae Jung Park","doi":"10.1002/smll.202570108","DOIUrl":"https://doi.org/10.1002/smll.202570108","url":null,"abstract":"<p><b>Supercapacitors</b></p><p>In article number 2406369, Ebrahim Alhajri, Nilesh R Chodankar, Tae Jung Park, and co-workers designed a longevous protic hybrid supercapacitor based on 2D Ti<sub>3</sub>C<sub>2</sub>T<sub><i>x</i></sub> MXene anode and Prussian Blue Analogue nanocomposite NiHCC/rGO cathode was designed, and the device demonstrated maximum specific energy and power of 38 Wh kg<sup>−1</sup> and 20.67 kW kg<sup>−1</sup>, respectively, with no loss of capacitance throughout 15,000 cycles of charge-discharge test.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":228,"journal":{"name":"Small","volume":"21 14","pages":""},"PeriodicalIF":13.0,"publicationDate":"2025-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/smll.202570108","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143809578","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Review on MXenes-Based Electrocatalysts for High-Energy-Density Lithium–Sulfur Batteries
IF 26.6 1区 材料科学 Q1 Engineering Pub Date : 2025-04-10 DOI: 10.1007/s40820-025-01726-z
Xintao Zuo, Yanhui Qiu, Mengmeng Zhen, Dapeng Liu, Yu Zhang

Highlights

  • The significance and challenges associated with high-sulfur loading and lean electrolytes in lithium–sulfur batteries are comprehensively reviewed.

  • Catalytic properties of MXenes-based electrocatalysts are optimized via d-band center tuning, internal electric field constructing, single-atom seeding, and cocktail effects introducing.

  • The structure–activity relationships between MXenes-based electrocatalysts and lithium–sulfur battery performances are comprehensively summarized.

{"title":"Review on MXenes-Based Electrocatalysts for High-Energy-Density Lithium–Sulfur Batteries","authors":"Xintao Zuo,&nbsp;Yanhui Qiu,&nbsp;Mengmeng Zhen,&nbsp;Dapeng Liu,&nbsp;Yu Zhang","doi":"10.1007/s40820-025-01726-z","DOIUrl":"10.1007/s40820-025-01726-z","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 <ul>\u0000 <li>\u0000 <p>The significance and challenges associated with high-sulfur loading and lean electrolytes in lithium–sulfur batteries are comprehensively reviewed.</p>\u0000 </li>\u0000 <li>\u0000 <p>Catalytic properties of MXenes-based electrocatalysts are optimized via d-band center tuning, internal electric field constructing, single-atom seeding, and cocktail effects introducing.\u0000</p>\u0000 </li>\u0000 <li>\u0000 <p>The structure–activity relationships between MXenes-based electrocatalysts and lithium–sulfur battery performances are comprehensively summarized. \u0000</p>\u0000 </li>\u0000 </ul>\u0000 </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"17 1","pages":""},"PeriodicalIF":26.6,"publicationDate":"2025-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-025-01726-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143809327","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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